Chinese Journal of Lasers, Volume. 52, Issue 4, 0402103(2025)

Electrical Properties of Conductive Silver Circuits After “Hot Airflow + Laser” Composite Sintering

Zhuo Chen, Xingzhi Xiao*, Wenhe Liao, Tingting Liu, Shilin Wang, and Gang Li
Author Affiliations
  • School of Mechanical Engineering, Nanjing University of Science and Technology, Nanjing 210094, Jiangsu , China
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    Figures & Tables(22)
    Principle of circuit extrusion
    Morphologies of extruded conductive silver paste circuit. (a) Optical microscope image; (b) laser confocal image
    Principle of “hot airflow + laser” composite sintering. (a) Schematic; (b) temperature curve
    “Hot airflow + laser” composite sintering system. (a) Physical drawing; (b) structure
    Image of temperature field during sintering circuit
    Relationship between laser power and conductive circuit resistivity under different sintering processes
    Relationship between scanning speed and conductive circuit resistivity under different sintering processes
    Surface morphologies of circuit after laser sintering and circuit after “hot airflow + laser” composite sintering
    Relationship between laser power and cross-sectional area of circuit under two sintering processes
    Relationship between scanning speed and cross-sectional area of circuit under two sintering processes
    Surface morphologies and surface roughnesses of circuit after laser sintering and circuit after “hot airflow + laser” composite sintering. (a) SEM image of circuit after 10 W laser sintering; (b) SEM image of circuit after “200 ℃ hot airflow +10 W laser” composite sintering; (c) surface roughness of circuit after 10 W laser sintering; (d) surface roughness ofcircuit after “200 ℃ hot airflow +10 W laser” composite sintering
    Cross-sectional CT images of sintered circuits under two sintering processes
    Thermogravimetric analysis of nano-silver paste
    Schematics of “hot airflow + laser” composite sintering . (a) Schematic of hot airflow sintering; (b) schematic of laser sintering after hot airflow sintering
    Relationship between laser power and circuit resistance under two sintering processes
    Relationship between scanning speed and circuit resistance under two sintering processes
    Volume fractions of circuit pores under different sintering processes. (a) Effect of laser power on volume fraction of stomatal defect; (b) circuit after 6 W laser sintering; (c) circuit after “6 W laser +200 °C hot air flow” composite sintering
    SEM images of cross sections of circuits. (a) “200 ℃ hot air flow +2 W laser” composite sintering; (b) “200 ℃ hot air flow +6 W laser” composite sintering; (c) “200 ℃ hot air flow +10 W laser” composite sintering
    • Table 1. Chemical compositions of conductive silver paste

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      Table 1. Chemical compositions of conductive silver paste

      CompositionEthylcelluloseDiethylene glycol butyl ether acetate2, 4-di-tert-butylphenolErucamidePowdered glassSilver powder
      Mass fraction /%0.894.570.020.174.3590
    • Table 2. Circuit extrusion molding process parameters

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      Table 2. Circuit extrusion molding process parameters

      Parameter

      Extrusion

      pressure /MPa

      Print speed /

      (mm/s)

      Nozzle

      height /mm

      Value0.457.000.40
    • Table 3. Sintering process parameters

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      Table 3. Sintering process parameters

      No.

      Laser

      power /W

      Airflow

      temperature /℃

      Offset /

      mm

      Amount of

      defocus /mm

      Spot

      diameter /μm

      Scan speed /

      (mm/s)

      12, 4, 6, 8, 1004000.5
      22, 4, 6, 8, 10200804000.5
      310804000.1,0.3,0.5,0.7,0.9,1.1,1.3
      410300804000.1,0.3,0.5,0.7,0.9,1.1,1.3
    • Table 4. Internal element contents of pre-sintered circuits under different temperatures

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      Table 4. Internal element contents of pre-sintered circuits under different temperatures

      TemperatureMass fraction /%
      COSiAg
      Unsintered circuit5.332.620.8491.21
      100 ℃4.312.040.8392.82
      200 ℃1.260.970.8596.92
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    Zhuo Chen, Xingzhi Xiao, Wenhe Liao, Tingting Liu, Shilin Wang, Gang Li. Electrical Properties of Conductive Silver Circuits After “Hot Airflow + Laser” Composite Sintering[J]. Chinese Journal of Lasers, 2025, 52(4): 0402103

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    Paper Information

    Category: Laser Forming Manufacturing

    Received: Jul. 25, 2024

    Accepted: Oct. 10, 2024

    Published Online: Jan. 20, 2025

    The Author Email: Xiao Xingzhi (xingzhi.xiao@njust.edu.cn)

    DOI:10.3788/CJL241095

    CSTR:32183.14.CJL241095

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