Chinese Journal of Lasers, Volume. 52, Issue 12, 1202202(2025)

Preparation and Photocatalytic Performance of Porous Ti-Based Electrodes via Laser Cladding and Dealloying

Yihou Xiang1,2,3, Jinghui Wang1,2,3, Yongyong Fang1,2,3, Guolong Wu1,2,3, and Jianhua Yao1,2,3、*
Author Affiliations
  • 1Institute of Laser Advanced Manufacturing, Zhejiang University of Technology, Hangzhou 310023, Zhejiang , China
  • 2Key Laboratory of Special Purpose Equipment and Advanced Processing Technology, Ministry of Education and Zhejiang Province, Zhejiang University of Technology, Hangzhou 310023, Zhejiang , China
  • 3College of Mechanical Engineering, Zhejiang University of Technology, Hangzhou 310023, Zhejiang , China
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    Figures & Tables(11)
    E-pH diagram of Cu and Ti
    SEM images of powders used in laser cladding. (a) Cu powder; (b) Ti powder; (c) SEM image of Cu-Ti mixed powder; (d) EDS image of Cu-Ti mixed powder
    Flow for preparation of porous Ti-based electrodes via laser cladding and dealloying composite process
    Macroscopic images of Cu-Ti alloys with different compositions prepared by laser cladding
    XRD spectra of Cu-Ti alloys with different compositions prepared by laser cladding
    Anodic polarization curves of Cu-Ti alloys with inset illustrating schematic of active dissolution potential (Ea), passivation potential (Ep), and overpassivation potential (Et) in polarization curve
    Comparison of constant potential treatment results for Cu-Ti alloys with different compositions. (a) Cu68Ti32 treated at 1.0 V for 7 h; (b) Cu33Ti67 treated at 1.8 V for 21 h; (c) Cu28Ti72 treated at 2.0 V for 21 h
    Relationship between characteristic potential and alloy composition of Cu-Ti alloy
    Photocatalytic performance of Cu68Ti32 porous structure. (a) Ultraviolet-visible absorption spectrum; (b) instantaneous photocurrent without bias; (c) instantaneous photocurrent at 0.3 V bias; (d) Nyquist plot
    • Table 1. Process parameters

      View table

      Table 1. Process parameters

      x(0, 68][73, 77][83, 100)
      Laser power /W600750850
    • Table 2. Phase compositions of Cu-Ti alloys

      View table

      Table 2. Phase compositions of Cu-Ti alloys

      CuxTi100-x alloyPhase
      Cu87Ti13Cu4TiCu
      Cu83Ti17Cu4TiCu
      Cu77Ti23Cu4TiCu
      Cu73Ti27Cu2TiCu4TiCu
      Cu68Ti32Cu4Ti3Cu4TiCu3Ti
      Cu63Ti37TiCu2TiCu4Ti
      Cu58Ti42TiCuTiCu4Ti3Cu2TiCu4Ti
      Cu52Ti48TiCuTiCu4Ti3Cu2Ti
      Cu47Ti53TiCuTi
      Cu42Ti58CuTi2TiCuTi
      Cu33Ti67CuTi2TiCuTi
      Cu28Ti72CuTi2TiCuTi
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    Yihou Xiang, Jinghui Wang, Yongyong Fang, Guolong Wu, Jianhua Yao. Preparation and Photocatalytic Performance of Porous Ti-Based Electrodes via Laser Cladding and Dealloying[J]. Chinese Journal of Lasers, 2025, 52(12): 1202202

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    Paper Information

    Category: Laser Surface Machining

    Received: Dec. 9, 2024

    Accepted: Feb. 20, 2025

    Published Online: May. 22, 2025

    The Author Email: Jianhua Yao (laser@zjut.edu.cn)

    DOI:10.3788/CJL241426

    CSTR:32183.14.CJL241426

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