Journal of Inorganic Materials, Volume. 40, Issue 2, 159(2025)

Pressureless Sintering of (Y0.2Gd0.2Er0.2Yb0.2Lu0.2)2Zr2O7 High-entropy Ceramic and Its High Temperature CMAS Corrosion Resistance

Wenkai FAN1,2, Xiao YANG1, Honghua LI1, Yong LI1, and Jiangtao LI1、*
Author Affiliations
  • 11. Key Laboratory of Cryogenic Science and Technology, Technical Institute of Physics and Chemistry, Chinese Academy of Sciences, Beijing 100190, China
  • 22. University of Chinese Academy of Sciences, Beijing 100049, China
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    Figures & Tables(12)
    Phase composition of rare-earth zirconates (REZs)
    Macroscopic and microscopic morphologies and EDS analyses of HE-REZ bulk ceramic (HE3) prepared by CIP+PLS
    Crystalline morphologies and CMAS corrosion depths of HE-REZ bulk samples with different relative densities
    Corrosion depths and Si distributions of bulk ceramic synthesized by CIP+PLS under the same CMAS corrosion condition
    Crystalline morphologies of control groups
    Morphology and element distribution in the reaction zone of HE-REZ after CMAS corrosion
    CMAS corrosion kinetics of HE-REZ bulk ceramic
    Schematic diagram of CMAS corrosion kinetics for HE-REZ ceramic
    Mechanical properties of HE-REZ, GZO and 7YSZ bulk ceramics
    Thermal properties of HE-REZ and GZO bulk ceramics
    • Table 1. Shannon ionic radii of some cations

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      Table 1. Shannon ionic radii of some cations

      ElementCoordination numberValencyIonic radius/pm
      Zr6+472.0
      Lu8+397.7
      Yb8+398.5
      Er8+3100.4
      Y8+3101.9
      Gd8+3105.3
      Sm8+3107.9
      Nd8+3110.9
      La8+3116.0
    • Table 2. Summary of some properties of bulk ceramic samples prepared in this work

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      Table 2. Summary of some properties of bulk ceramic samples prepared in this work

      SamplePreparation methodRelative density/%Average grain size/μm Corrosion depth (1300 ℃, 10 h)/μm
      HE1SPS99.77.20±3.2018±2
      HE2PLS95.42.60±0.8045±5
      HE3CIP+PLS98.62.40±0.6028±3
      GZOCIP+PLS98.32.70±0.80124±8
      7YSZCIP+PLS97.20.36±0.141070±10
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    Wenkai FAN, Xiao YANG, Honghua LI, Yong LI, Jiangtao LI. Pressureless Sintering of (Y0.2Gd0.2Er0.2Yb0.2Lu0.2)2Zr2O7 High-entropy Ceramic and Its High Temperature CMAS Corrosion Resistance [J]. Journal of Inorganic Materials, 2025, 40(2): 159

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    Paper Information

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    Received: May. 22, 2024

    Accepted: --

    Published Online: Apr. 24, 2025

    The Author Email: Jiangtao LI (lijiangtao@mail.ipc.ac.cn)

    DOI:10.15541/jim20240256

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