Chinese Journal of Liquid Crystals and Displays, Volume. 38, Issue 12, 1631(2023)
Research status of the blue InP and ZnSe quantum dots for electroluminescent quantum-dot light-emitting diodes
Fig. 1. (a)Schematic illustration of synthetic procedure of blue InPESC@ZnS QDs;(b)Schematic of the InPESC@ZnS device structure;(c)Corresponding energy band diagram;(d)Current density-voltage-luminance curves of the device;(e)EL spectra of a QLED at increasing operating voltages[36];(f)Schematic illustration of the synthesis of blue InP/ZnS/ZnS QDs;(g)Energy-band diagram of the QLED;(h)UPS spectra of secondary-electron cut-off regions and valence band edge regions for InP/ZnS/ZnS QD films;(i)Normalized EL and PL spectra;(j)Current density and luminance versus driving voltage characteristics[38].
Fig. 2. (a)Schematic synthesis of blue-emitting InP/ZnS QDs with Cu-assisted process[39];(b)Schematic illustration for the synthesis of InP/ZnS/ZnS quantum dots;(c)Energy band diagram of the quantum dot light-emitting diodes;(d)Normalized PL and EL spectra;(e)Current density-voltage-luminance curves;(f)EQE-Current density curves[40].
Fig. 3. (a)Energy levels of InP,GaP and ZnS,and the lattice mismatch values between them and schematic diagram of the synthesis process of InP/GaP/ZnS//ZnS with thick shell structure;(b)Energy level illustration for each layer materials of QLEDs;(c)EL spectra and highly bright EL emission from one emitting spot of devices at different voltages[9];(d)Schematic of InP/GaP/ZnS reaction scheme presented in the top panel,the expected quantum dot structure at each reaction step is shown in the panel below;(e)Schematic of the InP/GaP/ZnS multilayered all-solution processed QLED;(f)Normalized PL and EL spectra;(g)Current density-voltage-luminance characteristics;(h)Current efficiency and external quantum efficiency as a function of the current density [44].
Fig. 4. (a)Absorption and photoluminescence spectra of the QDs;(b)Schematic of the synthesis procedure of the large-size ZnSe/ZnS/ZnS core/shell/shell QDs[51];(c)Energy level diagram Schematic;(d)Effect of ZnS shell thickness on electron and hole injection efficiency in the device;Different ZnS shell thicknesses of quantum dots(e)UV-absorption spectra and(f)photoluminescene spectra;Different ZnSe thicknesses of quantum dots(g)normalized electroluminescence spectra and(h)current density-voltage curve[41].
Fig. 5. (a)Schematic diagram of the syntheses of the ZnSeTe core and ZnSeTe/ZnSe/ZnS QDs without hydrofluoric acid(HF);(b)Representative schematic illustration of the ligand exchange from oleic acid(OA)to alkanethiol ligands;(c)Absorbance and photoluminescence spectra of C/S/S QDs depending on the HF treatment[53];(d)Schematic diagram of the Br passivation of unsaturated Zn on QD surface with a magnified area extracted from the red rectangular box;(e)Energy band diagram of each functional layer in QLEDs;(f)Steady-state photoluminescence of the pristine and pristine-Br QDs(inset:the fluorescent pictures of QD solution under UV-lamp);(g)EL spectra of the pristine and pristine-Br QDs[47].
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Shu-qi YANG, Fang-hai LIU, Ping CHEN, Lei CHEN. Research status of the blue InP and ZnSe quantum dots for electroluminescent quantum-dot light-emitting diodes[J]. Chinese Journal of Liquid Crystals and Displays, 2023, 38(12): 1631
Category: Research Articles
Received: Sep. 8, 2023
Accepted: --
Published Online: Mar. 7, 2024
The Author Email: Lei CHEN (shanggan2009@qq.com)