Laser & Optoelectronics Progress, Volume. 60, Issue 17, 1700004(2023)

Research Progress of Optical Fiber Sensors Based on Novel Fluorescent Materials: Dissolved Oxygen, pH, and Carbon Dioxide

Qiang Song1, Liang Wang1, Xiaoyin Zhang2, Yan Liu2, Jing Zhang2, and Xiangfeng Kong2、*
Author Affiliations
  • 1College of Chemistry and Chemical Engineering, Ocean University of China, Qingdao 266000, Shandong , China
  • 2Institute of Marine Instrumentation, Qilu University of Technology (Shandong Academy of Sciences), Qingdao 266000, Shandong , China
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    Figures & Tables(15)
    Schematic diagram of fluorescence excitation
    Basic structure and working principle of fluorescent optical fiber sensing system
    Detection principle of dissolved oxygen optical fiber sensor[16].(a) Schematic diagram of evanescent wave generation; (b) schematic diagram of dissolved oxygen detection process; (c) schematic diagram of instrumental setup and flow cell design
    Schematic diagram of luminescence process of lanthanide metal ions[26]
    Crystal structures[27].(a) Crystal structure of EuNDC; (b) tetrahedral crystal structure; (c) octahedral crystal structure
    Upper: pH responsive DAOTA dyes 1a and 1b in protonated form and reference DMQA dye 2; bottom: with light emitting diode (LED) light source, optical fiber connector, photodiode/sensor point and optical fiber spectrometer detector[40]
    Crystal structure and PXRD spectra[44].(a) Crystal structure of Tb-MOF; (b) PXRD patterns of as-synthesized Eu0.034Tb0.966-NMOF and Eu0.034Tb0.966-NMOF soaked in water with pH values of 3.00 and 11.00, and simulated Tb-MOF from X-ray single structure
    Diagram of preparation process of CDs@UiO-66 (OH)2 using solvent-free method[47]
    Spatial topology and fluorescence emission spectra[48].(a) Spatial topological structure of Zr-TCPBP; (b) fluorescence emission spectra of Zr-TCPBP in aqueous solution with pH of 1.10-6.70
    Schematic diagram of pH detection with LMOFl and γ-Fe2O3@LMOF1[49]
    Schematic diagram of pH response of MOF/PC materials[50]
    Scheme for synthesis of UIO-66-ONa by Schiff Base reaction[63]
    • Table 1. Summary of fluorescent dissolved oxygen optical fiber sensing research

      View table

      Table 1. Summary of fluorescent dissolved oxygen optical fiber sensing research

      Sensor typeFluorescent sensitive materialLinear concentration rangeSensitivityResponse timeReference
      DOPdTFPP0-40 mg/L21.700 (I0/I10011
      DOPdTCPP0-40 mg/L7.400 (I0/I10011
      DOPtTFPP0-40 mg/L6.500 (I0/I10011
      DOPtOEP0-40 mg/L9.200 (I0/I10011
      DOPtEEP0-40 mg/L0.4 s12
      DOPtTFPP0-15 mg/L10 s13
      DO[Ru(bpy)32+0-100%1.408 (I0/I10012 s16
      DORu (DPP)3Cl20-15 mg/L18
      DOTris(2,20-bipyridyl) ruthenium (Ⅱ)5-15 mg/L3.340 (I0/I10088 s20
      DODichlorotris (1,10-phenanthroline) Ruthenium (Ⅱ)0-44 mg/L7 min22
      O2EuNDC0-1.0 p O2 atm10 s29
      O2PEA2SnI450×10-6-5%10 s34
    • Table 2. Summary of fluorescent pH optical fiber sensing research

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      Table 2. Summary of fluorescent pH optical fiber sensing research

      Sensor typeFluorescent sensitive materialApplicable pH rangeSensitivityResponse timeReference
      pHDAOTA3.80-6.800.251 signal units per pH8 s40
      pHDLF-PEGDA3.79-9.550.680 signal units per pH43
      pHEu0.034Tb0.966-NMOFs3.00-7.0044
      pH{[Cd1.5(EDDA)]·(H3O)(H2O)3n2.00-11.5045
      pHZr-TCPBP1.10-6.7048
      pHLMOF13.00-7.0049
      pHMOF/PC3.00-7.0050
      pHDMF-Tb-Phen0.20-11.0151
      pHCdSe/ZnS4.00-12.000.500 pH unit52
      pHCR-ANPs1.00-7.007.950 Counts/pH53
      9.00-12.005.050 Counts/pH15 s
      pH

      Nitrogen-doped carbon dots

      (N-CDs)

      2.00-3.9215 s54
      8.00-13.0215 s
    • Table 3. Summary of fluorescent carbon dioxide optical fiber sensing research

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      Table 3. Summary of fluorescent carbon dioxide optical fiber sensing research

      Sensor typeFluorescent sensitive materialLinear concentration rangeSensitivityResponse timeReference
      CO2α-naphtholphthalein in polyIBM0-100%100 (I100/I023 s58
      CO2TPPS20%-100%83 s59
      CO2Phenol red0-100%144 (I100/I020 s60
      CO2UIO-66-ONa63
      CO2PAAChl625×10-664
      CO2nanoZIF-80.2%-100%A few seconds67
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    Qiang Song, Liang Wang, Xiaoyin Zhang, Yan Liu, Jing Zhang, Xiangfeng Kong. Research Progress of Optical Fiber Sensors Based on Novel Fluorescent Materials: Dissolved Oxygen, pH, and Carbon Dioxide[J]. Laser & Optoelectronics Progress, 2023, 60(17): 1700004

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    Paper Information

    Category: Reviews

    Received: Jul. 4, 2022

    Accepted: Sep. 15, 2022

    Published Online: Aug. 29, 2023

    The Author Email: Xiangfeng Kong (kxf_1985@163.com)

    DOI:10.3788/LOP221976

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