Chinese Journal of Liquid Crystals and Displays, Volume. 39, Issue 6, 752(2024)

Preparation of dual-monomer high spatial frequency H-PDLC grating based on acrylic polymer

Ning ZHU, Jihong ZHENG*, Tong SHEN, Ke LI, and Yourong LIU
Author Affiliations
  • School of Optical-Electrical and Computer Engineering,University of Shanghai for Science and Technology,Shanghai 200093,China
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    Figures & Tables(15)
    Formation mechanism of holographic polymer dispersed liquid crystal grating
    Diagram of the reproduction of the Bragg angle of the transmissive volume hologram
    Schematic diagram of the liquid crystal cell
    Diagram of interference and detection optical path
    (a)Diffraction efficiency curves of monomers with different functionalities as exposure;(b)Comparison of the effects of different functional monomers on the diffraction efficiency of doped and undoped samples.
    Transmittance curves of gratings with different functionalities
    (a)Diffraction efficiency variation curves and(b)transmittance change curves of single-monomer and dual-monomer
    Chemical structural formulas of two monomers
    (a)Diffraction efficiency curve and(b)grating morphology of the sample at spatial frequency 2 941 lp/mm
    (a)Curves of diffraction efficiency versus initiator content(mass fraction);(b)Transmittance curves(w(RB)=0.8%,w(RB)=1.0%).
    Grating morphology images of grating samples with different initiator contents(mass fraction)
    AFM image of grating at the ration of w(RB)=1.0%
    Curves of wavelength response to bandwidth
    Grating sample image
    • Table 1. Materials of dual-monomer system

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      Table 1. Materials of dual-monomer system

      成分名称化学式作用
      单体1TMPTACH2=CHCOOCH23CCH2CH3光聚合反应的主体
      单体2EP828C20H28ClNO4光聚合反应的主体
      液晶TEB50-提供折射率差、可电控
      光引发剂RBC20H2Cl4I4Na2O5吸收光子、引发光聚合
      交联剂NVPC₆H₉NO改善体系聚合速率
      协引发剂NPGC5H12O2控制单体自由基固化速率
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    Ning ZHU, Jihong ZHENG, Tong SHEN, Ke LI, Yourong LIU. Preparation of dual-monomer high spatial frequency H-PDLC grating based on acrylic polymer[J]. Chinese Journal of Liquid Crystals and Displays, 2024, 39(6): 752

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    Paper Information

    Category: Research Articles

    Received: Apr. 9, 2024

    Accepted: --

    Published Online: Jul. 30, 2024

    The Author Email: Jihong ZHENG (jihongzheng@usst.edu.cn)

    DOI:10.37188/CJLCD.2024-0114

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