Laser & Optoelectronics Progress, Volume. 56, Issue 23, 233002(2019)

Mid-Infrared Spectroscopy Detection of Methanol Content in Methanol Gasoline Based on CARS Band Screening

Jun Hu, Yande Liu*, Aiguo Ouyang, and Hongliang Liu
Author Affiliations
  • School of Mechatronics and Vehicle Engineering, East China Jiaotong University, Nanchang, Jiangxi 330013, China
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    Figures & Tables(12)
    Flow chart of mid-infrared detection model for determining methanol content of methanol gasoline
    Original mid-infrared spectra of gasoline and absolute methanol. (a) Mid-infrared spectrum of gasoline; (b) mid-infrared spectrum of absolute methanol
    Original mid-infrared spectra of methanol gasoline with different methanol volume fractions
    Band selected by UVE method. (a) Band selection in full spectrum; (b) band points selected in full spectrum
    Wavelength variable screening based on CARS algorithm. (a) Number of variables versus sampling times; (b) RMSECV value versus sampling times; (c) regression coefficient versus sampling times
    Band points selected by CARS method within full spectrum
    Frequency of each wavelength being selected
    RMSECV varying with number of variables
    Scatter plots of methanol content in methanol gasoline predicted by CARS-PLS model. (a) Calibration set; (b) prediction set
    • Table 1. Methanol volume fractions of samples in calibration and prediction sets

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      Table 1. Methanol volume fractions of samples in calibration and prediction sets

      Data setNMinimum /%Maximum /%Mean /%RSD /%
      Total1200.6018.609.415.37
      Calibration900.6018.609.435.25
      Prediction300.6018.609.335.45
    • Table 2. Calibration effect of PLS corrected by middle infrared spectra of methanol gasoline

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      Table 2. Calibration effect of PLS corrected by middle infrared spectra of methanol gasoline

      PretreatmentmethodPCRcRMSECRpRMSEP
      Original90.9811.0290.9331.925
      S-G130.9970.3750.9441.772
      MSC100.9960.4500.9401.843
      SNV30.9621.4400.8732.871
    • Table 3. Comparison of calibration effects of different wavelength screening methods combined with PLS method

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      Table 3. Comparison of calibration effects of different wavelength screening methods combined with PLS method

      MethodNumber of wavelengthsPCRcRMSECRpRMSEP
      PLS1557130.9970.3750.9441.772
      UVE-PLS135100.9721.2320.9481.777
      CARS-PLS11890.9940.5630.9781.177
      GA-PLS130110.9830.9940.9561.527
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    Jun Hu, Yande Liu, Aiguo Ouyang, Hongliang Liu. Mid-Infrared Spectroscopy Detection of Methanol Content in Methanol Gasoline Based on CARS Band Screening[J]. Laser & Optoelectronics Progress, 2019, 56(23): 233002

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    Paper Information

    Category: Spectroscopy

    Received: Apr. 12, 2019

    Accepted: Jun. 3, 2019

    Published Online: Nov. 27, 2019

    The Author Email: Yande Liu (jxliuyd@163.com)

    DOI:10.3788/LOP56.233002

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