Acta Physica Sinica, Volume. 69, Issue 9, 090701-1(2020)

Calibration source for OH radical based on synchronous photolysis

Feng-Yang Wang1,2, Ren-Zhi Hu1、*, Pin-Hua Xie1,2,3,4、*, Yi-Hui Wang1,2, Hao Chen5, Guo-Xian Zhang1,2, and Wen-Qing Liu1,2,3,4
Author Affiliations
  • 1Key Laboratory of Environmental Optics and Technology, Anhui Institute of Optics and Fine Mechanics, Chinese Academy of Sciences, Hefei 230031, China
  • 2University of Science and Technology of China, Hefei 230026, China
  • 3CAS Center for Excellence in Regional Atmospheric Environment, Institute of Urban Environment, Chinese Academy of Sciences, Xiamen 361000, China
  • 4University of Chinese Academy of Sciences, Beijing 100049, China
  • 5College of Mechanical Engineering, Suzhou University of Science and Technology, Suzhou 215009, China
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    Figures & Tables(9)
    Schematic diagram of laminar distribution in the flow tube
    System diagram of synchronous photolysis of H2O and O2.
    Schematic diagram of O3-CRDS.
    (a) When the instrument only samples zero air, the black point represents the average data of 1 s, and the red point represents the average data of 30 s; (b) Allan variance of ozone concentration.
    Measurement results of ozone concentration distribution factor P.
    (a) Light intensity at 185 nm as a function of N2O concentration; (b) relationship between light intensity and ozone concentration.
    Concentration of OH radicals produced by the calibration device corresponds to the fluorescence count of LIF-OH system.
    Calibration results of LIF-OH instrument by OH radical calibration source under field conditions.
    • Table 1.

      Uncertainty of OH radical calibration source.

      OH自由基标定装置不确定度

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      Table 1.

      Uncertainty of OH radical calibration source.

      OH自由基标定装置不确定度

      误差源不确定度来源
      臭氧分布系数P6.0%测量
      臭氧灵敏度Qv2.9%测量
      PD光强 I'1.0%测量
      水汽浓度[H2O] 2.0%测量
      氧气吸收截面 $ \sigma _{\rm O_2} $7.0%测量
      水汽吸收截面 $ {\sigma _{{{\rm{H}}_2}{\rm{O}}}} $3.0%引用
      标定装置产生OH自由基误差10.4%计算
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    Feng-Yang Wang, Ren-Zhi Hu, Pin-Hua Xie, Yi-Hui Wang, Hao Chen, Guo-Xian Zhang, Wen-Qing Liu. Calibration source for OH radical based on synchronous photolysis[J]. Acta Physica Sinica, 2020, 69(9): 090701-1

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    Paper Information

    Category:

    Received: Jan. 21, 2020

    Accepted: --

    Published Online: Nov. 26, 2020

    The Author Email: Xie Pin-Hua (phxie@aiofm.ac.cn)

    DOI:10.7498/aps.69.20200153

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