[3] [3] Battersby A R, McDonald E. Origin of the pigments of life: the type-III problem in porphyrin biosynthesis［J］. Accounts of Chemical Research, 1979, 12(1): 14-22.

[4] [4] Biesaga M, Pyrzyńska K, Trojanowicz M. Porphyrins in analytical chemistry. A review［J］. Talanta, 2000, 51(2): 209-224.

[5] [5] Senge M O, Fazekas M, Notaras E G A, et al. Nonlinear optical properties of porphyrins［J］. Advanced Materials, 2007, 19(19): 2737-2774.

[6] [6] Liddell P A, Gervaldo M, Bridgewater J W, et al. Porphyrin-based hole conducting electropolymer［J］. Chemistry of Materials, 2007, 20(1): 135-142.

[7] [7] Choi B G, Ko S Y, Nam W W, et al. Recyclable porphyrin catalyst with core-shell nanostructure［J］. Bulletin of the Korean Chemical Society, 2005, 26(11): 1819-1822.

[8] [8] Ho C M, Zhang J L, Zhou C Y, et al. A water-soluble ruthenium glycosylated porphyrin catalyst for carbenoid transfer reactions in aqueous media with applications inbioconjugation reactions［J］. Journal of the American Chemical Society, 2010, 132(6): 1886-1894.

[9] [9] Le Maux P, Simonneaux G. First enantioselective iron-porphyrin-catalyzed sulfide oxidation with aqueous hydrogen peroxide［J］. Chemical Communications, 2011, 47(24): 6957-6959.

[10] [10] Martin R B, Li H, Gu L, et al. Superior optical limiting performance of simple metalloporphyrin derivatives［J］. Optical Materials, 2005, 27(8): 1340-1345.

[11] [11] McEwan K, Lewis K, Yang G Y, et al. Synthesis, characterization, and nonlinear optical study of metalloporphyrins［J］. Advanced Functional Materials, 2003, 13(11): 863-867.

[12] [12] Li L L, Diau E W G. Porphyrin-sensitized solar cells［J］. Chemical Society Reviews, 2013, 42(1): 291-304.

[13] [13] O′regan B, Grtzel M. A low-cost, high-efficiency solar cell based on dye-sensitized colloidal TiO2 films［J］. Nature, 1991, 353(6346): 737-740.

[14] [14] Cai L, Moehl T, Moon S J, et al. 4, 9-Dihydro-4, 4, 9, 9-tetrahexyl-s-indaceno ［1, 2-b: 5, 6-b′］ dithiophene as a π-spacer of donor-π-acceptor dye and its photovoltaic performance with liquid and solid-state dye-sensitized solar cells［J］. Organic letters, 2013, 16(1): 106-109.

[15] [15] Chaurasia S, Hsu C Y, Chou H H, et al. Synthesis, optical and electrochemical properties of pyridal ［2, 1, 3］ thiadiazole based organic dyes for dye sensitized solar cells［J］. Organic Electronics, 2014, 15(2): 378-390.

[16] [16] Namuangruk S, Sirithip K, Rattanatwan R, et al. Theoretical investigation of the charge-transfer properties in different meso-linked zinc porphyrins for highly efficient dye-sensitized solar cells［J］. Dalton Transactions, 2014, 43(24): 9166-9176.

[17] [17] Hsieh C P, Lu H P, Chiu C L, et al. Synthesis and characterization of porphyrin sensitizers with various electron-donatingsubstituents for highly efficient dye-sensitized solar cells［J］. Journal of Materials Chemistry, 2010, 20(6): 1127-1134.

[18] [18] Lu H P, Tsai C Y, Yen W N, et al. Control of dye aggregation and electron injection for highly efficient porphyrin sensitizers adsorbed on semiconductor films with varying ratios of coadsorbate［J］. The Journal of Physical Chemistry C, 2009, 113(49): 20990-20997.

[19] [19] Wu S L, Lu H P, Yu H T, et al. Design and characterization of porphyrin sensitizers with a push-pull framework for highly efficient dye-sensitized solar cells［J］. Energy & Environmental Science, 2010, 3(7): 949-955.

[20] [20] Matsuzawa N N, Ishitani A, Dixon D A, et al. Time-dependent density functional theory calculations of photoabsorption spectra in the vacuum ultraviolet region［J］. The Journal of Physical Chemistry A, 2001, 105(20): 4953-4962.

[21] [21] BecNe A D. Densityüfunctional thermochemistry. III. The role of exact exchange［J］.The Journal of Chemical Physics, 1993, 98: 5648-5652.

[22] [22] Yanai T, Tew D P, Handy N C. A new hybrid exchange-correlation functional using the Coulomb-attenuating method (CAM-B3LYP) ［J］. Chemical Physics Letters, 2004, 393(1): 51-57.

[23] [23] Dennington R, Keith T, Millam J. GaussView, version 5. Semichem Inc., Shawnee Mission, KS, 2009.

[24] [24] Frisch M, Trucks GW, Schlegel HB, et al. Gaussian 09, revision a. 02, Gaussian Inc., Wallingford, CT, 2009.

[25] [25] Zhang Y H, Zhao W, Jiang P, et al. Structural parameters and vibrational spectra of a series of zinc meso-phenylporphyrins: A DFT and experimental study［J］. Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy, 2010, 75(2): 880-890.