Journal of Inorganic Materials, Volume. 37, Issue 10, 1065(2022)

Mn-HAP SCR Catalyst: Preparation and Sulfur Resistance

Yaling CHEN1,2, Song SHU1,2, Shaoxin WANG1,2, and Jianjun LI1,2、*
Author Affiliations
  • 11. College of Architecture and Environment, Sichuan University, Chengdu 610000, China
  • 22. National Engineering Research Center for FGD, Chengdu 610000, China
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    Figures & Tables(10)
    Schematic illustration for preparing and poisoning catalysts
    Schematic illustration of denitration activity evaluation device
    (a) SCR activity of CPF, CPM, CPA, and HAP, and sulfur resistance test of CPF and (b) stability test of CPF
    (a) XRD patterns and (b) DTG curves of catalysts
    (a) N2 adsorption-desorption isotherms and (b) pore size distributions of CPF, CPM, and CP
    (a) Mn2p and (b) O1s XPS spectra of CPF, CPM and CPA
    (a) H2-TPR and (b) NH3-TPD curves of CPF, CPM and CPA
    • Table 1. Activity comparison of different catalysts

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      Table 1. Activity comparison of different catalysts

      CatalystPreparation methodNO conversion/%Temperature and conditionRef.
      Mn-HAPCo-preparation62.60140 ℃, 200×10-6 SO2, 2 h This research
      NB-C-PHydrothermal45.00150 ℃, 250×10-6 SO2, 2 h [20]
      MnO2Oxalic acid co-precipitation17.65150 ℃, 200×10-6 SO2, 2 h [21]
      MnCrOxHydrothermal redox reaction37.46150 ℃, 50×10-6 SO2, 2 h [22]
    • Table 2. Physical parameters of fresh catalysts and toxic catalysts

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      Table 2. Physical parameters of fresh catalysts and toxic catalysts

      SampleSpecific area/ (m2·g-1) Pore volume/ (cm3·g-1) Average pore size/nm
      CPF153.60.550013.49
      CPM117.30.460014.11
      CPA133.20.430011.57
    • Table 3. XPS results of Mn and O on the surface of fresh catalysts and toxic catalysts

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      Table 3. XPS results of Mn and O on the surface of fresh catalysts and toxic catalysts

      SampleOMn
      Olatt/O Oads/O Oads/OlattMn2+/Mn Mn3+/Mn Mn4+/Mn
      CPF0.90500.09500.10500.065100.16700.7300
      CPM0.92100.07900.08600.100000.59000.3100
      CPA0.87600.12300.14100.135000.22400.6410
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    Yaling CHEN, Song SHU, Shaoxin WANG, Jianjun LI. Mn-HAP SCR Catalyst: Preparation and Sulfur Resistance[J]. Journal of Inorganic Materials, 2022, 37(10): 1065

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    Paper Information

    Category: RESEARCH ARTICLE

    Received: Jan. 13, 2022

    Accepted: --

    Published Online: Jan. 12, 2023

    The Author Email: Jianjun LI (jjli@scu.edu.cn)

    DOI:10.15541/jim20220020

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