Chinese Journal of Liquid Crystals and Displays, Volume. 38, Issue 12, 1631(2023)

Research status of the blue InP and ZnSe quantum dots for electroluminescent quantum-dot light-emitting diodes

Shu-qi YANG1, Fang-hai LIU1, Ping CHEN1, and Lei CHEN1,2、*
Author Affiliations
  • 1School of Materials Science and Engineering, Hefei University of Technology, Hefei 230009, China
  • 2Intelligent Manufacturing Institute of HFUT, Hefei 230051, China
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    Figures & Tables(7)
    (a)Schematic illustration of synthetic procedure of blue InPESC@ZnS QDs;(b)Schematic of the InPESC@ZnS device structure;(c)Corresponding energy band diagram;(d)Current density-voltage-luminance curves of the device;(e)EL spectra of a QLED at increasing operating voltages[36];(f)Schematic illustration of the synthesis of blue InP/ZnS/ZnS QDs;(g)Energy-band diagram of the QLED;(h)UPS spectra of secondary-electron cut-off regions and valence band edge regions for InP/ZnS/ZnS QD films;(i)Normalized EL and PL spectra;(j)Current density and luminance versus driving voltage characteristics[38].
    (a)Schematic synthesis of blue-emitting InP/ZnS QDs with Cu-assisted process[39];(b)Schematic illustration for the synthesis of InP/ZnS/ZnS quantum dots;(c)Energy band diagram of the quantum dot light-emitting diodes;(d)Normalized PL and EL spectra;(e)Current density-voltage-luminance curves;(f)EQE-Current density curves[40].
    (a)Energy levels of InP,GaP and ZnS,and the lattice mismatch values between them and schematic diagram of the synthesis process of InP/GaP/ZnS//ZnS with thick shell structure;(b)Energy level illustration for each layer materials of QLEDs;(c)EL spectra and highly bright EL emission from one emitting spot of devices at different voltages[9];(d)Schematic of InP/GaP/ZnS reaction scheme presented in the top panel,the expected quantum dot structure at each reaction step is shown in the panel below;(e)Schematic of the InP/GaP/ZnS multilayered all-solution processed QLED;(f)Normalized PL and EL spectra;(g)Current density-voltage-luminance characteristics;(h)Current efficiency and external quantum efficiency as a function of the current density [44].
    (a)Absorption and photoluminescence spectra of the QDs;(b)Schematic of the synthesis procedure of the large-size ZnSe/ZnS/ZnS core/shell/shell QDs[51];(c)Energy level diagram Schematic;(d)Effect of ZnS shell thickness on electron and hole injection efficiency in the device;Different ZnS shell thicknesses of quantum dots(e)UV-absorption spectra and(f)photoluminescene spectra;Different ZnSe thicknesses of quantum dots(g)normalized electroluminescence spectra and(h)current density-voltage curve[41].
    (a)Schematic diagram of the syntheses of the ZnSeTe core and ZnSeTe/ZnSe/ZnS QDs without hydrofluoric acid(HF);(b)Representative schematic illustration of the ligand exchange from oleic acid(OA)to alkanethiol ligands;(c)Absorbance and photoluminescence spectra of C/S/S QDs depending on the HF treatment[53];(d)Schematic diagram of the Br passivation of unsaturated Zn on QD surface with a magnified area extracted from the red rectangular box;(e)Energy band diagram of each functional layer in QLEDs;(f)Steady-state photoluminescence of the pristine and pristine-Br QDs(inset:the fluorescent pictures of QD solution under UV-lamp);(g)EL spectra of the pristine and pristine-Br QDs[47].
    • Table 1. Recent advances of blue InP QDs and QLEDs

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      Table 1. Recent advances of blue InP QDs and QLEDs

      年份QDsPL峰/nmPLQY/%FWHM/nmLuminance/(cd·m-2EQE/%参考文献
      2007InP/ZnS4504090//33
      2012InP/ZnS475539//34
      2022InP/ZnS48352491 1621.436
      2020InP/ZnS/ZnS46845471401.737
      2022InP/ZnS/ZnS4659638910.1538
      2019InP/ZnS4252572//39
      2017InP/ZnS47765.943.790/30
      2022InP/ZnS/ZnS47493474222.640
      2016InP/GaP/ZnS4604050//42
      2020InP/GaP/ZnS48881453 1201.019
      2020InP/GaP/ZnS48545521 045144
      2023In(Zn)P/ZnS4663441//45
      2020InGaP/ZnSeS/ZnS46582471 0382.546
    • Table 2. Recent advances of blue ZnSe QDs and QLEDs

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      Table 2. Recent advances of blue ZnSe QDs and QLEDs

      年份QDsPL峰/nmPLQY/%FWHM/nmLuminance/(cd·m-2EQE/%参考文献
      2021ZnSe/ZnS/ZnS44453141002.6251
      2021ZnSe/ZnS446959.61 05512.224
      2020ZnSeTe/ZnSeS/ZnS45032412610.338
      2020ZnSeTe/ZnSe/ZnS445~4508016~253 2004.0652
      2021ZnSeTe/ZnSe/ZnS452~45790~9623~274 36618.641
      2020ZnTeSe/ZnSe/ZnS4571003688 90020.216
      2022ZnSeTe/ZnSe/ZnS4669450//53
      2023ZnSeTe/ZnSe/ZnS44386223325.4647
      2020ZnSeTe/ZnSe/ZnS44584272 9049.554
      2020ZnSe/ZnS43355224506.8849
      2022ZnSe/ZnS44393121 03113.648
      2020ZnS/ZnTeSe/ZnS446852314 1466.855
      2023ZnSe/ZnS455~4706016~25//56
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    Shu-qi YANG, Fang-hai LIU, Ping CHEN, Lei CHEN. Research status of the blue InP and ZnSe quantum dots for electroluminescent quantum-dot light-emitting diodes[J]. Chinese Journal of Liquid Crystals and Displays, 2023, 38(12): 1631

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    Paper Information

    Category: Research Articles

    Received: Sep. 8, 2023

    Accepted: --

    Published Online: Mar. 7, 2024

    The Author Email: Lei CHEN (shanggan2009@qq.com)

    DOI:10.37188/CJLCD.2023-0299

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