Chinese Optics Letters, Volume. 22, Issue 11, 113801(2024)
Titanium hyperdoped black silicon prepared by femtosecond laser irradiation: first-principle calculations and experimental verification Editors' Pick
Fig. 1. Atomic configurations for (a) undoped crystal Si (Si64), (b) substitutional Ti-doped Si (TiSiSi63), and (c) interstitial Ti-doped Si (TiiSi64). The graphs below are the band structures for (d) Si64, (e) relaxed TiSiSi63, and (f) relaxed TiiSi64 compounds.
Fig. 2. Optical absorption coefficients for the Si64, TiSiSi63, and TiiSi64 compounds.
Fig. 3. (a) Absorptance spectra for the b-Si:Ti samples at different fluences and following RTA treatment at a temperature of 600°C. (b) Absorptance spectra for the b-Si:Ti samples (1.2 kJ/m2) before and after annealing under different temperatures, in which 25°C represents the unannealed sample of b-Si:Ti. The inset in (b) provides the variation in absorption at 1550 nm as a function of temperature.
Fig. 4. The obtained SEM images of the b-Si:Ti surface for different laser fluences at a rotation angle of 45° fabricated. (a) 1.2, (b) 2.5, (c) 4.5, and (d) 6.8 kJ/m2, whereas their corresponding high magnification images are presented in (e)–(h).
Fig. 5. (a) Raman spectra for the b-Si:Ti samples manufactured under different laser fluences and compared with Si substrate; (b) Raman spectra for the b-Si:Ti samples (1.2 kJ/m2) before annealing and after RTA treatment under different temperatures, in which 25°C represents an unannealed b-Si:Ti sample.
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Song Huang, Anmin Wu, Guanting Song, Jiaxin Cao, Jianghong Yao, Qiang Wu, Weiqing Gao, Jingjun Xu, "Titanium hyperdoped black silicon prepared by femtosecond laser irradiation: first-principle calculations and experimental verification," Chin. Opt. Lett. 22, 113801 (2024)
Category: Light-matter Interaction
Received: May. 10, 2024
Accepted: Jul. 10, 2024
Published Online: Nov. 28, 2024
The Author Email: Qiang Wu (wuqiang@nankai.edu.cn), Weiqing Gao (gaoweiqing@hfut.edu.cn)