NUCLEAR TECHNIQUES, Volume. 47, Issue 6, 060607(2024)

Preparation process and performance of graphene oxide-doped UO2 pellets

Feng WEN1,2, Jiangping DU1,2, Yumeng ZHAO1,2、*, Ning YANG2, Zongyi SHAO1,2, Wei LIU1,2, and Zhenfang CAI2
Author Affiliations
  • 1CNNC Key Laboratory of Fabrication Technology of Reactor Irradiation Special Elements, Baotou 014035, China
  • 2China North Nuclear Fuel Element Co., Ltd., Baotou 014035, China
  • show less
    Figures & Tables(11)
    Process flowchart for UO2 powder via ADU co-precipitation method (a) and solid-liquid mixing method (b)
    Process curve of spark plasma sintering for GO-doped UO2 pellets
    Diagram of sampling position for doping uniformity test
    Element distribution of UO2-GO powder for GO doping amounts of 0.5 wt.% (a), 1.5 wt.% (b) and 5.0 wt.% (c)
    SEM morphology of UO2-GO powder for GO doping amounts of 0.5 wt.% (a), 1.5 wt.% (b) and 5.0 wt.% (c)
    Effects of different SPS sintering parameters on pellets properties
    Metallographic structure of UO2-GO pellets for GO doping amounts of 0.5 wt.% (a), 1.5 wt.% (b) and 5.0 wt.% (c)
    Thermal conductivity (a) and increase of thermal conductivity compared to those of conventional UO2 pellets (b) for UO2 pellets prepared under different conditions
    • Table 1. Mixing uniformity of UO2-GO powder for different doping amounts

      View table
      View in Article

      Table 1. Mixing uniformity of UO2-GO powder for different doping amounts

      方法

      Methods

      掺杂量

      Doping amounts / wt.%

      碳含量Carbon content / μg‧g–1M / %
      上部Top中部Middle下部Bottom

      ADU共沉淀法

      ADU co-precipitation method

      0.538322375.65
      1.542415385.31
      5.075375073999.01

      固-液混合法

      Solid-liquid mixing method

      0.51 3181 3381 30398.67
      1.56 3456 3656 26599.16
      5.07 8728 3128 22297.14
    • Table 2. Influence of different heating/cooling rates on the density and cosmetic integrity of pellets

      View table
      View in Article

      Table 2. Influence of different heating/cooling rates on the density and cosmetic integrity of pellets

      编号

      Number

      加热速率

      Heating rate / ℃‧min-1

      冷却速率

      Cooling rate / ℃‧min-1

      外观完整性

      Appearance integrity

      相对密度

      Relative density / %T.D.

      14050

      从中部开裂

      Cracking from the center

      88.1
      24010087.2
      3505087.2
      45010087.4
      51005087.5
      610010087.6
      7

      <1 200 ℃: 100

      1 200~1 700 ℃: 50

      50完好Undamaged88.2
      810088.2
    • Table 3. Density and porosity of UO2 pellets for different GO doping amounts

      View table
      View in Article

      Table 3. Density and porosity of UO2 pellets for different GO doping amounts

      GO掺杂量GO doping amounts / wt.%相对密度Relative density / % T.D.孔隙率Porosity / %
      常规UO2芯块Conventional UO2 pellets95.3~98.0<0.3
      0.593.42.67
      1.597.60.60
      5.096.11.07
      纯UO2 Pure UO297.20.75
    Tools

    Get Citation

    Copy Citation Text

    Feng WEN, Jiangping DU, Yumeng ZHAO, Ning YANG, Zongyi SHAO, Wei LIU, Zhenfang CAI. Preparation process and performance of graphene oxide-doped UO2 pellets[J]. NUCLEAR TECHNIQUES, 2024, 47(6): 060607

    Download Citation

    EndNote(RIS)BibTexPlain Text
    Save article for my favorites
    Paper Information

    Category: Research Articles

    Received: Dec. 13, 2023

    Accepted: --

    Published Online: Jul. 8, 2024

    The Author Email: Yumeng ZHAO (赵雨梦)

    DOI:10.11889/j.0253-3219.2024.hjs.47.060607

    Topics