Spectroscopy and Spectral Analysis, Volume. 41, Issue 12, 3808(2021)

X-Ray Fluorescence Spectroscopy Combined With SEM-EDS Analysis to Glaze Composition of Glazed Tiles in Yuan Dynasty

Ruo-yu SHI1、*, Rui WEN1、1; *;, Xiang GAO2、2;, Wen-xuan WANG1、1;, Li-ge BAO3、3;, Xue-feng ZHAO4、4;, Zi-xuan LI1、1;, Kun CAO1、1;, Wei XIAO1、1;, and Yu-long LI1、1;
Author Affiliations
  • 11. Key Laboratory of Cultural Heritage Research and Conservation (Northwest University), School of Cultural Heritage (Northwest University), Xi’an 710127, China
  • 22. School of Chemistry and Materials Science, Northwest University, Xi’an 710075, China
  • 33. Yuan Shangdu Cultural Heritage Administration, Xilingol League 027200, China
  • 44. Management Office of Yuan Zhongdu Heritage Protection Zone, Zhangjiakou 076450, China
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    Figures & Tables(10)
    Sample YSDG-005 at site of Yuan Shangdu
    Sample YZDY-011 at site of Yuan Zhongdu
    Sample YSDB-003 at site of Yuan Shangdu
    Sample YSDG-002 at site of Yuan Shangdu
    Composition of PbO-SiO2-K2O in turquoise glazes during Jin to Ming Dynasty
    Rate of Pb/Si in green glaze during Tang, Period Song and Yuan
    Rate of Pb/Si in yellow glaze during Yuan, Ming and Qing Dynasty
    Micro structures of the glazes in Yuan Dynasty
    • Table 1. Major and minor chemical composition of glazes in Yuan Dynasty/Wt%

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      Table 1. Major and minor chemical composition of glazes in Yuan Dynasty/Wt%

      样品编号釉色Na2OMgOAl2O3SiO2K2OCaOTiO2MnOFe2O3CuOPbO
      YSDB-0012.180.494.6640.895.958.050.090.021.124.3132.71
      YSDB-0022.550.458.2438.957.358.280.390.032.172.7729.24
      YSDB-0031.940.444.8342.065.946.030.120.010.984.2933.79
      YSDG-001绿0.000.394.7431.350.391.090.090.031.052.8057.58
      YSDG-002绿0.000.345.3634.600.932.130.170.011.012.5152.50
      YSDG-003绿0.630.355.0041.570.671.270.090.040.882.3646.70
      YSDG-004绿0.740.414.0631.560.681.300.070.020.942.8357.33
      YSDG-005绿0.000.403.8632.650.101.280.080.000.822.9557.80
      YSDG-006绿0.860.404.5133.370.851.160.040.010.952.9054.86
      YSDG-007绿0.000.394.6430.380.632.090.130.000.970.7460.02
      YSDG-008绿0.000.404.3530.970.282.260.100.020.890.9159.80
      YSDG-009绿0.750.424.7128.140.342.290.190.020.950.8661.30
      YZDG-001绿0.020.070.5233.410.030.320.040.010.721.7459.19
      YZDG-002绿0.020.521.0233.980.050.520.040.020.311.5357.89
      YZDG-003绿0.991.111.0234.180.030.340.080.030.321.0055.94
      YZDG-004绿0.021.992.5436.480.041.420.130.010.551.5152.07
      YZDG-005绿2.941.105.0135.860.041.130.110.020.421.2450.07
      YZDG-006绿2.232.074.5440.440.021.390.250.020.961.3644.70
      YZDG-007绿0.021.872.1637.410.070.770.060.020.281.3851.46
      YZDG-008绿1.122.063.7141.390.020.720.070.020.471.1546.37
      YZDG-009绿0.021.672.6338.160.040.950.140.020.681.4051.78
      YZDG-010绿0.191.284.5634.080.071.680.180.010.711.3053.75
      YZDG-011绿1.033.353.0133.170.031.920.120.000.621.2051.89
      YZDG-012绿0.375.642.4830.730.021.310.130.010.641.5054.44
      YZDG-013绿2.050.022.3135.140.001.680.140.020.521.6054.42
      YZDY-0011.500.820.9936.920.100.410.080.003.390.1852.43
      YZDY-0023.311.872.3034.790.070.270.100.012.620≸0450.91
      YZDY-0034.442.351.3833.320.040.250.070.013.000.0651.18
      YZDY-0040.282.633.0037.240.101.020.080.002.980.0850.28
      YZDY-0050.022.162.8437.290.131.540.130.023.150.0949.49
      YZDY-0060.462.331.6336.160.040.700.070.012.960.1053.02
    • Table 2. EDS results of the slips of samples in Yuan Dynasty/Wt%

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      Table 2. EDS results of the slips of samples in Yuan Dynasty/Wt%

      编号Na2OMgOAl2O3SiO2K2OCaOFe2O3CuOPbO
      YSDB-0023.33.6710.7825.867.1922.280.742.821.04
      YSDG-0051.541.323.825.342.1685.021.140.380.30
      YZDG-0030.781.172.805.802.2585.930.290.130.86
      YZDY-0061.542.083.215.462.7282.381.600.190.82
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    Ruo-yu SHI, Rui WEN, Xiang GAO, Wen-xuan WANG, Li-ge BAO, Xue-feng ZHAO, Zi-xuan LI, Kun CAO, Wei XIAO, Yu-long LI. X-Ray Fluorescence Spectroscopy Combined With SEM-EDS Analysis to Glaze Composition of Glazed Tiles in Yuan Dynasty[J]. Spectroscopy and Spectral Analysis, 2021, 41(12): 3808

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    Paper Information

    Category: Research Articles

    Received: Dec. 10, 2020

    Accepted: --

    Published Online: Dec. 17, 2021

    The Author Email: Ruo-yu SHI (sruoyu97@163.com)

    DOI:10.3964/j.issn.1000-0593(2021)12-3808-07

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