Fig. 1. （a） Three-dimensional model of the Gyroid structure. The red color represents the enantiomeric skeletons， and the light gray part is TPMS； （b） Saddle surfaces with negative Gaussian curvature in the Gyroid structure， similar to Pringles chips； （c） Type 1 and type 2 Gyroid based on the spatial distribution characteristics of the water and the oil phases.

Fig. 2. Critical packing parameter （CPP） and its relationship with the self-assembled morphologies^［23］

Fig. 3. （a） Photo of viscous Gyroid liquid crystals； （b） “Dark” image of Gyroid liquid crystals with no bright optical texture under polarized light； （c） Photo of the SAXS beamline of the Shanghai Synchrotron Radiation Facility used to study Gyroid liquid crystals； （d） SAXS diffraction pattern showing typical diffraction rings； （e） TEM observation of microtomed Gyroid liquid crystals after photocuring.

Fig. 4. （a） Molecular structure of the polymerizable amphiphilic molecule （Diene-GZI）； （b） Schematic illustration of the molecular arrangement within the Gyroid skeleton structure.

Fig. 5. Molecular structures and schematic illustrations of polymerizable zwitterionic surfactants （SB11-1MA） （a） and Pluronic surfactants （P105-DA） （b）； （c） Gyroid structures formed by self-assembly. （d） Li⁺ transport process within the Gyroid structure.