Acta Photonica Sinica, Volume. 52, Issue 2, 0216001(2023)

Preparation and Luminescent Properties of Red-emitting Y6TeO12:Eu3+ Phosphor

Rongqing LI, Weiwei ZHOU, Yue TONG*, Qinghua ZHENG, Zhaocheng LV, Wang ZHAO, Zhengrong XIA, and Fangfang LIU
Author Affiliations
  • School of Electrical Engineering,Huainan Normal University,Huainan 232038,China
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    Figures & Tables(12)
    XRD patterns,rietveld refinement and crystal structure schematic diagram of(Y0.7)6TeO12:0.3Eu3+ phosphor
    SEM image and grain size distribution of(Y0.7)6TeO12:0.3Eu3+ phosphor
    Diffuse reflection spectra of(Y0.7)6TeO12:0.3Eu3+ phosphors. The inset presents curves for[F(R)hn]1/2 versus hn
    Excitation(left black line,λem=632 nm)and emission(right red line,λex=393 n m)spectra of(Y0.7)6TeO12:0.3Eu3+ phosphors
    Emission spectra of(Y1-x)6TeO12:xEu3+ with different doping concentrations(x=0.1~0.5,λex=393 nm),the inset shows the relationship between integral luminescence intensity and doping concentrations x
    The relationship between lg(I/x)and lg x of integral luminescence intensity I and doping concentrations x
    Emission spectra of(Y0.7)6TeO12:0.3Eu3+ phosphors at different temperatures(the inset shows the relationship between ln[I0/IT-1]and 1/(kBT))
    Decay curves of(Y1-x)6TeO12:xEu3+ phosphors
    Electroluminescent spectrum,relevant chromaticity coordinates and photographs of the fabricated red LED
    • Table 1. The refined atomic parameters of(Y0.76TeO12:0.3Eu3+ phosphor

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      Table 1. The refined atomic parameters of(Y0.76TeO12:0.3Eu3+ phosphor

      AtomWyckoff positionSite symmetryx/ay/bz/cSite occupancy
      Te13aS60001
      Eu118fC10.253 30.211 00.354 60.3
      Y118fC10.253 30.211 00.354 60.7
      O118fC10.183 40.142 20.109 21
      O218fC10.193 50.968 60.401 41
    • Table 2. Judd-Ofelt analysis of(Y0.76TeO12:0.3Eu3+

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      Table 2. Judd-Ofelt analysis of(Y0.76TeO12:0.3Eu3+

      Wavelength λ/nmRadiative transition rate A/s-1Radiative lifetime τr/μsMeasured lifetime τf/μsQuantum efficiency η
      57714.61 122.1813.272.5%
      588100.5
      632620.8
      66126.5
      725128.8
      Ω2=10.2×10-20 cm2Ω4=4.3×10-20 cm2
    • Table 3. Luminescence properties comparison of some Eu3+ activated phosphors

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      Table 3. Luminescence properties comparison of some Eu3+ activated phosphors

      PhosphorSintered temperature /℃Asymmetric ratioLuminescence lifetimes /μsActivation energy /eVReference
      Sr1.5Na0.25MgTeO6:0.25Eu3+1 1007.47-0.27024
      Ba0.9LaLiTeO6:0.1Eu3+8004.11550-17
      La1.6ZnTiO6:0.4Eu3+1 2003.105440.1933
      LiLa0.7MgWO6:0.3Eu3+1 20010.04500.22525
      Ca2Lu0.6TaO6:0.4Eu3+1 500-5800.2421
      Y0.5Lu0.5NbO4:5%Eu3+1 4505.02650-18
      Ca2La0.5SbO6:0.5Eu3+1 500-9270.21128
      BaLa0.7MgNbO6:0.3Eu3+1 45012-0.27029
      CaLa0.5MgSbO6:0.5Eu3+1 4505.90-0.17319
      (Y0.76TeO12:0.3Eu3+1 2006.3388130.196 9This work
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    Rongqing LI, Weiwei ZHOU, Yue TONG, Qinghua ZHENG, Zhaocheng LV, Wang ZHAO, Zhengrong XIA, Fangfang LIU. Preparation and Luminescent Properties of Red-emitting Y6TeO12:Eu3+ Phosphor[J]. Acta Photonica Sinica, 2023, 52(2): 0216001

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    Paper Information

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    Received: Aug. 21, 2022

    Accepted: Oct. 14, 2022

    Published Online: Mar. 28, 2023

    The Author Email: Yue TONG (22311264@qq.com)

    DOI:10.3788/gzxb20235202.0216001

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