Journal of Radiation Research and Radiation Processing, Volume. 42, Issue 6, 060210(2024)

Reaction rate constant of phosphate esters with hydroxyl radicals investigated using fluorescence probe method

Yunjia YANG, Yiqian WU, Jing PENG*, Maolin ZHAI*, and Jiuqiang LI
Author Affiliations
  • Radiochemistry and Radiation Chemistry Key Laboratory of Fundamental Science,Beijing National Laboratory for Molecular Sciences,College of Chemistry and Molecular Engineering,Peking University,Beijing 100871,China
  • show less
    References(24)

    [1] TANG Jia, WENG Hanqin, HE Hui et al. Radiation chemistry in spent fuel reprocessing Ⅰ.Radiation stability of extractant[J]. Journal of Nuclear and Radiochemistry, 41, 115-132(2019).

    [2] Zhang H, Ao Y Y, Wang Y et al. Effect of radiolysis of TODGA on the extraction of TODGA/n-dodecane toward Eu(III): an experimental and DFT study[J]. Nuclear Science and Techniques, 34, 48(2023).

    [3] Geist A, Adnet J M, Bourg S et al. An overview of solvent extraction processes developed in Europe for advanced nuclear fuel recycling,part 1—heterogeneous recycling[J]. Separation Science and Technology, 56, 1866-1881(2021).

    [4] Li F Z, Qin Y L, Liao W et al. Gamma and beta radiolysis of tri-iso-amyl phosphate: degradation of tri-iso-amyl phosphate and formation of di-iso-amyl phosphoric acid[J]. Radiation Physics and Chemistry, 199, 110354(2022).

    [5] Brodda B G, Heinen D. Solvent performance in THTR nuclear fuel reprocessing. part II: on the formation of dibutyl phosphoric acid by radiolytic and hydrolytic degradation of the TBP-n-paraffin extractant[J]. Nuclear Technology, 34, 428-437(1977).

    [6] Foley S, Rotureau P, Pin S et al. Radiolysis of confined water: production and reactivity of hydroxyl radicals[J]. Angewandte Chemie International Edition, 44, 110-112(2005).

    [7] Zhang J, Nosaka Y. Quantitative detection of OH radicals for investigating the reaction mechanism of various visible-light TiO2 photocatalysts in aqueous suspension[J]. The Journal of Physical Chemistry C, 117, 1383-1391(2013).

    [8] Petersson F, Jonsson M. The reactivity of hydroxyl radicals toward boric acid as a function of pH[J]. The Journal of Physical Chemistry A, 128, 7593-7600(2024).

    [9] BAI Ge, CHEN Maoqing, CAI Nan et al. Advances on determination methods of free radicals in advanced oxidation processes[J]. Journal of Instrumental Analysis, 40, 1109-1118(2021).

    [10] De-Nasri S J, Nagarajan S, Robertson P K J et al. Quantification of hydroxyl radicals in photocatalysis and acoustic cavitation: utility of coumarin as a chemical probe[J]. Chemical Engineering Journal, 420, 127560(2021).

    [11] Milanović Ž, Dimić D, Antonijević M et al. Influence of acid-base equilibria on the rate of the chemical reaction in the advanced oxidation processes: coumarin derivatives and hydroxyl radical[J]. Chemical Engineering Journal, 453, 139648(2023).

    [12] Fan Y F, Wu Y, Hou J et al. Coumarin-based near-infrared fluorogenic probes: recent advances,challenges and future perspectives[J]. Coordination Chemistry Reviews, 480, 215020(2023).

    [13] Dong X Y, Tian Y, Wang F Q et al. Gold-nanoparticle-enhanced radio-fluorogenic hydrogel sensor for low radiation doses in clinical radiotherapy[J]. Polymers, 14, 4841(2022).

    [14] Mincher B J, Modolo G, Mezyk S P. Review article: the effects of radiation chemistry on solvent extraction: 1. Conditions in acidic solution and a review of TBP radiolysis[J]. Solvent Extraction and Ion Exchange, 27, 1-25(2009).

    [15] Mincher B J, Modolo G, Mezyk S P. Review article: the effects of radiation chemistry on solvent extraction: 2. A review of fission-product extraction[J]. Solvent Extraction and Ion Exchange, 27, 331-353(2009).

    [16] Vasudeva Rao P R, Kolarik Z. A review of third phase formation in extraction of actinides by neutral organophosphorus extractants[J]. Solvent Extraction and Ion Exchange, 14, 955-993(1996).

    [17] Hasan S H, Shukla J P. Tri-iso-amyl phosphate (TAP): an alternative extractant to tri-butyl phosphate (TBP) for reactor fuel reprocessing[J]. Journal of Radioanalytical and Nuclear Chemistry, 258, 563-573(2003).

    [18] LIU Chunxia, LI Ruifen, HE Shuhua et al. Extraction behavior of U(Ⅵ) and Th(Ⅳ) by tri-iso-amyl phosphate and tri-sec-butyl phosphate[J]. Journal of Nuclear and Radiochemistry, 36, 282-288(2014).

    [19] Sun J Y, Ao Y Y, Wang Y et al. Effect of radiolysis and radiolytic products of tri-iso-amyl phosphate on the extraction behavior of uranium[J]. Journal of Radioanalytical and Nuclear Chemistry, 332, 4089-4099(2023).

    [20] Que X Y, Li S X, Hu Y et al. Fluorescence spectroscopy study on the reaction of hydroxyl radicals and hydrated electrons in MXene suspension[J]. The Journal of Physical Chemistry C, 126, 10703-10712(2022).

    [21] Liu J, Wu L P, Kümmel S et al. Carbon and hydrogen stable isotope analysis for characterizing the chemical degradation of tributyl phosphate[J]. Chemosphere, 212, 133-142(2018).

    [22] Singh T S, Madhava Rao B S, Mohan H et al. A pulse radiolysis study of coumarin and its derivatives[J]. Journal of Photochemistry and Photobiology A: Chemistry, 153, 163-171(2002).

    [23] Sreenivasulu B, Suresh A, Rajeswari S et al. Physicochemical properties and radiolytic degradation studies on tri-iso-amyl phosphate (TiAP)[J]. Radiochimica Acta, 105, 249-261(2017).

    [24] Mincher B J, Mezyk S P, Martin L R. A pulse radiolysis investigation of the reactions of tributyl phosphate with the radical products of aqueous nitric acid irradiation[J]. The Journal of Physical Chemistry A, 112, 6275-6280(2008).

    Tools

    Get Citation

    Copy Citation Text

    Yunjia YANG, Yiqian WU, Jing PENG, Maolin ZHAI, Jiuqiang LI. Reaction rate constant of phosphate esters with hydroxyl radicals investigated using fluorescence probe method[J]. Journal of Radiation Research and Radiation Processing, 2024, 42(6): 060210

    Download Citation

    EndNote(RIS)BibTexPlain Text
    Save article for my favorites
    Paper Information

    Category: RADIATION CHEMISTRY

    Received: Oct. 26, 2024

    Accepted: Nov. 24, 2024

    Published Online: Jan. 15, 2025

    The Author Email: Jing PENG (彭静), Maolin ZHAI (翟茂林)

    DOI:10.11889/j.1000-3436.2024-0091

    Topics