[1] [1] QUANG R D, PETITJEAN V, HOLLEBECQUE F, et al. Vitrification of HLW produced by uranium/molybdenum fuel reprocessing in cogema’s cold crucible melter［C］//WM’03 Conference, Tucson, AZ, 2003.

[5] [5] OJOVAN M I, LEE W E, KALMYKOV S N. Immobilisation of radioactive wastes in glass［C］// OJOVAN M I, LEE W E, KALMYKOV S N eds. An Introduction to Nuclear Waste Immobilisation. 3rd ed. Elsevier, 2019: 319-368.

[6] [6] SZUMERA M. Molybdenum modified phosphate glasses studied by 31P MAS NMR and Raman spectroscopy［J］. Spectrochim Acta A Mol Biomol Spectrosc, 2015, 137: 111-115.

[7] [7] CAMARA B, LUTZE W, LUX J. An Investigation on the valency state of molybdenum in glasses with and without fission products［C］// NORTHRUP C J N ed. Scientific Basis for Nuclear Waste Management. Boston, MA: Springer, 1980.

[8] [8] SUBCIK J, KOUDELKA L, MONER P, et al. Glass-forming ability and structure of ZnO-MoO3-P2O5 glasses［J］. J Non-Cryst Solids, 2010, 356: 2509-2516.

[9] [9] KHATTAK G D, SALIM M A, AL-HARTHI A S, et al. Structure of molybdenum-phosphate glasses by X-ray photoelectron spectroscopy (XPS)［J］. J Non-Cryst Solids, 1997, 212: 180-191.

[11] [11] CAURANT D, MAJRUS O. Glasses and glass-ceramics for nuclear waste immobilization［C］//POMEROY M ed. Encyclopedia of Materials: Technical Ceramics and Glasses. Elsevier, 2021: 762-789.

[12] [12] SHORT R J, HAND R J, HYATT N C, et al. Environment and oxidation state of molybdenum in simulated high level nuclear waste glass compositions［J］. J Nucl Mater, 2005, 340(2/3): 179-186.

[13] [13] TAURINES T, BOIZOT B. Synthesis of powellite-rich glasses for high level waste immobilization［J］. J Non-Cryst Solids, 2011, 357(14): 2723-2725.

[14] [14] BRINKMAN K, FOX K, MARRA J, et al. Single phase melt processed powellite (Ba,Ca)MoO4 for the immobilization of Mo-rich nuclear waste［J］. J Alloys Compd, 2013, 551: 136-142.

[15] [15] CAURANT D, MAJRUS O, FADEL E, et al. Structural investigations of borosilicate glasses containing MoO3 by MAS NMR and Raman spectroscopies［J］, J Nucl Mater, 2010, 396: 94-101.

[16] [16] MAGNIN M, SCHULLER S, MERCIER C, et al. Modification of molybdenum structural environment in borosilicate glasses with increasing content of boron and calcium oxide by 95Mo MAS NMR［J］. J Am Ceram Soc, 2011, 94(12): 4274-4282.

[17] [17] CHOUARD N, CAURANT D, MAJERUS O, et al. Effect of MoO3, Nd2O3, and RuO2 on the crystallization of soda-lime aluminoborosilicate glasses［J］. J Mater Sci, 2015, 50: 219-241.

[18] [18] CAURANT D, MAJRUS O, FADEL E, et al. Effect of molybdenum on the structure and on the crystallization of SiO2-Na2O-CaO-B2O3 glasses［J］. J Am Ceram Soc, 2007, 90(3): 774-783.

[20] [20] RAY C S, SAMARANAYAKE V A, MOHAMMADKHAH A, et al. Iron phosphate glass waste forms for vitrifying Hanford AZ102 low activity waste (LAW), part I: Glass formation model［J］. J Non-Cryst Solids, 2017, 458: 149-156.

[21] [21] FUKUI T, ISHINOMORI T, ENDO Y, et al. Iron phosphate glass as potential waste matrix for high-level radioactive waste［C］// WM‘03 Conference, Tucson, AZ, 2003.

[22] [22] BRIDGE B, PATEL N D. The elastic constants and structure of the vitreous system Mo-P-O［J］. J Mater Sci, 1986, 21: 1187-1205.

[23] [23] BAI J, HSU J, SANDINENI P, et al. The structure and properties of cesium loaded Mo-Fe-phosphate glasses［J］. J Non-Cryst Solids, 2019, 510: 121-129.

[24] [24] MOGUS-MILANKOVIC A, SANTIC A, GAJOVIC A, et al. Spectroscopic investigation of MoO3-Fe2O3-P2O5 and SrO-Fe2O3-P2O5 glasses. Part I［J］. J Non-Cryst Solids, 2003, 325(1-3): 76-84.

[25] [25] WANG Y, WANG F, ZHOU J, et al. Effect of molybdenum on structural features and thermal properties of iron phosphate glasses and boron-doped iron phosphate glasses［J］. J Alloys Compd, 2020, 826: 154225.

[26] [26] BINGHAM P A, HAND R J, HANNANT O M, et al. Effects of modifier additions on the thermal properties, chemical durability, oxidation state and structure of iron phosphate glasses［J］. J Non-Cryst Solids, 2009, 355: 1526-1538.

[27] [27] BROW R K, KIRKPATRICK R J, TURNER G L. Nature of alumina in phosphate glass: II, structure of sodium aluminophosphate glass［J］. J Am Ceram Soc, 1993, 76(4): 919-928.

[28] [28] BROW R K. Nature of alumina in phosphate glass: I, properties of sodium aluminophosphate glass［J］. J Am Ceram Soc, 1993, 76(4): 913-918.

[29] [29] MOGUS-MILANKOVIC A, SANTIC A, PAVIC L. Glasses: Phosphates［C］// POMEROY M ed. Encyclopedia of Materials: Technical Ceramics and Glasses. Elsevier, 2021: 580-590.

[30] [30] QIAN M, XUE T, FAN S, et al. Influence of ZrO2 content on the chemical durability and structure of P2O5-Fe2O3-Al2O3-Na2O-ZrO2 glass ceramics［J］. J Non-Cryst Solids, 2022, 582: 121446.

[31] [31] ZHANG L Y, LI H, HU L L. Statistical structure analysis of GeO2 modified Yb3+: Phosphate glasses based on Raman and FTIR study［J］. J Alloys Compd, 2017, 698: 103-113.

[32] [32] YADAV A K, SINGH P. A review of the structures of oxide glasses by Raman spectroscopy［J］. RSC Adv, 2015, 5: 67583-67609.

[33] [33] KUCZEK J, JELEN P, STOCH P, et al. Raman and Mssbauer studies of iron phosphate-silicate glasses［J］. J Mol Struct, 2018, 1170: 82-89.

[34] [34] STEFANOVSKY S V, STEFANOVSKY O I, KADYKO M I. FTIR and Raman spectroscopic study of sodium aluminophosphate and sodium aluminum-iron phosphate glasses containing uranium oxides［J］. J Non-Cryst Solids, 2016, 443: 192-198.

[35] [35] CHEN K, XIE S, IGLESIA E, et al. Structure and properties of zirconia-supported molybdenum oxide catalysts for oxidative dehydrogenation of propane［J］. J Catal, 2000, 189: 421-430.

[36] [36] PERSHINA S V, ANTONOV B D, LEONIDOV I I. Effect of MoO3 on structural, thermal and transport properties of lithium phosphate glasses［J］. J Non-Cryst Solids, 2021, 569: 120944.

[37] [37] BAI J, BROW R K, KIM C-W, et al. Redox effects on the structure and properties of Na-Mo-Fe-phosphate glasses［J］. J Non-Cryst Solids, 2021, 557: 120573.

[38] [38] MYSEN B O, FINGER L W, VIRGO D, et al. Curve-fitting of Raman spectra of silicate glasses［J］. Am Mineral, 1982, 67(7/8): 686-695.

[39] [39] MA L, BROW R K, CHOUDHURY A. Structural study of Na2O-FeO-Fe2O3-P2O5 glasses by Raman and Mssbauer spectroscopy［J］. J Non-Cryst Solids, 2014, 402: 64-73.

[40] [40] GRUENERT W, STAKHEEV A Y, FELDHAUS R, et al. Analysis of molybdenum(3d) XPS spectra of supported molybdenum catalysts: An alternative approach［J］. J Phys Chem, 1991, 95(3): 1323-1328.

[41] [41] ZATSEPIN D A, BOUKHVALOV D W, GAVRILOVE N V, et al. XPS and DFT analyses of the Pb 4f-Zn 3s and Pb 5d-O 2s overlapped ambiguity contributions to the final electronic structure of bulk and thin-film Pb-modulated zincite［J］. Appl Surf Sci, 2017, 405: 129-136.

[42] [42] KOCHUR A G, IVANOVA T M, SHCHUKAREV A V, et al. X-ray photoelectron Fe 3s and Fe 3p spectra of polynuclear trimethylacetate iron complexes［J］. J Electron Spectros Relat Phenomena, 2010, 180(1-3): 21-26.

[43] [43] MEKKI A, HOLLAND D, MCCONVILLE C F, et al. An XPS study of iron sodium silicate glass surfaces［J］. J Non-Cryst Solids, 1996, 208(3): 267-276.

[44] [44] CRIST B V. Handbook of Monochromatic XPS Spectra［M］. 1st ed. Wiley, 2000.

[45] [45] MASLAKOV K I, TETERIN Y A, STEFANOVSKY S V, et al. XPS study of uranium-containing sodium-aluminum-iron-phosphate glasses［J］. J Alloys Compd, 2017, 712: 36-43.

[46] [46] GISELA C, LUQUE J L F. Electrocatalysis of oxygen reduction at electrodeposited molybdenum phosphate-based films［J］. J Power Sources, 2012, 203: 57-64.

[47] [47] MA Y, LI Y, WANG E, et al. Synthesis, characterization and crystal structure of a new cobalt phosphomolybdate that contains ［(Mo16O32)Co16(H2O)18(PO4)6(HPO4)18］ wheels［J］. Transit Metal Chem, 2006, 31(2): 262-267.

[48] [48] BACH H, KRAUSE D. Analysis of the composition and structure of glass and glass ceramics［M］. Springer, 1999.

[49] [49] YAMASHITA T, HAYES P. Analysis of XPS spectra of Fe2+ and Fe3+ ions in oxide materials［J］. Appl Surf Sci, 2008, 254(8): 2441-2449.

[50] [50] WILLIAMS G L. 57Fe Mossbauer studies of phosphate-based glass systems［D］. United Kingdom: Sheffield Hallam University, 1990.

[51] [51] MARASINGHE G K, KARABULUT M, RAY C S, et al. Structural features of iron phosphate glasses［J］. J Non-Cryst Solids, 1997(222): 144-152.

[52] [52] BIH L, ABBAS L, NADIRI A, et al. Investigations of molybdenum redox phenomenon in Li2O-MoO3-P2O5 phosphate glasses［J］. J Mol Struct, 2008, 872(1): 1-9.