Journal of Infrared and Millimeter Waves, Volume. 40, Issue 4, 439(2021)

Progress in carbon nanotube films based photodetectors

Lu-Han YANG1,2, Jia-Zhen ZHANG2, Huang XU2, Jie ZHOU2,3, Han-Xun QIU1、*, and Gang CHEN2、*
Author Affiliations
  • 1School of Materials Science and Engineering, University of Shanghai for Science and Technology, Shanghai 200093,China
  • 2State Key Laboratory of Infrared Physics, Shanghai Institute of Technical Physics, Chinese Academy of Sciences, Shanghai 200083,China
  • 3School of Mathematics and Physics, Shanghai Normal University, Shanghai 200234,China
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    Figures & Tables(18)
    (a)horizontal lift, (b)vertical immersion[48]
    Schematic diagram of carbon nanotube films prepared by different angle stretching [52]
    (a)device diagram, (b) reaction photos of hollow carbon nanotube cylinders blown from carbon nanotubes, (c)the entire carbon nanotube film removed from the substrate, (d)cut small pieces of carbon nanotube film[57]
    (a)-(c) Macro and micro morphology of the prepared carbon nanotube film, (d) a schematic diagram of a device designed to synthesize, deposit, and transfer SWCNTS films, (e)carbon nanotube film on simple substrate[63]
    Fabrication and characterization of wafer-scale monodomain films of aligned CNTs (a) A CNT suspension goes through a standard vacuum filtration system. For spontaneous CNT alignment to occur, the filtration speed must be kept low and the CNTs must be well dispersed in the suspension, (b) A wafer-scale, uniform CNT film is formed on the filter membrane, (c)Optical image of the produced film after being transferred to a transparent substrate by dissolving the filter membrane, (d)a high-resolution SEM image, (e) and a top-view TEM image[76]
    Schematic diagram of layer by layer self-assembly of MWCNTs with negative charge[85]
    (a)-(c) Carbon nanotube optical and SEM microscopic images, (d)device preparation process and schematic diagram,(e)schematic diagram of device testing,[91]
    (a)-(b) are the respective current-voltage characteristics of bolometer and PTE devices under darkness and illuminated conditions.
    Schematics of the (a) millimeter-scale and (b) micrometer-scale CNT-based photodetector [96]
    (a) suspended SWCNTs films with a thickness of 140nm, Al/Au electrode gap is 3.9mm; (b) photothermoeletric detector with p-n doping [110]
    (a) The current-voltage characteristics of the photoconductive detector with or without light, (b) the current-voltage characteristics of the photodiode detector with or without light, (c) the current-voltage characteristics of the phototransistor with or without light
    Flexible and fully transparent photodetector based on porphyrin-SWNT-graphene heterostructure. (a)Schematic showing the fabricationof graphene electrodes, SWNT networks, and porphyrin layer on plastic substrate, (b)SEM image of boundary between graphene electrode and PET substrate after porphyrin functionalization. The SWNTs, covered by porphyrin molecules, are coated uniformly on the both graphene and PETsubstrate, (c)-(d) Photographs of as-fabricated photodetector exhibiting high transparency and flexibility[137]
    (a) Schematic diagram of graphene/s-SW CNTs cross-shaped photodiode, (b) optical image, (c) Raman spectroscopy of s-SWCNT film in radial stretching mode before and after, (d) graphene/s-SWCNT AFM image of film overlap area[138]
    (a) Schematic diagram of graphene s-SWCNTs heterostructure photocell and test circuit, (b) optical image of AS manufacturing device[151]
    Schemes for the fabrication of the (PEA)2SnI4/semi-CNT hybrid TFTs[166]
    • Table 1. Summary of Carbon nanotube film -based bolometric and PTE photodetectors with key device parameters from 2015to 2020

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      Table 1. Summary of Carbon nanotube film -based bolometric and PTE photodetectors with key device parameters from 2015to 2020

      材料响应率响应时间波长/频率
      Aligned swcnt film922.5 V/W0.11.39-3.11 THZ
      Aligned swcnt film1130.028 A/W≈32 μs0.66-3.3 μm
      Aligned swcnt film1142.5 V/W0.1 s1.39-3.11 THZ
      M-swcnt/thymine103252 V/W0.8-1.6 ms10.6 μm
      VO2/swcnts1070.017 A/W0.28 s0.8-2.5 μm
      Suspended s-swcnts960.58 A/W150 μs10 THZ
      Swcnt film95N/AN/A0.66-1.8 μm
      Aligned swcnt film115N/AN/A2.5-25 μm
    • Table 2. Summary of Carbon nanotube film photovoltaic detectors from 2015 to 2020

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      Table 2. Summary of Carbon nanotube film photovoltaic detectors from 2015 to 2020

      材料响应率/(A/W)比探测率/(cmHz1/2W-1波长/μm

      S-swcnt/CO/PC71BM121

      Swcnts/SiO2132

      Swcnt film133

      Graphene/s-SWCNTfilm135

      Mwcnts/n-Si137

      Swcnts/NDIDPP134

      Swcnts/CH3NH3PbI3124

      0.25

      N/A

      N/A

      1.75

      N/A

      0.15∼0.4

      0.027~0.065

      0.9×1012

      N/A

      N/A

      N/A

      N/A

      2~6×1012

      1.2~3.8×1012

      0.86

      0.85∼1.2

      1.65

      0.78∼0.85

      0.6∼0.8

      0.3∼0.8

      0.4∼1.2

    • Table 3. Summary of Carbon nanotube film photoconductive detectors and phototransistors from 2015 to 2020

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      Table 3. Summary of Carbon nanotube film photoconductive detectors and phototransistors from 2015 to 2020

      材料响应率/(A/W)比探测率/(cmHZ1/2w-1波长/μm

      Swcnt/SGR150

      Graphene/s-SWCNT film151

      Swcnt/n-si149

      Swcnt thin film/C60153

      Swcnts/CH3NH3PbI3155

      Swcnt/SLG158

      Swcnt/graphene160

      Swcnt/PBSQDs164

      Swcnts/CH3NH3PbI3-xClx/PBSQDs165

      Swcnts/(PEA)2SnI4166

      CsBi3I10/SWNTs167

      3000

      78

      N/A

      97.5

      7.7x105

      0.209

      50

      353.4

      0.5~0.35

      6.3×104

      6.0×104

      N/A

      N/A

      N/A

      109

      N/A

      4.8×1010

      N/A

      7.1×1010

      1.4~0.9×1011

      1.12×1017

      2.46×1014

      0.38~0.77

      0.405~1.064

      0.532

      1~1.4

      0.52

      0.4~1.1

      0.4~1.2

      1.55

      0.5~1.3

      0.6~0.8

      0.74~0.76

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    Lu-Han YANG, Jia-Zhen ZHANG, Huang XU, Jie ZHOU, Han-Xun QIU, Gang CHEN. Progress in carbon nanotube films based photodetectors[J]. Journal of Infrared and Millimeter Waves, 2021, 40(4): 439

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    Paper Information

    Category: Research Articles

    Received: Nov. 17, 2020

    Accepted: --

    Published Online: Sep. 9, 2021

    The Author Email: Han-Xun QIU (hxqiu@usst.edu.cn), Gang CHEN (hxqiu@usst.edu.cn)

    DOI:10.11972/j.issn.1001-9014.2021.04.003

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