Laser & Optoelectronics Progress, Volume. 57, Issue 9, 091601(2020)

Ultrasensitive Biochemical Detection by Employing Two-Dimensional Ti3C2Tx MXene Nanosheets

Caiyan Lu1, Yongping Li1, Yufeng Yuan2、**, and Junxian Liu1、*
Author Affiliations
  • 1College of Physical Science and Technology, Guangxi Normal University, Guilin, Guangxi 541004, China
  • 2College of Physics and Optoelectronic Engineering, Shenzhen University, Shenzhen, Guangdong 518061, China
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    Figures & Tables(9)
    Schematic of SPR sensor enhanced by two-dimensional Ti3C2Tx MXene nanosheet
    For the BAK1 prism/35 nm silver film/Ti3C2Tx MXene/monolayer graphene hybrid configuration, the calculated sensing performance by changing the number of Ti3C2Tx MXene layers when the excitation wavelength is 632.8 nm and the sensing medium is deionized water with the refractive index of 1.333. (a) Reflectivity; (b) phase
    SPR phase and reflectivity curves generated by the coupling BAK1 prism/35 nm silver film/3-layer Ti3C2Tx MXene/monolayer graphene when the excitation wavelength is 632.8 nm, and the sensing medium is deionized water with the refractive index of 1.333
    For the coupling BAK1 prism/silver film/Ti3C2Tx MXene/monolayer graphene SPR configuration, sensing performance changed with thicknesses of silver film and number of Ti3C2Tx MXene layers at Δnbio=0.0012 RIU when the excitation wavelength is 632.8 nm. (a) Phase difference; (b) angle deflection
    Curves of phase difference changed with refractive index of medium by varying different thicknesses of silver film in the coupling BAK1 prism/silver film/Ti3C2Tx MXene/monolayer graphene SPR configuration when the excitation wavelength is 632.8 nm. (a) 30 nm; (b) 35 nm; (c) 40 nm; (d) 45 nm; (e) 50 nm; (f) 55 nm
    Simulated results at the sensing interface between Ti3C2Tx MXene and graphene. (a) Distribution of electric field intensity; (b) evanescent decay curve of electric field
    Comparison of the SPR sensing performances for different structures when the excitation wavelength is 632.8 nm
    • Table 1. Refractive indexes of SF11, BAF10, BAK1, BK7, gold film, and silver film

      View table

      Table 1. Refractive indexes of SF11, BAF10, BAK1, BK7, gold film, and silver film

      λ /nmRefractive index
      AuAgSF11BAF10BAK1BK7
      5320.5438+2.2309i0.0540+3.4290i1.79481.67471.57581.5195
      632.81.7231+4.7557i0.0563+4.2760i1.77861.66711.57041.5151
      7850.1489+4.7830i0.0345+5.4581i1.76551.66051.56571.5111
      9800.2178+6.3201i0.0400+6.9264i1.75661.65551.56201.5078
      15500.0344+5.4581i0.1445+11.3660i1.74341.64691.55521.5007
    • Table 2. Results of optimized SPR sensing performance

      View table

      Table 2. Results of optimized SPR sensing performance

      λ /nmMetalPrismdmetal /nmNumberof MXenelayersθSPR /(°)ΔθSPR /(°)nbio=0.001)Δφd /(°)Sp /[(°)/RIU]FWTM /(°)Rmin
      Δnbio=10-6Δnbio=0.0012
      1550AuBK730264.000.2680.0001106.168.85×1040.09744.51×10-7
      980AuSF1133452.010.0610.443380.687.17×1040.41154.08×10-5
      785AuSF1133553.890.0240.509688.017.33×1040.29094.74×10-5
      632.8AuBAK140237.000.0271.80543.923.27×1030.43804.77×10-7
      532AuSF1130559.460.0052.6198108.359.03×1040.08202.65×10-7
      1550AgBAF1036254.800.6360.105012.641.05×1040.09905.22×10-5
      980AgBAK131561.600.0882.655599.228.27×1040.09841.73×10-6
      785AgBAF1030557.840.0420.903889.217.43×1040.09793.95×10-6
      632.8AgBAK135365.270.12135.0396110.559.21×1040.09693.48×10-9
      532AgBAK150066.840.1202.1918100.298.36×1040.09666.81×10-6
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    Caiyan Lu, Yongping Li, Yufeng Yuan, Junxian Liu. Ultrasensitive Biochemical Detection by Employing Two-Dimensional Ti3C2Tx MXene Nanosheets[J]. Laser & Optoelectronics Progress, 2020, 57(9): 091601

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    Paper Information

    Category: Materials

    Received: Jul. 3, 2019

    Accepted: Sep. 12, 2019

    Published Online: May. 6, 2020

    The Author Email: Yufeng Yuan (yfyuan@szu.edu.cn), Junxian Liu (jxliu@mailbox.gxnu.edu.cn)

    DOI:10.3788/LOP57.091601

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