NUCLEAR TECHNIQUES, Volume. 47, Issue 1, 010302(2024)

Separation of rare earth fission products from LiF-BeF2 molten salt by sulfide precipitation

Yujiao WANG1,2, Yaxin QU2,3, Haiying FU2,3、*, Ming CHENG2,3, Qiang DOU2,3, and Yu GONG2,3
Author Affiliations
  • 1ShanghaiTech University, Shanghai 201210, China
  • 2Shanghai Institute of Applied Physics, Chinese Academy of Sciences, Shanghai 201800, China
  • 3University of Chinese Academy of Sciences, Beijing 100049, China
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    Figures & Tables(15)
    LiF-BeF2 and REF3-LiF-BeF2 mixed molten salts (color online)(a) LiF-BeF2, (b) NdF3-LiF-BeF2, (c) CeF3-LiF-BeF2, (d) SmF3-LiF-BeF2, (e) YbF3-LiF-BeF2
    Gibbs free energy (ΔrGm) change of REF3-Na2S reaction
    Removal ratios when the ratio of NdF3 to Na2S∙5H2O content is 1:2 under different temperatures for 5 h
    Photograph of Salt after adding Na2S·5H2O to REF3-LiF-BeF2 at 600 °C (a) NdF3, (b) CeF3, (c) SmF3, (d) YbF3
    XRD patterns of the precipitates after adding Na2S·5H2O to REF3-LiF-BeF2(a) NdF3, (b) CeF3, (c) SmF3, (d) EuF3
    SEM images of the precipitates after adding Na2S·5H2O to NdF3 (a), SmF3 (b)-LiF-BeF2 molten salt
    EDS images of precipitates after adding Na2S·5H2O to EuF3-LiF-BeF2 molten salt
    S 2p XPS spectra of precipitate after adding Na2S∙5H2O to NdF3-LiF-BeF2
    Removal ratio comparison of two systems for RE elements (Nd, Ce, Sm, and Eu)
    Snapshots of distillation equipment (a) and quartz tube with nickel foil collection device (b)[28]
    Photograph of ThF4-LiF-BeF2 salt (a) and mixed molten salt after adding Na2S∙5H2O (b)
    XRD patterns of precipitates after adding Na2S·5H2O to ThF4-LiF-BeF2
    • Table 1. Removal ratios, oxygen and sulfur content for various Na2S5H2O contents at 600

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      Table 1. Removal ratios, oxygen and sulfur content for various Na2S5H2O contents at 600

      Na2S∙5H2O∶NdF3

      去除率R

      Removal ratio R / %

      氧含量

      Oxygen content / 10-6 g∙g-1

      硫含量

      Sulphur content / 10-6 g∙g-1

      1∶172.31 120403
      1.5∶178.91 8301 160
      2∶181.42 1191 275
      3∶188.92 5602 450
    • Table 2. Removal ratios of RE with REF3Na2S5H2O = 12 at 600 ℃

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      Table 2. Removal ratios of RE with REF3Na2S5H2O = 12 at 600 ℃

      样品

      Sample

      上层盐中RE3+的浓度 RE3+ concentration in salt / %(w/w)去除率 RRemoval ratio R / %
      反应前 Before reaction反应后 After reaction
      NdF3-LiF-BeF22.1510.398 181.4
      CeF3-LiF-BeF21.5410.338 078.0
      SmF3-LiF-BeF22.5010.996 260.1
      EuF3-LiF-BeF22.0520.271 586.2
      YF3-LiF-BeF21.197 30.347 171.0
      YbF3-LiF-BeF21.296 60.491 062.2
    • Table 3. Oxygen content in molten salt before and after reaction

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      Table 3. Oxygen content in molten salt before and after reaction

      样品

      Sample

      氧含量

      Oxygen content / 10-6 g∙g-1

      LiF-BeF2360
      CeF3-LiF-BeF2974
      CeF3-LiF-BeF2-Na2S∙5H2O1 621
      NdF3-LiF-BeF21 093
      NdF3-LiF-BeF2-Na2S∙5H2O2 119
      SmF3-LiF-BeF2625
      SmF3-LiF-BeF2-Na2S∙5H2O2 113
      EuF3-LiF-BeF2985
      EuF3-LiF-BeF2-Na2S∙5H2O2 095
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    Yujiao WANG, Yaxin QU, Haiying FU, Ming CHENG, Qiang DOU, Yu GONG. Separation of rare earth fission products from LiF-BeF2 molten salt by sulfide precipitation[J]. NUCLEAR TECHNIQUES, 2024, 47(1): 010302

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    Paper Information

    Category: Research Articles

    Received: Jul. 23, 2023

    Accepted: --

    Published Online: Mar. 7, 2024

    The Author Email: FU Haiying (付海英)

    DOI:10.11889/j.0253-3219.2024.hjs.47.010302

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