Laser & Optoelectronics Progress, Volume. 56, Issue 10, 101602(2019)

Influence of Ferrous Metal Chloride on Photoluminescence Properties of Fully-Inorganic Lead Halide Perovskite Nanocrystals

Jiapei Hu, Chao Wu, Junqi Weng, Yihui Wang, and Xianghong He*
Author Affiliations
  • School of Chemistry and Environmental Engineering, Jiangsu University of Technology, Changzhou, Jiangsu 213001, China
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    Figures & Tables(5)
    XRD patterns of samples. (a) CsPbBr3 and as-obtained samples prepared by ferrous metal chlorides as chlorine sources (from top to bottom, NiCl2, CoCl2, FeCl2, and FeCl3 used as chlorine sources); (b) local patterns
    TEM and HR-TEM images of nanocrystals. (a) TEM image of CsPbBr3; (b) HR-TEM image of CsPbBr3; (c) TEM image of CsPbCl3 prepared using FeCl3 as chlorine source; (d) HR-TEM image of CsPbCl3 prepared using FeCl3 as chlorine source; (e) TEM image of CsPbCl3 prepared using FeCl2 as chlorine source; (f) HR-TEM image of CsPbCl3 prepared using FeCl2 as chlorine source; (g) TEM image of CsPbCl3 prepared using CoCl2 as chlorine source; (h) HR-TEM image of CsPbCl3 prepared using CoCl2 as chlorine source; (
    UV-vis absorption spectrum, emission spectrum and digital photographs of CsPbBr3 nanocrystals. (a) UV-vis absorption and emission spectra; (b) digital photograph without UV light irradiation; (c) digital photograph with 365 nm UV light irradiation
    UV-vis absorption spectra, emission spectra and digital photographs of as-obtained nanocrystals using different chlorine sources. (a) UV-vis absorption spectra; (b) emission spectra; (c) digital photographs without UV light irradiation (from left to right, CoCl2, FeCl2, FeCl3, and NiCl2 used as chlorine sources); (d) digital photographs with 365 nm UV light irradiation (from left to right, CoCl2, FeCl2, FeCl3, and NiCl2 used as chlorine sources)
    • Table 1. Chemical compositions of samples (atomic fraction, %)

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      Table 1. Chemical compositions of samples (atomic fraction, %)

      ConditionCsPbCl
      NiCl2 as Cl- source19.720.360.0
      CoCl2 as Cl- source19.120.660.3
      FeCl2 as Cl- source19.320.260.5
      FeCl3 as Cl- source19.920.459.7
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    Jiapei Hu, Chao Wu, Junqi Weng, Yihui Wang, Xianghong He. Influence of Ferrous Metal Chloride on Photoluminescence Properties of Fully-Inorganic Lead Halide Perovskite Nanocrystals[J]. Laser & Optoelectronics Progress, 2019, 56(10): 101602

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    Paper Information

    Category: Materials

    Received: Nov. 27, 2018

    Accepted: Dec. 13, 2018

    Published Online: Jul. 4, 2019

    The Author Email: Xianghong He (hexh@jsut.edu.cn)

    DOI:10.3788/LOP56.101602

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