Chinese Journal of Lasers, Volume. 46, Issue 9, 911001(2019)

Rapid Quantitative Analysis of Element Content Ratios in Cu(In,Ga)Se2 Thin Films Using Laser-Induced Breakdown Spectroscopy

Liu Shiming, Xiu Junshan*, and Liu Yunyan
Author Affiliations
  • School of Physics and Optoelectronic Engineering, Shandong University of Technology, Zibo, Shandong 255049, China
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    Figures & Tables(8)
    LIBS experimental setup for detecting CIGS thin films
    Relationship between spectral line intensity and bombardment times of 327.39 nm Cu atomic radiation spectral line during 20 consecutive laser bombardments
    LIBS spectra of CIGS thin films. (a) 280-305 nm; (b) 320-334 nm; (c) 402-420 nm; (d) 505-530 nm; (e) 570-580 nm; (f) 775-810 nm
    Relationship among spectral line intensity ratio, atomic ratio, and sputtering time. (a) Relationship between spectral line intensity ratio and sputtering time; (b) relationship between atomic ratio and sputtering time
    Calibration curves of atom ratios of elements in CIGS thin films. (a) P1; (b) P2
    Transmission analysis of CIGS thin films at different sputtering time
    Relationship among P1, forbidden bandwidth, and sputtering time
    • Table 1. EDS values of CIGS thin films deposited at different sputtering time

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      Table 1. EDS values of CIGS thin films deposited at different sputtering time

      Sputtering time /minAtomic fraction /%A1A2
      CuInGaSe
      516.5017.1107.4858.9100.3040.67
      1018.4216.0056.8058.7700.2980.81
      2021.3318.2907.2453.1350.2840.84
      3020.5318.2756.9454.2550.2750.81
      4021.7619.4156.2652.5700.2440.85
      5022.3918.7456.7852.0800.2660.88
      5522.5917.7887.2452.3900.2890.90
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    Liu Shiming, Xiu Junshan, Liu Yunyan. Rapid Quantitative Analysis of Element Content Ratios in Cu(In,Ga)Se2 Thin Films Using Laser-Induced Breakdown Spectroscopy[J]. Chinese Journal of Lasers, 2019, 46(9): 911001

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    Paper Information

    Category: spectroscopy

    Received: Mar. 5, 2019

    Accepted: --

    Published Online: Sep. 10, 2019

    The Author Email: Junshan Xiu (xiujunshan@126.com)

    DOI:10.3788/CJL201946.0911001

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