Chinese Optics Letters, Volume. 23, Issue 1, 011601(2025)

Linear optical characterization of meter-size zinc sulfide polycrystal

Xiaobo Zhao1, Kui Wu1、*, Dazhi Lu1、**, Cong Zhang2、***, Haohai Yu1, and Huaijin Zhang1
Author Affiliations
  • 1State Key Laboratory of Crystal Materials and Institute of Crystal Materials, Shandong University, Jinan 250100, China
  • 2Sinoma Synthetic Crystal (Shandong) Co., Ltd., Jinan 250000, China
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    Figures & Tables(7)
    (a) ZnS tablet with a size of 1 m × 2 m. (b) Polished transparent ZnS plate after HIP (Ø45 × 18 mm3). (c) Micro-structure from SEM and (d) surface morphology from SEM with the measured ZnS sample in the upper right corner (10 mm × 8 mm × 2 mm).
    (a) XRD patterns of the grown ZnS; (b) SEM image of the ZnS sample used for EDS analyses; (c) EDS analyses results for the sample shown in (b).
    Refractive index of ZnS polycrystalline along the growth direction.
    (a) ZnS transmission spectrum from the ultraviolet to infrared region. (b) Optical loss from 0.4–15 µm.
    • Table 1. Comparison of Measured and Fitted Refractive Indices

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      Table 1. Comparison of Measured and Fitted Refractive Indices

      λ (µm)Measured refractive indexFitted refractive index
      0.40472.52819662.527736001
      0.43582.47340182.474110722
      0.48002.42214882.422468522
      0.54612.37451152.374299764
      0.58752.35440812.354088187
      0.64382.33417862.33383809
      0.70652.31787972.317632451
      0.85212.29414092.294236568
      1.01402.27942932.279861088
      1.53002.26062782.260728303
      2.32502.25059972.250516680
    • Table 2. Different Expressions of the ZnS Sellmeier Equation

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      Table 2. Different Expressions of the ZnS Sellmeier Equation

      Ref.Sellmeier equation of ZnS materials
      [19]
      [20]
      [21]
      [22]
      This work
    • Table 3. Transmittance and Refractive Indices of Common Infrared Materials

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      Table 3. Transmittance and Refractive Indices of Common Infrared Materials

       Refractive index at 530 nmTransmittanceIR cut-off edge (µm)
      ZnS (this work)2.367775% at 0.4–12 µm14
      Silicon[26]3.42255% at 1.5–6.5 µm10
      Germanium[27]4.00350% at 2–10 µm12
      Sapphire[28]1.76888% at 0.16–4 µm5
      Magnesium fluoride[29]1.41391% at 3–7.5 µm10
      Calcium fluoride[30]1.43487% at 3–5 µm10
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    Xiaobo Zhao, Kui Wu, Dazhi Lu, Cong Zhang, Haohai Yu, Huaijin Zhang, "Linear optical characterization of meter-size zinc sulfide polycrystal," Chin. Opt. Lett. 23, 011601 (2025)

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    Paper Information

    Category: Optical Materials

    Received: Jun. 12, 2024

    Accepted: Jul. 29, 2024

    Posted: Jul. 30, 2024

    Published Online: Feb. 10, 2025

    The Author Email: Kui Wu (wukui@sdu.edu.cn), Dazhi Lu (dazhi.lu@sdu.edu.cn), Cong Zhang (zhangc_1984@163.com)

    DOI:10.3788/COL202523.011601

    CSTR:32184.14.COL202523.011601

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