Fig. 1. Crystal geometric close packing structure and Frank-Kasper phase topological close packing structure

Fig. 2. Frank-Kasper coordination number（CN）and phase type

Fig. 3. Ionic surfactants form body-centered cubic phase，Frank- Kasper A15 phase and σ phase^［26］.

Fig. 4. （a）Illustration of the molecular structure of a poly（isopreneblactide）diblock copolymer；（b）Isolated self-assembled spherical micelle^［42］.

Fig. 5. Dendritic macromolecules assembled into spherical mesoatom to form Frank-Kasper A15 phase^［53］

Fig. 6. （a）Chemical structures of the DPOSS-nPSm giant molecules；（b）Experimental phase boundary diagrams of DPOSS-nPSm（n=1~4）giant surfactants with different topological structures^［73］.