Chinese Journal of Lasers, Volume. 52, Issue 18, 1803005(2025)

Research Progress on Defects in KDP/DKDP Crystals for High‑Power Laser Facility (Invited)

Baoan Liu1,2, Mingxia Xu1,2, Lisong Zhang1,2, Yang Li1,2, Guodong Lei1,2, Zhongjun Cao1,2, Hongkai Ren1,2, Xinguang Xu1,2, and Xun Sun1,2、*
Author Affiliations
  • 1Institute of Crystal Materials, Shandong University, Jinan 250100, Shandong , China
  • 2State Key Laboratory of Crystal Materials, Shandong University, Jinan 250100, Shandong , China
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    Figures & Tables(9)
    Morphologies and size distribution of bulk damage sites in DKDP crystals[13]. (a) Bulk damage sites in DKDP crystals observed parallel to beam direction; (b) distribution of diameters of central cavities of damage sites; (c) scanning electron microscope (SEM) image of central cavities of damage sites
    Wavelength dependence of laser damage threshold of DKDP crystal [16]
    Electron paramagnetic resonance spectra and linear absorption spectra of Cr doped KDP crystals[27]. (a)(b) Electron paramagnetic resonance spectra of KDP: Cr3+crystals at room temperature; (c) linear absorption spectra of KDP: Cr3+ measured experimentally
    Images of cross section of KDP crystal[30]. (a) Light scattering image; (b) fluorescence image under 351 nm laser excitation before irradiation; (c) plasma emission image during single-pulse irradiation; (d) light scattering image after 355 nm pulse irradiation
    Impact of “hair” inclusion on laser induced damage of DKDP crystal[50]. (a)(b) In-situ dark-field scattering images of crystal when it is damaged; (c)(d) morphologies of damage points in “hair” inclusion test area
    Differential charge diagrams of KDP crystals in different defect systems[58]. (a) Oxygen vacancies (VO2+); (b) VO2++ potassium vacancies (VK-) + hydrogen vacancies (VH-); (c) VO2++ 2VH-; (d) VO2++2VK-
    Partial densities of states (PDOS) of defect clusters in pristine KDP and KDP crystals[58]
    Partial densities of states of KDP, K2H2P2O7 , and KPO3 crystals[59]
    • Table 1. Different types of defects in KDP/DKDP crystals and their formation mechanisms

      View table

      Table 1. Different types of defects in KDP/DKDP crystals and their formation mechanisms

      Type of defectsDimensionFormation mechanism
      Point defectsSeveral ÅLattice misarrangement, intrinsic defects, impurities in solution (raw materials and intentionally doped impurities), and dissolution of growth tank material
      Defect clusternmCharge compensation and point defect (migration, diffusion, reaction) aggregation
      InclusionSub-micron to tens of micrometersParticulates and solution inclusion
      Dislocation and low angle boundaryTens of micrometers to several hundred micrometersComing out from seed or generating at inclusions during growth, and changes in dislocation structure or growth step
      Growth boundary and growth striationMacro dimensionAdjacent growth hills, sectorial boundaries, and fluctuations in growth conditions (supersaturation and temperature)

      Residual stress and

      deuterium inhomogeneity

      Macro dimensionMicroscopic defects, thermal stress, fluctuations in growth conditions, etc.
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    Baoan Liu, Mingxia Xu, Lisong Zhang, Yang Li, Guodong Lei, Zhongjun Cao, Hongkai Ren, Xinguang Xu, Xun Sun. Research Progress on Defects in KDP/DKDP Crystals for High‑Power Laser Facility (Invited)[J]. Chinese Journal of Lasers, 2025, 52(18): 1803005

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    Paper Information

    Category: Materials

    Received: Jun. 16, 2025

    Accepted: Jul. 7, 2025

    Published Online: Sep. 13, 2025

    The Author Email: Xun Sun (sunxun@sdu.edu.cn)

    DOI:10.3788/CJL250955

    CSTR:32183.14.CJL250955

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