Acta Optica Sinica, Volume. 41, Issue 22, 2216001(2021)

Effect of Side-Chain Liquid Crystalline Polymer on Helical Structure of Chiral Nematic Liquid Crystal

Zhixuan Jia, Hongjun Hei, Shengwang Yu, and Yanyan Shen*
Author Affiliations
  • College of Material Science and Engineering, Taiyuan University of Technology, Taiyuan, Shanxi 030024, China
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    Figures & Tables(6)
    Experimental materials and cell preparation process. (a) Chemical structures of nematic liquid crystal, chiral dopant (CB15), OTS, and PMMAZO; (b) cell preparation process
    Morphologies of CLCs confined in cells with different cell thicknesses and grafting densities of PMMAZO for scale bar of 25 μm
    Average size of fingerprint domain in cells with 7 μm and 9 μm thicknesses. (a) OTS; (b) mass fraction of PMMAZO is 0.03%, σ=1.800×10-2 chain/nm2; (c) mass fraction of PMMAZO is 0.06%, σ=2.060×10-2 chain/nm2; (d) mass fraction of PMMAZO is 0.08%, σ=2.362×10-2 chain/nm2; (e) mass fraction of PMMAZO is 0.12%, σ=2.680×10-2 chain/nm2; (f) average size of fingerprint domain for OTS and different PMMAZO mass fractions when σ=1.800×10-2 chain/nm2
    Morphologies of CLCs in cells with different thicknesses when mass fraction of PMMAZO is 0.03% and scale bar is 10 μm. (a) 0.1 μm; (b) 1 μm; (c) 2 μm; (d) 3 μm; (e) 5 μm; (f) 7 μm; (g) 9 μm; (h) 10 μm; (i) 12 μm; (j) 14 μm
    Period of helix versus thickness of cell under different PMMAZO concentrations. (a) OTS; (b) mass fraction of PMMAZO is 0.03%; (c) mass fraction of PMMAZO is 0.06%; (d) mass fraction of PMMAZO is 0.08%; (e) mass fraction of PMMAZO is 0.12%
    • Table 1. Relationship between PMMAZO grafting density and spin-coating liquid concentration

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      Table 1. Relationship between PMMAZO grafting density and spin-coating liquid concentration

      Mass fraction /%Coating thickness /nmσ /(10-2 chain·nm-2)Σ
      0.032.6321.86.47
      0.063.0112.067.41
      0.083.4522.3628.49
      0.123.9122.689.63
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    Zhixuan Jia, Hongjun Hei, Shengwang Yu, Yanyan Shen. Effect of Side-Chain Liquid Crystalline Polymer on Helical Structure of Chiral Nematic Liquid Crystal[J]. Acta Optica Sinica, 2021, 41(22): 2216001

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    Paper Information

    Category: Materials

    Received: Apr. 12, 2021

    Accepted: Jun. 8, 2021

    Published Online: Nov. 21, 2021

    The Author Email: Shen Yanyan (shenyanyan@tyut.edu.cn)

    DOI:10.3788/AOS202141.2216001

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