Journal of the Chinese Ceramic Society, Volume. 53, Issue 4, 808(2025)

Anti-Reduction BaTiO3-Based Dielectric Ceramics for Multi-Layer Ceramic Capacitors

WANG Zhen1,2, HAO Hua1,2、*, JIANG Songsong1,2, ZHANG Jie2, CAO Minghe2, YAO Zhonghua1,2, GAN Xiaoyan1,2, and LIU Hanxing1,2
Author Affiliations
  • 1Sanya Science and Education Innovation Park, Wuhan University of Technology, Sanya 572000, Hainan, China
  • 2School of Material Science and Engineering, International School of Material Science and Engineering, State Key Laboratory of Advanced Technology for Materials Synthesis and Processing, Wuhan University of Technology, Wuhan 430070, China
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    References(27)

    [1] [1] ZHEN Y C, XIAO M J, CHENG X, et al. Defect control of Yb-doped dielectric ceramics on improving the reliability for MLCC application[J]. Ceram Int, 2023, 49(8): 12097–12104.

    [2] [2] ALKATHY M S, MILTON F P, GATASHEH M K, et al. Enhancing dielectric properties and thermal stability in microwave-synthesized Nd-modified Barium titanate nanoceramics for possible MLCC applications[J]. Appl Phys A, 2024, 130(6): 402.

    [3] [3] YUILE A, WISS E, BARTH D, et al. Simulation of mechanical stresses in BaTiO3 multilayer ceramic capacitors during desoldering in the rework of electronic assemblies using a framework of computational fluid dynamics and thermomechanical models[J]. Materials, 2024, 17(11): 2702.

    [5] [5] SUZUKI S, YAMAGUCHI S, DOI A, et al. Effect of alloying Ni inner electrodes on the leakage current degradation of BaTiO3-based multilayer ceramic capacitors[J]. Appl Phys Lett, 2020, 116(13): 132903.

    [6] [6] ZHANG J M, HAO Y N, LI H H, et al. Coating of crystalline BaTiO3 layer on Ni nanoparticles for multilayer ceramic capacitor electrode[J]. Adv Eng Mater, 2020, 22(10): 1901483.

    [7] [7] LI Z Q, WANG J X, YAN S G, et al. Preparation of X5R type Ni-MLCCs and capacitance response to combined out-field variations[J]. Ceram Int, 2023, 49(11): 17766–17775.

    [8] [8] HUANG X, WANG P F, ZHAO J W, et al. Significantly enhanced dielectric properties of BaTiO3-based ceramicsviasynergetic grain size and defect engineering[J]. Ceram Int, 2024, 50(9): 15202–15208.

    [9] [9] XU H F, WANG P F, LUAN S W, et al. Vacancy engineering for high tetragonal BaTiO3 synthesized by solid-state approaches[J]. Powder Technol, 2024, 444: 119955.

    [10] [10] LIU Q, HAO H, GUO Q H, et al. Enhanced breakdown strength of BaTiO3-based multilayer ceramic capacitor by structural optimization[J]. Rare Met, 2023, 42(8): 2552–2561.

    [11] [11] WANG M L, XUE K Y, ZHANG K, et al. Dielectric properties of BaTiO3-based ceramics are tuned by defect dipoles and oxygen vacancies under a reducing atmosphere[J]. Ceram Int, 2022, 48(15): 22212–22220.

    [12] [12] XU K, ZHU G S, XU H R, et al. The colossal permittivity effect on BaTiO3 induced by different sinter atmosphere[J]. Appl Phys A, 2022, 128(12): 1044.

    [13] [13] MURAKAMI S, AHMED N T A F, WANG D W, et al. Optimising dopants and properties in BiMeO3 (Me = Al, Ga, Sc, Y, Mg2/3Nb1/3, Zn2/3Nb1/3, Zn1/2Ti1/2) lead-free BaTiO3–BiFeO3 based ceramics for actuator applications[J]. J Eur Ceram Soc, 2018, 38(12): 4220–4231.

    [14] [14] LUO Z P, HAO H, CHEN C, et al. Dielectric and anti-reduction properties of (1–x)BaTiO3–xBi(Zn0.5Y0.5)O2.75 ceramics for BME- MLCC application[J]. J Alloys Compd, 2019, 794: 358–364.

    [15] [15] ZHANG J, HAO H, GUO Q H, et al. Dielectric and anti-reduction properties of BaTiO3-based ceramics for MLCC application[J]. Ceram Int, 2023, 49(15): 24941–24947.

    [16] [16] LI D, GUO Q, CAO M, et al. The influence of A/B-sites doping on antiferroelectricity of PZO energy storage films[J]. Microstructures, 2023, 3(1): 2023007.

    [18] [18] WANG Z, HAO H, PENG F, et al. Defect evolution and effect on structure and electric properties of A/B site Sm doped BaTiO3 sintered in different atmospheres[J]. J Alloys Compd, 2023, 945: 169211.

    [19] [19] WANG X H, CHEN R Z, ZHOU H, et al. Dielectric properties of BaTiO3-based ceramics sintered in reducing atmospheres prepared from nano-powders[J]. Ceram Int, 2004, 30(7): 1895–1898.

    [22] [22] SASIKUMAR S, RAJARAM M, NATARAJAN A, et al. Architecting B-site Ni doped BaTiO3 photocatalyst for environmental remediation: Enhanced photodegradation performance[J]. Mater Sci Semicond Process, 2024, 174: 108222.

    [23] [23] ZHANG F, TAN J H, WANG P F, et al. Defect dipole engineering enhanced the dielectric performance and reliability of Mn-doped BaTiO3-based multilayer ceramic capacitor[J]. Ceram Int, 2024, 50(20): 38263–38273.

    [24] [24] ZHANG Z R, HUANG X, YANG J, et al. Investigation of coherent interface on relaxation behavior and reliability of Mg-doped BaTiO3 dielectric ceramics: Experiments and first-principle calculations[J]. J Eur Ceram Soc, 2024, 44(13): 7630–7641.

    [26] [26] XUE K Y, XIE J L, WANG M L, et al. Defect structure and dielectric properties of Mn-doped X8R BaTiO3-based ceramics with high permittivity: Experiments and first-principle calculations[J]. Ceram Int, 2023, 49(11): 16514–16523.

    [27] [27] SHEN Z B, WANG X H, GONG H L, et al. Effect of MnO2 on the electrical and dielectric properties of Y-doped Ba0.95Ca0.05Ti0.85Zr0.15O3 ceramics in reducing atmosphere[J]. Ceram Int, 2014, 40(9): 13833–13839.

    [28] [28] ZHU H, LI K, CHEN M L, et al. A melamine formaldehyderesin route toin situencapsulate Co2O3 into carbon black for enhanced oxygen reduction in alkaline media[J]. Int J Hydrog Energy, 2017, 42(41): 25960–25968.

    [29] [29] SOMPALLI N K, LI Y, LI J, et al. An innovative triple interface reinforced photocatalytic system based on BiOCl/BaTiO3@Co-BDC -MOF composite for the simultaneous detoxification of Cr(VI) and sulfamethoxazole[J]. Environ Res, 2024, 259: 119532.

    [30] [30] GU Y, ZHANG F Q, WU W H, et al. Microstructure regulation and failure mechanism study of BaTiO3-based dielectrics for MLCC application[J]. J Adv Dielect, 2023, 13(2): 2350002.

    [31] [31] SONG H, GOUD J P, YE J, et al. Review of the thermally stimulated depolarization current (TSDC) technique for characterizing dielectric materials[J]. J Korean Ceram Soc, 2023, 60(5): 747–759.

    [32] [32] BISHOP S, BLEA M, PERETTI A, et al. Oxygen vacancy migration and impact on high voltage DC polarization in BaTiO3–Bi(Zn, Ti)O3[C]//ACerS EMA 2023 - Orlando, Florida, United States of America - January - 2023. US DOE, 2023: 6192–6203.

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    WANG Zhen, HAO Hua, JIANG Songsong, ZHANG Jie, CAO Minghe, YAO Zhonghua, GAN Xiaoyan, LIU Hanxing. Anti-Reduction BaTiO3-Based Dielectric Ceramics for Multi-Layer Ceramic Capacitors[J]. Journal of the Chinese Ceramic Society, 2025, 53(4): 808

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    Paper Information

    Special Issue:

    Received: Nov. 28, 2024

    Accepted: May. 29, 2025

    Published Online: May. 29, 2025

    The Author Email: HAO Hua (haohua@whut.edu.cn)

    DOI:10.14062/j.issn.0454-5648.20240752

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