Chinese Journal of Lasers, Volume. 52, Issue 18, 1803004(2025)

Research Progress of Rare‑Earth‑Doped Laser Single‑Crystal Fibers (Invited)

Xu Wu1,2, Zhen Zhang1,2, Zhonghan Zhang1,2, Liangbi Su1,2、*, and Anhua Wu1,2、**
Author Affiliations
  • 1State Key Laboratory of Functional Crystals and Devices, Shanghai Institute of Ceramics, Chinese Academy of Sciences, Shanghai 201899, China
  • 2College of Materials Science and Opto-Electronic Technology, University of Chinese Academy of Sciences, Beijing 100049, China
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    Figures & Tables(34)
    Schematic diagrams of single-crystal fibers. (a) Transitional single-crystal fiber[10]; (b) cladded single-crystal fiber[11]
    Schematic diagram of crystal fiber growth equipment by micro-pulling-down method. (a) Schematic diagram of the device[12]; (b) crucibles with various specifications[14]
    Schematic diagram of the LHPG method device and its principle[18]
    Schematic diagram of the multi-microporous crucible method. (a) Schematic diagram of the device; (b) cross-sectional view; (c) schematic diagram of single-crystal fiber growth
    Schematic diagram of the energy level structure of Nd3+
    1.8-μm Nd∶YAG single-crystal fiber laser[33]. (a) Schematic diagram of the device; (b) relationship between output power and pump power in continuous and passive Q-switching modes
    Nd∶YAG single-crystal fiber laser[7]. (a) Schematic diagram of the device; (b) relationship between output power and pump power in continuous mode; (c) pulse peak power and single-pulse energy in passive Q-switching mode
    Structure diagram of 251-W high-power Yb∶YAG single-crystal fiber laser[38]
    Relationship between laser output power and pump power of Yb∶Lu2O3 single-crystal fiber, the inset is a microscopic image of the single-crystal fiber endface[41]
    Tm∶YAG single-crystal fiber laser[42] (a) Schematic diagram of wing pumping; (b) continuous laser output power;
    Tm∶YAP single-crystal fiber laser[43]. (a) Schematic diagram of single-end pumping device and continuous laser output performance; (b) schematic diagram of double-end pumping device and continuous laser output performance
    Relationship between laser output power and absorbed pump power of Tm∶CaF2 single-crystal fiber in continuous mode[44]. (a) 3%Tm∶CaF2; (b) 4%Tm∶CaF2
    Ho∶YAG single-crystal fiber laser[47]. (a) Schematic diagram of the device; (b) physical diagram of the device; (c) relationship between output power and absorbed pump power
    Cascaded Ho∶YAG single-crystal fiber laser[9]. (a)‒(d) Schematic diagrams of the device; (e) continuous laser output power; (f) corresponding spectra
    Schematic diagram of cooperative up-conversion between adjacent Er3+ ions
    Er∶CaF2 single-crystal fiber laser[52]. (a) Schematic diagram of the device; (b) laser performance of Er∶CaF2 single-crystal fiber with different concentrations
    Comparison between Nd∶YAG single-crystal fiber and Nd∶YAG crystals with other geometric shapes[62]. (a) Relationship between gain and pump power, the inset is a schematic diagram of the test device; (b) influence of different pump powers on spectral gain shift
    Nd∶YAG single-frequency master oscillator power amplifier system[63]
    Output characteristics of each amplifier. (a) SCF pre-amplifier; (b) first-stage main amplifier; (c) second-stage main amplifier
    Two-stage Nd∶YAG single-crystal fiber MOPA amplification system[64]. (a) Schematic diagram of the device; (b) output power and extraction efficiency of the second-stage amplification
    High-power linearly polarized continuous-wave single-frequency laser based on Nd∶YAG single-crystal fiber[7]. (a) Schematic diagram of the device; (b) total output power; (c) output power of the linearly polarized laser; (d) output power of the depolarized laser
    Schematic diagram of double-pass structure Yb∶YAG single-crystal fiber amplifier[67]
    High-energy ultrashort pulse amplification system with coherent beam combining of two single-crystal fibers[58]. (a) Schematic diagram of the device; (b) compressed pulse energy and variation of combining efficiency
    Yb∶YAG single-crystal fiber amplifier based on DPA technology[57]. (a) High-gain amplification stage; (b) high-energy sub-pulse amplification stage
    Multi-stage end-pumped Yb∶YAG single-crystal fiber CPA system[8]
    CDLHPG system[85]. (a) Schematic diagram of the principle; (b) end view and side view of the sapphire tube with fused-silica capillary
    LD-pumped glass-cladding Ti∶sapphire crystal fiber laser[86]. (a) Schematic diagram of the optical path; (b) output power under different pump powers; (c) laser spectra under different pump powers
    Cr⁴⁺∶YAG single-crystal fiber wavelength-scanning laser[87]. (a) Schematic diagram of the device; (b)‒(d) wavelength tuning and scanning characteristics
    Schematic diagram of the growth of “C4”-type optical fiber by the LPE method[11]
    “C4”-type optical fiber[11]. (a) Cross-sectional view; (b) quasi-continuous laser performance
    Gradient-doped Nd∶YAG single-crystal fiber[90]. (a) Schematic diagram of the growth principle; (b) laser performance
    1%Yb∶YAG tapered single-crystal fiber[91]. (a) Physical image; (b) schematic diagram of the small-signal gain test setup;
    • Table 1. Characteristics of common single‒crystal fiber preparation methods

      View table

      Table 1. Characteristics of common single‒crystal fiber preparation methods

      ParameterMechanical processingμ-PDLHPGMulti-microporous crucible
      Fiber diameter0.5‒2 mm0.3‒2 mm17 μm‒1 mm0.9‒2 mm
      Growth rate~5 mm/h2 cm/h(max)0.1‒1 mm/h
      Temperature gradient~2000 K/cm>4000 K/cm10‒50 K/cm
      Stress magnitudeSmallSmallLargeSmall
      Applicable range

      Existing bulk

      crystals

      Fluorides, high-melting-point oxides

      (below crucible melting point)

      Fluorides, high-melting-point oxidesMedium and high-melting-point fluorides

      High-throughput

      preparation

      NoYesNoYes
      CostHighLowLowLow
    • Table 2. Summary of ultrafast laser amplification experimental results of Yb∶YAG single-crystal fiber amplifiers

      View table

      Table 2. Summary of ultrafast laser amplification experimental results of Yb∶YAG single-crystal fiber amplifiers

      Year

      Size /

      mm

      Amplification

      method

      Average

      power /W

      Pulse

      energy

      Peak

      power

      Pulse

      width

      Repetition frequencyExtraction efficiency /%

      Beam

      quality

      Ref.
      2011Φ1×40Single-stage12400 nJ570 kW330 fs30 MHz7

      Mx2=1.28

      My2=1.68

      67
      2013Φ1×40CPA10‒23

      1 mJ

      @10 kHz

      2.2 GW380 fs10 kHz‒10 MHz28.5‒50<1.156
      2014Φ1×40Single-stage100(>2 MHz)1 μJ@7 kHz28 MW27 ps<3 MHz<1.169
      2014Φ1×40CBC3 mJ@6 kHz3.7 GW695 fs6 kHz‒100 MHz1.258
      2015Φ1×40Two-stage1601.9 μJ800 fs5 MHz42<1.968
      2015

      Φ1×40

      Φ1×30

      Three-stage1005 μJ7 MW750 fs20 MHz38<1.370
      2016Φ1×40CPA~30(500 kHz)

      0.42 mJ

      @21 kHz

      78‒210 ps21‒500 kHz~25<1.1371
      2016Φ1×30MOPA/CPA55(500 kHz)

      2 mJ

      @12.5 kHz

      320 MW6 ps12.5‒500 kHz<1.157
      2017Φ1×40Single-stage66.31.63 μJ1.58 MW909 fs40.7 MHz

      Mx2=2.3

      My2=2.1

      72
      2018Φ1×30Single-stage14.663.5 μJ73.9 MW859 fs100 kHz

      Mx2=1.23

      My2=1.24

      73
      2018

      Φ0.8×15

      Φ1×30

      CPA282.5 mJ2.8 ps11.5 kHz74
      2020

      Φ0.8×10

      Φ1×35

      CPA4 mJ1 ps1.5 kHz75
      2020Φ1CPA41.8309 μJ1.5 ps200 kHz

      Mx2=1.24

      My2=1.19

      76
      2020Φ1×40Single-stage2906 μJ6.4 MW829 fs48.5 MHz30.9

      Mx2=2.4

      My2=3.4

      77
      2022Φ1×40Three-stage240240 μJ1 MHz51.4

      Mx2=1.72

      My2=1.12

      78
      2024Φ0.1×10.5MOPA3.232 W2079
      2025Φ1×40CPA1031.03 mJ2.6 GW323 fs100 kHz<1.38
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    Xu Wu, Zhen Zhang, Zhonghan Zhang, Liangbi Su, Anhua Wu. Research Progress of Rare‑Earth‑Doped Laser Single‑Crystal Fibers (Invited)[J]. Chinese Journal of Lasers, 2025, 52(18): 1803004

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    Paper Information

    Category: Materials

    Received: Jun. 17, 2025

    Accepted: Jul. 21, 2025

    Published Online: Sep. 19, 2025

    The Author Email: Liangbi Su (suliangbi@mail.sic.ac.cn), Anhua Wu (wuanhua@mail.sic.ac.cn)

    DOI:10.3788/CJL250968

    CSTR:32183.14.CJL250968

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