Journal of the Chinese Ceramic Society, Volume. 50, Issue 1, 70(2022)

Recent Development on Lithium-Rich Cathode Materials for High Specific Energy Lithium-Ion Batteries

LIU Rixin1,2、*, ZHANG Zhenjie2, LI Haoyu1,2, KE Bingyu1,2, GUO Shaohua1,2, and ZHOU Haoshen2
Author Affiliations
  • 1[in Chinese]
  • 2[in Chinese]
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    References(111)

    [1] [1] FAN Y, ZHANG W, ZHAO Y, et al. Fundamental understanding and practical challenges of lithium-rich oxide cathode materials: Layered and disordered-rocksalt structure[J]. Energy Storage Mater, 2021, 40:51–71.

    [2] [2] HE W, GUO W, WU H, et al. Challenges and recent advances in high capacity Li-rich cathode materials for high energy density lithium-ion batteries[J]. Adv Mater, 2021, https://doi.org/10.10021adma.202005937.

    [3] [3] MIZUSHIMA K, JONES P C, WISEMAN P J, et al. LixCoO2(0<x?1): A new cathode material for batteries of high energy density[J]. Mater Res Bull, 1980, 15(6): 783–789.

    [4] [4] XIA Y, ZHENG J, WANG C, et al. Designing principle for Ni-rich cathode materials with high energy density for practical applications[J]. Nano Energy, 2018, 49: 434–452.

    [5] [5] SUSAI F A, SCLAR H, SHILINA Y, et al. Horizons for Li-ion batteries relevant to electro-mobility: High-specific-energy cathodes and chemically active separators[J]. Adv Mater, 2018, 30(41):1801348.

    [6] [6] NAYAK P K, ERICKSON E M, SCHIPPER F, et al. Review on challenges and recent advances in the electrochemical performance of high capacity Li- and Mn-rich cathode materials for Li-ion batteries[J]. Adv Energy Mater, 2018, 8(8): 1802057.

    [7] [7] LEE J, URBAN A, LI X, et al. Unlocking the potential of cation-disordered oxides for rechargeable lithium batteries[J]. Science,2014, 343(6170): 519–522.

    [8] [8] HUANG J, ZHONG P, HA Y, et al. Non-topotactic reactions enable high rate capability in Li-rich cathode materials[J]. Nat Energy, 2021,6: 706–614.

    [9] [9] LUN Z, OUYANG B, KWON D, et al. Cation-disordered rocksalt-type high-entropy cathodes for Li-ion batteries[J]. Nature Mater, 2021, 20: 214–221.

    [10] [10] YUE Y, LI N, HA Y, et al. Tailoring the redox reactions for high-capacity cycling of cation-disordered rocksalt cathodes[J]. Adv Funct Mater, 2021, 31(14): 2008696.

    [11] [11] ZHAO E, HE L, WANG B, et al. Structural and mechanistic revelations on high capacity cation-disordered Li-rich oxides for rechargeable Li-ion batteries[J]. Energy Storage Mater, 2019, 16:354–363.

    [12] [12] URBAN A, MATTS I, ABDELLAHI A, et al. Computational design and preparation of cation-disordered oxides for high-energy-density Li-ion batteries[J]. Adv Energy Mater, 2016, 6(15): 1600488.

    [13] [13] CHEN Q, PEI Y, CHEN H, et al. Highly reversible oxygen redox in layered compounds made possible by surface polyanions[J]. Nat Commun, 2020, 11: 3411.

    [14] [14] QIU B, ZHANG M H, WU L J, et al. Gas–solid interfacial modification of oxygen activity in layered oxide cathodes for lithium-ion batteries[J]. Nat Commun, 2016, 7: 12108.

    [15] [15] SI M, WANG D, ZHAO R, et al. Local electric-field-driven fast Li diffusion kinetics at the piezoelectric LiTaO3 modified Li-rich cathode–electrolyte interphase[J]. Adv Sci, 2020, 7(3): 1902538.

    [16] [16] ZHU Z, YU D, YANG Y, et al. Gradient Li-rich oxide cathode particles immunized against oxygen release by a molten salt treatment[J]. Nat Energy, 2019, 4: 1049–1058.

    [17] [17] LEE J, SEO D H, BALASUBRAMANIAN M, et al. A new class of high capacity cation-disordered oxides for rechargeable lithium batteries: Li–Ni–Ti–Mo oxides[J]. Energy Environ Sci, 2015, 8(11):3255–3265.

    [18] [18] LEE J, KITCHAEV D A, KWON D, et al. Reversible Mn2+/Mn4+ double redox in lithium-excess cathode materials[J]. Nature, 2018,556: 185–190.

    [19] [19] ZHENG S, ZHOU K, ZHENG F, et al. Mn4+-substituted Li-rich Li1.2Mn0.4 3+Mnx 4+Ti0.4–xO2 materials with high energy density[J]. ACS Appl Mater Interfaces, 2020, 12(36): 40347–40354.

    [20] [20] ASSAT G , TARASCON J. Fundamental understanding and practical challenges of anionic redox activity in Li-ion batteries[J]. Nat Energy,2018, 3: 373–386.

    [21] [21] ZHENG H, HAN X, GUO W, et al. Recent developments and challenges of Li-rich Mn-based cathode materials for high-energy lithium-ion batteries[J]. Mater Today Energy, 2020, 18: 100518.

    [22] [22] YU H, ISHIKAWA R, SO Y, et al. Direct atomic-resolution observation of two phases in the Li1.2Mn0.567Ni0.166Co0.067O2 cathode material for lithium-ion batteries[J]. Angew Chem Int Ed, 2013,52(23): 5969–5973.

    [23] [23] YU X, LYU Y, GU L, et al. Understanding the rate capability of high-energy-density Li-rich layered Li1.2Ni0.15Co0.1Mn0.55O2 cathode materials[J]. Adv Energy Mater, 2014, 4(5): 1300950.

    [24] [24] LUO D, LI G, Fu C, et al. A new spinel-layered Li-rich microsphere as a high-rate cathode material for Li-ion batteries[J]. Adv Energy Mater, 2014, 4(11): 1400062.

    [25] [25] JARVIS K A, DENG Z, ALLARD L F, et al. Atomic structure of a lithium-rich layered oxide material for lithium-ion batteries: Evidence of a solid solution[J]. Chem Mater, 2011, 23(16): 3614–3621.

    [26] [26] ZHU Z, GAO R, WALUYO I, et al. Stabilized Co-free Li-rich oxide cathode particles with an artificial surface prereconstruction[J]. Adv Energy Mater, 2020, 10(35): 2001120.

    [27] [27] ABDELLAHI A, URBAN A, DACEK S, et al. Understanding the effect of cation disorder on the voltage profile of lithium transition-metal oxides[J]. Chem Mater, 2016, 28(15): 5373–5383.

    [28] [28] KITCHAEV D, LEE J, CEDER G, et al. Short-range order and unusual modes of nickel redox in a fluorine-substituted disordered rocksalt oxide lithium-ion cathode[J]. Chem Mater, 2018, 30(19):6945–6956.

    [29] [29] WANG R. Short-range structure for amorphous intertransition metal alloys[J]. Nature, 1979, 278: 700–704.

    [30] [30] OUYANG B, ARTRITH N, LUN Z, et al. Effect of fluorination on lithium transport and short-range order in disordered-rocksalt-type lithium-ion battery cathodes[J]. Adv Energy Mater, 2020, 10(10):1903240.

    [31] [31] ASSAT G, FOIX D, DELACOURT C, et al. Fundamental interplay between anionic/cationic redox governing the kinetics and thermodynamics of lithium-rich cathodes[J]. Nat Commun , 2017, 8:2219.

    [32] [32] ZHANG J, LI Q, OUYANG C, et al. Trace doping of multiple elements enables stable battery cycling of LiCoO2 at 4.6 V[J]. Nat Energy, 2019, 4: 594–603.

    [33] [33] WANG Y, ZHANG Q, XUE Z, et al. An in situ formed surface coating layer enabling LiCoO2 with stable 4.6 V high-voltage cycle performances[J]. Adv Energy Mater, 2020, 10(28): 2001413.

    [34] [34] LYU Y, WU X, WANG K, et al. An overview on the advances of LiCoO2 cathodes for lithium-ion batteries[J]. Adv Energy Mater,2021, 11(2): 2000982.

    [35] [35] KOGA H, CROGUENNEC L, MéNéTRIER M, et al. Operando X-ray absorption study of the redox processes involved upon cycling of the Li-rich layered oxide Li1.20Mn0.54Co0.13Ni0.13O2 in Li ion batteries[J]. J Phys Chem C, 2014, 118(11): 5700–5709.

    [36] [36] LIM B, MYUNG S, YOON C S, et al. Comparative study of Ni-rich layered cathodes for rechargeable lithium batteries: Li[Ni0.85Co0.11Al0.04]O2 and Li[Ni0.84Co0.06Mn0.09Al0.01]O2 with two-step full concentration gradients[J]. ACS Energy Lett, 2016, 1(1): 283–289.

    [37] [37] SARI H M K, LI X. Controllable cathode–electrolyte interface of Li[Ni0.8Co0.1Mn0.1]O2 for lithium ion batteries: A review[J]. Adv Energy Mater, 2019, 9(39): 1901597.

    [38] [38] HOU P, YIN J, DING M, et al. Surface/interfacial structure and chemistry of high-energy nickel-rich layered oxide cathodes:Advances and perspectives[J]. Small, 2017, 13(45): 1701802.

    [39] [39] JI H, KITCHAEV D A, LUN Z, et al. Computational investigation and experimental realization of disordered high-capacity Li-ion cathodes based on Ni redox[J]. Chem Mater, 2019, 31(7): 2431–2442.

    [40] [40] CAMBAZ M A, URBAN A, PERVEZ S A, et al. Understanding the origin of higher capacity for Ni-based disordered rock-salt cathodes[J].Chem Mater, 2020, 32(8): 3447–3461.

    [41] [41] NAKAJIMA M, YABUUCHI N, ABUOCHI N, et al. Lithium-excess cation-disordered rocksalt-type oxide with nanoscale phase segregation: Li1.25Nb0.25V0.5O2[J]. Chem Mater, 2017, 29(16):6927–6935.

    [42] [42] BOSUBABU D, ETTE P M, KUMAR A K N, et al. Proliferation of atomic shuffling through mechanical stress on cationic disorder Li4FeMoO6 as a cathode material for a lithium-ion battery[J]. ACS Appl Energy Mater, 2020, 3(9): 8716–8724.

    [43] [43] HOSHINO S, GLUSHENKOV A M, ICHIKAWA S, et al. Reversible three-electron redox reaction of Mo3+/Mo6+ for rechargeable lithium batteries[J]. ACS Energy Lett, 2017, 2(4): 733–738.

    [44] [44] LEE H, CHOI W, LEE W, ICHIKAWA S, et al. Impact of local separation on the structural and electro-chemical behaviors in Li2MoO3-LiCrO2 disordered rock-salt cathode material[J]. Adv Energy Mater, 2021, 11(3): 2002958.

    [45] [45] RADIN M D, VINCKEVICIUTE J, SESHADRI R, et al. Manganese oxidation as the origin of the anomalous capacity of Mn-containing Li-excess cathode materials[J]. Nat Energy, 2019, 4: 639–646.

    [46] [46] KALYANI P, CHITRA S, MOHAN T, et al. Lithium metal rechargeable cells using Li2MnO3 as the positive electrode[J]. J Power Sources, 1999, 80(1/2): 103–106.

    [47] [47] ROBERTSONA A D, BRUCE P G. The origin of electrochemical activity in Li2MnO3[J]. Chem Commun, 2002, 23: 2790–2791.

    [48] [48] ROBERTSON A D, BRUCE P G. Mechanism of electrochemical activity in Li2MnO3[J]. Chem Mater, 2003, 15(10): 1984–1992.

    [49] [49] ARMSTRONG A R, HOLZAPFEL M, NOVAK P, et al.Demonstrating oxygen loss and associated structural reorganization in the lithium battery cathode Li[Ni0.2Li0.2Mn0.6]O2[J]. J Am Chem Soc,2006, 128(26): 8694–8698.

    [50] [50] RANA J, PAPP J K, LEBENS-HIGGINS Z, et al. Quantifying the capacity contributions during activation of Li2MnO3[J]. ACS Energy Lett, 2020, 5(2): 634–641.

    [51] [51] GUERRINI N, JIN L, LOZANO J G, et al. Charging mechanism of Li2MnO3[J]. Chem Mater, 2020, 32(9): 3733–3740.

    [52] [52] ZHUO Z, DAI K, QIAO R, et al. Cycling mechanism of Li2MnO3:Li–CO2 batteries and commonality on oxygen redox in cathode materials[J]. Joule, 2021, 5(4): 975–997.

    [53] [53] KOGA H, CROGUENNECA L, MéNéTRIERET M, et al. Different oxygen redox participation for bulk and surface: A possible global explanation for the cycling mechanism of Li1.20Mn0.54Co0.13Ni0.13O2[J].J Power Sources, 2013, 236: 250–258.

    [54] [54] SATHIYA M, RAMESHA K, ROUSSE G, et al. High performance Li2Ru1–yMnyO3 (0.2≤y≤0.8) cathode materials for rechargeable lithium-ion batteries: Their understanding[J]. Chem Mater, 2013,25(7): 1121–1131.

    [55] [55] SATHIYA M, ROUSSE G, RAMESHA K, et al. Reversible anionic redox chemistry in high-capacity layered-oxide electrodes[J]. Nat Mater, 2013, 12: 827–835.

    [56] [56] SEO D, LEE J, URBAN A, et al. The structural and chemical origin of the oxygen redox activity in layered and cation-disordered Li-excess cathode materials[J]. Nat Chem, 2016, 8: 692–697.

    [57] [57] PEARCE P E, PEREZ A J, ROUSSE G, et al. Evidence for anionic redox activity in a tridimensional-ordered Li-rich positive electrode β-Li2IrO3[J]. Nat Mater, 2017, 16: 580–586.

    [58] [58] LI B, XIA D. Anionic redox in rechargeable lithium batteries[J]. Adv Mater, 2017, 29(48): 1701054.

    [59] [59] HONG J, GENT W E, XIAO P, et al. Metal–oxygen decoordination stabilizes anion redox in Li-rich oxides[J]. Nat Mater, 2019, 18:256–265.

    [60] [60] DAI K, WU J, ZHUO Z, et al. High reversibility of lattice oxygen redox quantified by direct bulk probes of both anionic and cationic redox reactions[J]. Joule, 2019, 3(2): 518–541.

    [61] [61] HAFIZ H, SUZUKI K, BARBIELLINI B, et al. Tomographic reconstruction of oxygen orbitals in lithium-rich battery materials[J]. Nature, 2021, 594: 213–216.

    [62] [62] CAO X, LI H, QIAO Y, et al. Stabilizing anionic redox chemistry in a Mn-based layered oxide cathode constructed by Li-deficient pristine state[J]. Adv Mater, 2021, 33(2): 2004280.

    [63] [63] LI X, QIAO Y, GUO S, et al. A new type of Li-rich rock-salt oxide Li2Ni1/3Ru2/3O3 with reversible anionic redox chemistry[J]. Adv Mater,2019, 31(11): 1807825.

    [64] [64] LI H, GUO S, ZHOU H. In-situ/operando characterization techniques in lithium-ion batteries and beyond[J]. J Energy Chem, 2021, 59:191–211.

    [65] [65] MOHANTY D, LI J L, ABRAHAM P D, et al. Unraveling the voltage-fade mechanism in high-energy-density lithium-ion batteries:Origin of the tetrahedral cations for spinel conversion[J]. Chem Mater,2014, 26(21): 6272–6280.

    [66] [66] LI N, HWANG S, SUN M L, et al. Unraveling the voltage decay phenomenon in Li-rich layered oxide cathode of no oxygen activity[J].Adv Energy Mater, 2019, 9(47): 1902258.

    [67] [67] SATHIYA M, ABAKUMOV A M, FOIX D, et al. Origin of voltage decay in high-capacity layered oxide electrodes[J]. Nat Mater, 2015,14: 230–238.

    [68] [68] XU B, FELL C, CHI M F, et al. Identifying surface structural changes in layered Li-excess nickel manganeseoxides in high voltage lithium ion batteries: A joint experimental and theoretical study[J]. Energy Environ Sci, 2011, 4: 2223–2233.

    [69] [69] GU M, BELHAROUAK I, ZHENG J M, et al. Formation of the spinel phase in the layered composite cathode used in Li-ion batteries[J]. ACS Nano, 2013, 7(1): 760–767.

    [70] [70] HE W, LIU P F, ZHOU Y, et al. A novel morphology-controlled synthesis of Na+-doped Li- and Mn-rich cathodes by the self-assembly of amphiphilic spherical micelles[J]. Sustain Mater Technol, 2020, 25: e00171.

    [71] [71] LI Q, LI G S, FU C C, et al. K+-doped Li1.2Mn0.54Co0.13Ni0.13O2: A novel cathode material with an enhanced cycling stability for lithium-ion batteries[J]. ACS Appl Mater Interfaces, 2014, 6(13):10330–10341.

    [72] [72] CHOI A, LIM J, KIM H, et al. In situ electrochemical Zn2+-doping for Mn-rich layered oxides in Li-ion batteries[J]. ACS Appl Energy Mater, 2019, 2(5): 3427–3434.

    [73] [73] SONG J H, SHIM J H, KAPYLOU A, et al. Suppression of voltage depression in Li-rich layered oxide by introducing GaO4 structural units in the Li2MnO3-like nano-domain[J]. Nano Energy, 2016, 30:717–727.

    [74] [74] KANG S F, QIN H F, FANG Y, et al. Preparation and electrochemical performance of yttrium-doped Li[Li0.20Mn0.534 Ni0.133Co0.133]O2 as cathode material for lithium-ion batteries[J].Electrochim Acta, 2014, 144: 22–30.

    [75] [75] WANG Y Q, YANG Z Z, QIAN Y M, et al. New insights into improving rate performance of lithium-rich cathode material[J]. Adv Mater, 2015, 27(26): 3915–3920.

    [76] [76] LI L, SONG B H, CHANG Y L, et al. Retarded phase transition by fluorine doping in Li-rich layered Li1.2Mn0.54Ni0.13Co0.13O2 cathode material[J]. J Power Source, 2015, 283: 162–170.

    [77] [77] SONG J H, KAPYLOU A, CHOI H S, et al. Suppression of irreversible capacity loss in Li-rich layered oxide by fluorine doping[J]. J Power Source, 2016, 313: 65–72.

    [78] [78] LEE S H, MOON J S, LEE M S, et al. Enhancing phase stability and kinetics of lithium-rich layered oxide for an ultra-high performing cathode in Li-ion batteries[J]. J Power Source, 2015, 281: 77–84.

    [79] [79] KAPYLOU A, SONG J H, MISSIUL A, et al. Improved thermal stability of lithium-rich layered oxide by fluorine doping[J]. Chemphyschem, 2018, 19( 1): 116–122.

    [80] [80] WANG T S, ZHANG C X, LI S W, et al. Regulating anion redox and cation migration to enhance the structural stability of Li-rich layered oxides[J]. ACS Appl Mater Interfaces, 2021, 13(10): 12159–12168.

    [81] [81] ZAHNG H Z, QIAO Q Q, LI G R, et al. PO43? polyanion-doping for stabilizing Li-rich layered oxides as cathode materials for advanced lithium-ion batteries[J]. J Mater Chem A, 2014, 2: 7454–7460.

    [82] [82] ZHANG H Z, LI F, PAN G L, et al. The effect of polyanion-doping on the structure and electrochemical performance of Li-rich layered oxides as cathode for lithium-ion batteries[J]. J Electrochem Soc,2015, 162: A1899.

    [83] [83] LI B, YAN H J, MA J, et al. Manipulating the electronic Structure of Li-rich manganese-based oxide using polyanions: Towards better electrochemical performance[J]. Adv Funct Mater, 2014, 24(32):5112–5118.

    [84] [84] LIU Y, NING D, ZHENG L R, et al. Improving the electrochemical performances of Li-rich Li1.20Ni0.13Co0.13Mn0.54O2 through a cooperative doping of Na+ and PO43? with Na3PO4[J]. J Power Source,2018, 375: 1–10.

    [85] [85] ZHENG H F, ZHANG C Y, ZHANG Y G, et al. Manipulating the local electronic structure in Li-rich layered cathode towards superior electrochemical performance[J]. Adv Funct Mater, 2021, 31(30):2100783.

    [86] [86] HU Y Y, QIN Z Z, CONG B W, et al. Sn and Na Co-doping to suppress voltage decay of Li-rich layered oxide[J]. ChenElectroChem,2021, 8(12): 2315–2320.

    [87] [87] YANG S Q, WANG P B, WEI H X, et al. Li4V2Mn(PO4)4-stablized Li[Li0.2Mn0.54Ni0.13Co0.13]O2 cathode materials for lithium ion batteries[J]. Nano Energy, 2019, 63: 103889.

    [88] [88] WU B, YANG X K, XIA J, et al. Synchronous tailoring surface structure and chemical composition of Li-rich–layered oxide for high-energy lithium-ion batteries[J]. Adv Funct Mater, 2018, 28(37):1803392.

    [89] [89] ZAHNG W, SUN Y G, DENG H Q, et al. Dielectric polarization in inverse spinel-structured Mg2TiO4 coating to suppress oxygen evolution of Li-rich cathode materials[J]. Adv Mater, 2020, 32(19):200496.

    [90] [90] GAO J, KIM J, MANTHIRAM A, et al. High capacity Li[Li0.2Mn0.54Ni0.13Co0.13]O2–V2O5 composite cathodes with low irreversible capacity loss for lithium ion batteries[J]. Electrochem Commun, 2009, 11(1): 84–86.

    [91] [91] WU F, WANG Z, SU Y F, et al. Li[Li0.2Mn0.54Ni0.13Co0.13]O2–MoO3 composite cathodes with low irreversible capacity loss for lithium ion batteries[J]. J Power Sources, 247: 20–25.

    [92] [92] QIAO Q Q, LI G R, WANG Y L, et al. To enhance the capacity of Li-rich layered oxides by surface modification with metal–organic frameworks (MOFs) as cathodes for advanced lithium-ion batteries[J]. J Mater Chem A, 2016, 4: 4440–4447.

    [93] [93] DING X, LI Y X, WANG S, et al. Towards improved structural stability and electrochemical properties of a Li-rich material by a strategy of double gradient surface modification[J]. Nano Energy,2019, 61: 411–419.

    [94] [94] ZHAO Y, LIU J T, WAANG S B, et al. Surface structural transition induced by gradient polyanion-doping in Li-rich layered oxides:implications for enhanced electrochemical performance[J]. Adv Funct Mater, 2016, 26(26): 4760–4767.

    [95] [95] ZHANG S M, GU H T, PAN H G, et al. A novel strategy to suppress capacity and voltage fading of Li- and Mn-rich layered oxide cathode material for lithium-ion batteries[J]. Adv Energy Mater, 2016, 7(6):1601066.

    [96] [96] ZHANG J, WANG J L, YANG J, et al. Artificial interface deriving from sacrificial tris(trimethylsilyl)phosphate additive for lithium rich cathode materials[J]. Electrochim Acta, 2014, 117: 99–104.

    [97] [97] BIRROZZI A, LASZCZYNSKI N, HEKMATFAR M, et al.Beneficial effect of propane sultone and tris(trimethylsilyl) borate as electrolyte additives on the cycling stability of the lithium rich nickel manganese cobalt (NMC) oxide[J]. J Power Sources, 2016, 325:525–533.

    [98] [98] LUO Q, XIE Y X, WU Z J, et al. Facile molten vanadate-assisted surface treatment strategy for Li2MnO3 activation of Li-rich cathode materials[J]. ACS Appl Energy Mater, 2021, 4(5): 4867–4878.

    [99] [99] WANG M J, SHAO A F, YU F D, et al. Simple water treatment strategy to optimize the Li2MnO3 activation of lithium-rich cathode materials[J]. ACS Sustain Chem Eng, 2019, 7, 15: 12825–12837.

    [100] [100] ERICKSON E M, SCHIPPER F, TIAN R Y, et al. Enhanced capacity and lower mean charge voltage of Li-rich cathodes for lithium ion batteries resulting from low-temperature electrochemical activation[J].RSC Adv, 2017, 7: 7116–7121.

    [101] [101] GUO H C, WEI Z, JIA K, et al. Abundant nanoscale defects to eliminate voltage decay in Li-rich cathode materials[J]. Energy Storage Mater, 2019, 16: 220–227.

    [102] [102] LI S Y, JI J P, LI Z H, et al. Pre-activation and defects introduced via citric acid to mitigate capacity and voltage fading in Li-rich cathode[J]. Z Anorg Allg Chem, 2020, 646(15): 1285–1291.

    [103] [103] CHEN R Y, REN S H, KNAPP M, et al. Disordered lithium-rich oxyfluoride as a stable host for enhanced Li+ intercalation storage[J].Adv Energy Mater, 2015, 5(9): 1401814.

    [104] [104] WANG X Y, HUANG Y Q, JI D S, et al. Structure evolution and thermal stability of high-energy-density Li-ion battery cathode Li2VO2F[J]. J Electrochem Soc, 2017, 164(7): 1552–1558.

    [105] [105] CAMBAZ M A, P. VINAYAN B, PERVEZ S A, et al. Suppressing dissolution of vanadium from cation-disordered Li2–xVO2F via a concentrated electrolyte approach[J]. Chem Mater, 2019, 31(19):7941–7950.

    [106] [106] K?LLQUIST I, MARTIN J F, NAYLOR A J, et al. Influence of electrolyte additives on the degradation of Li2VO2F Li-rich cathodes[J]. J Phys Chem C, 2020, 124(24): 12956–12967.

    [107] [107] BAUR C, KALLQUIST I, CHABLE J, et al. Improved cycling stability in high-capacity Li-rich vanadium containing disordered rock salt oxyfluoride cathodes[J]. J Mater Chem A, 2019, 7: 21244–21253.

    [108] [108] YABUUCHI A, TAKEUCHI M, NAKAYAMA M, et al.High-capacity electrode materials for rechargeable lithium batteries:Li3NbO4-based system with cation-disordered rocksalt structure[J].Proc Natl Acad Sci, 2015, 112( 25): 7650–7655.

    [109] [109] WANG R, LI X, LIU L, et al. A disordered rock-salt Li-excess cathode material with high capacity and substantial oxygen redox activity: Li1.25Nb0.25Mn0.5O2[J]. Electrochem Commun, 2015, 60:70–73.

    [110] [110] HOSHINO S, M. GLUSHENKOV A, ICHIKAWA S, et al. Reversible three-electron redox reaction of Mo3+/Mo6+ for rechargeable lithium batteries[J]. ACS Energy Lett, 2017, 2(4):733–738.

    [111] [111] TAKEDA N, HOSHIMO S, XIE L X, et al. Reversible Li storage for nanosize cation/anion-disordered rocksalt-type oxyfluorides: LiMoO2–xLiF (0≤x≤2) binary system[J]. J Power Sources, 2017,367: 122–129.

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    LIU Rixin, ZHANG Zhenjie, LI Haoyu, KE Bingyu, GUO Shaohua, ZHOU Haoshen. Recent Development on Lithium-Rich Cathode Materials for High Specific Energy Lithium-Ion Batteries[J]. Journal of the Chinese Ceramic Society, 2022, 50(1): 70

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    Received: Jul. 19, 2021

    Accepted: --

    Published Online: Nov. 14, 2022

    The Author Email: LIU Rixin (njuceas2018lrx@qq.com)

    DOI:10.14062/j.issn.0454-5648.20210645

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