Journal of Inorganic Materials, Volume. 36, Issue 12, 1247(2021)
Tailoring MAX Phase Magnetic Property Based on M-site and A-site Double Solid Solution
Figures & Tables(6)
. Characterization results of (V, Nb)2(Sn, Fe)C after acid treatment
. XRD patterns of (a) (V, Nb)2(Sn, Co)C, (c) (V, Nb)2(Sn, Ni)C, and (e) (V, Nb)2(Sn, Mn)C after acid treatment; SEM-EDS elemental mappings of (b) (V, Nb)2(Sn, Co)C, (d) (V, Nb)2(Sn, Ni)C, and (f) (V, Nb)2(Sn, Mn)C after acid treatment
. Temperature dependent magnetization M-T curves for (a) V2(Sn, A)C and (b) V2(Sn, A)C (A = Fe, Co, Ni and Mn) at 0.1 T in the range of 2-100 K
. Magnetic hysteresis loops of V2(Sn, A)C and V2(Sn, A)C (A=Fe, Co, Ni and Mn) at different temperatures in the range from -1 to 1 T, respectively
Table 1. Lattice parameters and atomic percentage of element in MAX phases
View tableView in ArticleTable 1. Lattice parameters and atomic percentage of element in MAX phases
MAX phase Lattice parameter Element percentage/% Nb element in M site/% Magnetic element in A site/% a/nm c/nm c/a V Nb Sn A V2(Sn, Fe)C[ 23 ]0.2984 1.3345 4.4718 66.84 - 22.05 11.11 - 33.50 (V, Nb)2(Sn, Fe)C 0.3014 1.3447 4.4622 54.32 13.38 25.03 7.27 19.76 22.51 V2(Sn, Co)C[ 23 ]0.2989 1.3409 4.4864 66.36 - 22.44 11.19 - 33.28 (V, Nb)2(Sn, Co)C 0.3016 1.3419 4.4493 56.41 11.23 24.60 7.76 16.60 23.98 V2(Sn, Ni)C[ 23 ]0.2985 1.3357 4.4751 67.47 - 24.36 8.16 - 25.10 (V, Nb)2(Sn, Ni)C 0.3021 1.3413 4.4402 56.87 13.00 21.66 8.47 18.61 28.10 V2(Sn, Mn)C[ 23 ]0.2982 1.3403 4.4941 66.19 - 23.07 10.74 - 31.76 (V, Nb)2(Sn, Mn)C 0.3026 1.3509 4.4646 57.10 10.84 23.50 8.56 15.96 26.70
Table 2. Magnetic parameters of V2(Sn, A)C and (V, Nb)2(Sn, A)C (A = Fe, Co, Ni and Mn)
View tableView in ArticleTable 2. Magnetic parameters of V2(Sn, A)C and (V, Nb)2(Sn, A)C (A = Fe, Co, Ni and Mn)
MAX phase TC 2 K 20 K 40 K Hc Mr Ms Hc Mr Ms Hc Mr Ms V2(Sn, Fe)C 63 458 0.59 1.73 305 0.42 1.53 152 0.18 1.08 (V, Nb)2(Sn, Fe)C 63 238 0.48 1.79 174 0.37 1.67 73 0.14 1.24 V2(Sn, Co)C 66 314 0.34 1.19 224 0.26 1.05 113 0.12 0.79 (V, Nb)2(Sn, Co)C 53 378 0.49 1.11 240 0.33 1.00 134 0.17 0.71 V2(Sn, Ni)C 60 276 0.30 1.54 191 0.23 1.42 94 0.10 1.12 (V, Nb)2(Sn, Ni)C 53 140 0.29 2.07 96 0.19 1.83 45 0.07 1.34 V2(Sn, Mn)C 56 780 0.26 0.98 545 0.21 0.84 206 0.07 0.63 (V, Nb)2(Sn, Mn)C 57 117 0.06 0.97 75 0.04 0.90 32 0.01 0.67
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Xiao ZHANG, Youbing LI, Ke CHEN, Haoming DING, Lu CHEN, Mian LI, Rongrong SHI, Zhifang CHAI, Qing HUANG. Tailoring MAX Phase Magnetic Property Based on M-site and A-site Double Solid Solution[J]. Journal of Inorganic Materials, 2021, 36(12): 1247
Paper Information
Category: EDITORIAL
Received: Mar. 3, 2021
Accepted: --
Published Online: Sep. 16, 2022
The Author Email: Xiao ZHANG (zhangxiao18@lzu.edu.cn)
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