Laser & Optoelectronics Progress, Volume. 59, Issue 15, 1516020(2022)

Research Progress on Rare-Earth-Doped Ultraviolet Upconversion Materials and Lasers

Haoyu Wang1、†, Xusheng Qiao†、*, and Xianping Fan
Author Affiliations
  • School of Materials Science and Engineering, Zhejiang University, Hangzhou 310027, Zhejiang , China
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    Figures & Tables(17)
    Mechanism of upconversion process. (a) ESA; (b) ETU; (c) CET; (d) PA; (e) EMU
    Gd-CSYS2S3 core-shell nanocrystal. (a) Structure diagram; (b) HAADF-STEM and HR-TEM image; (c) UV upconversion emission spectra under 808 nm continuouswave laser[47]
    Ba2LaF7∶Yb3+/Tm3+ nanocrystal. (a) TEM image; (b) corresponding size distribution[22]
    Relationship between the multiphonon nonradiative relaxation rate of rare earth ions and the energy gap in materials with different average phonon energies[68]
    Energy transfer process of Gd-CSYS2S3@IR-806 under 808 nm laser excitation [56]
    Upconversion spectra changes of 1% Tm3+ under excitation power of 104 W·cm-2 and 2.5×106 W·cm-2 [75]
    Upconversion luminescence of Tm3+ under 464 nm laser excitation. (a) Upconversion energy level diagram; (b) upconversion spectrum [59]
    Upconversion luminescence behavior of Ho3+ ions at different pulse widths and the curves of upconversion luminescence intensity with time in a pulse at different wavelengths[77]
    Upconversion emission intensity at 311 nm of the NaYF4 @ NaYbF4∶Tm/Gd NaYF4 nanoparticles as a function of excitation power for different excitation schemes[18]
    Experimental results. (a) Spectra of ultraviolet upconversion laser; (b) power-intensity curve of the cylindrical microcavity; (c) stability measurement of the cylindrical microcavity[22]
    Microlaser array. (a) Preparation process; (b) (c) TEM images [19]
    Experimental results. (a) UV emission spectra of 300 nm WGMs; (b) P-I curve corresponding to Fig.(a); (c) computer simulation of loss of WGMs to light of different wavelengths; (d) UV emission spectra of 130 nm WGMs; (e) P-I curve corresponding to Fig. (d); (f) loss of WGMs of different thicknesses to light of different wavelengths [19]
    ZBLAN upconversion fiber laser. (a) Schematic; (b) schematic diagram of the upconversion energy level of Tm3+ under the excited of 1064 nm laser[11]
    • Table 1. UV upconversion luminescent crystals and transparent ceramics

      View table

      Table 1. UV upconversion luminescent crystals and transparent ceramics

      ActivatorHostExcitation /nmEmission /nmCorresponding transitionRef.
      Pr3+Pr3+∶Y2SiO5 single crystal800

      270

      305

      4f5d→3H4,5,6

      4f5d→3F2,3

      38
      Er3+Er3+∶YAlO3 single crystal6523382H9/24I13/243
      Er3+Y2O3 ceramic532

      262

      276

      320

      4D5/24I15/2

      2H9/24I15/2

      2P3/24I15/2

      39
      Ho3+Y2O3 ceramic532

      306

      362

      3D35I8

      3D35I7

      4042
      Ho3+/Gd3+Y2O3 ceramic5323156PJ8S7/244
      Yb3+/Tm3+Langatate ceramic9733651D23H645
      Yb3+/Ho3+/Gd3+Y2O3 ceramic976

      309

      315

      6P5/28S7/2

      6P7/28S7/2

      46
    • Table 2. UV upconversion luminescent nanocrystals

      View table

      Table 2. UV upconversion luminescent nanocrystals

      ActivatorHostExcitation /nmEmission /nmCorresponding transitionRef.
      Ho3+YF3 NCs4502885D45I848
      Yb3+/Tm3+NaYbF4 NCs980

      291

      345

      1I63H6

      1I63F4

      49
      Yb3+/Tm3+LiYbF4 NCs9802891I63H619
      Yb3+/Tm3+Sr2YbF7 NCs9802901I63H650
      Yb3+/Tm3+NaYbF4 NCs9802901I63H651
      Yb3+/Ho3+NaYF4 NCs970

      247

      277

      287

      3F,5D)45I8

      3H,5D,1G)45I8

      5G,5D,3G)→5I8

      32
      Er3+/Gd3+BaGd2ZnO5 NCs532

      217

      254

      278

      4D1/28S7/2

      4D7/28S7/2

      2H9/28S7/2

      52
      Pr3+/Gd3+Lu6O5F8 NCs4503156P7/28S7/220
      Yb3+/Gd3+CaF2 NCs9803156P7/28S7/253
      Yb3+/Er3+/Gd3+NaYF4 NCs1560

      277

      306

      311

      6IJ8S7/2

      6P5/28S7/2

      6P7/28S7/2

      33
      Yb3+/Tm3+/Gd3+La2Zr2O7 NCs980

      265

      289

      6IJ8S7/2

      3P03H6

      54
      Yb3+/Tm3+/Gd3+YF3 NCs980

      204

      195

      6G7/28S7/2

      6G13/28S7/2

      55
      Yb3+/Tm3+/Gd3+NaYF4 NCs980

      277

      305

      311

      6IJ8S7/2

      6P5/28S7/2

      6P7/28S7/2

      34-36
      Nd3+/Yb3+/Tm3+/Gd3+Gd-CSYS2S3 NCs808

      311

      290

      273

      253

      6P7/28S7/2

      1I63H6

      6IJ8S7/2

      6DJ8S7/2

      4756
    • Table 3. UV upconversion luminescent glass and glass ceramics

      View table

      Table 3. UV upconversion luminescent glass and glass ceramics

      ActivatorHostExcitation /nmEmission /nmCorresponding transitionRef.
      Tm3+ZBLAN455

      292

      350

      363

      1I63H6

      1I63F4

      1D23H6

      59
      Tm3+ZBLAN4583661D23H663
      Tm3+ZBLAN1064

      365

      284

      1D23H6

      1I63H6

      11
      Tm3+Silica glass microspheres15273731D23H664
      Yb3+/Tb3+Fluorophosphate glass9803795D37F658
      Yb3+/Tb3+Oxyfluoride GC9803825D35G6)→7F665
      Yb3+/Er3+Oxyfluoride GC9733804G11/24I15/266
      Yb3+/Ho3+Oxyfluoride GC9803625G5/3H65I867
      Yb3+/Tm3+Oxyfluoride GC9802633P1,03H622
      Yb3+/Tm3+/Gd3+Oxyfluoride GC980

      311

      277

      253

      6P7/28S7/2

      6IJ8S7/2

      6DJ8S7/2

      61
      Yb3+/Tm3+/Gd3+Oxyfluoride GC980

      293

      277

      1I63H6

      6IJ8S7/2

      21
      Yb3+/Er3+/Gd3+/Eu3+Oxide GC9802486DJ8S7/262
    • Table 4. Ultraviolet upconversion laser material

      View table

      Table 4. Ultraviolet upconversion laser material

      ActivatorHostLaser resonatorLaser emission /nmLaser thresholdOutput power /μWSlope efficiency /%Quality factorRef.
      Tm3+ZBLANFiber Laser284200 mW42911
      Yb3+/Tm3+/Gd3+NaYF4 NCsWGM31186 mJ/cm2280018
      Yb3+/Tm3+LiYbF4 NCsWGM2897.42 mJ/cm2480019
      Pr3+/Gd3+Lu6O5F8 NCsRL31589.7 mJ/cm220
      Yb3+/Tm3+/Gd3+Oxyfluoride GCRL290141 mJ/cm221
      Yb3+/Tm3+Oxyfluoride GCRL26380 mJ/cm222
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    Haoyu Wang, Xusheng Qiao, Xianping Fan. Research Progress on Rare-Earth-Doped Ultraviolet Upconversion Materials and Lasers[J]. Laser & Optoelectronics Progress, 2022, 59(15): 1516020

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    Paper Information

    Category: Materials

    Received: Feb. 8, 2022

    Accepted: Mar. 24, 2022

    Published Online: Jul. 27, 2022

    The Author Email: Xusheng Qiao (qiaoxus@zju.edu.cn)

    DOI:10.3788/LOP202259.1516020

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