Spectroscopy and Spectral Analysis, Volume. 42, Issue 10, 3103(2022)

Determination of Trace Tellurium Content in Steel by Hydride Generation Atomic Fluorescence Spectrometry

Pan LIU1、1; 2;, Mi-fang DU1、1;, Zhi-ya LI1、1;, Ling-qing GAO1、1; 3;, Hua-yun HAN4、4;, and Xin-yao ZHANG1、1; 3;
Author Affiliations
  • 11. Luoyang Ship Material Research Institute, Luoyang 471023, China
  • 44. College of Chemistry and Molecular Engineering, Zhengzhou University, Zhengzhou 450000, China
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    Figures & Tables(7)
    Effect of spectral working parameters on fluorescence intensity and signal-to-noise ratio(a): Negative high voltage; (b): Lamp current; (c): Observation height; (d): Carrier gas flow; (e): Shielding gas flow
    Effect of acidity in solution on fluorescence intensity(a): Solution; (b): Carrier
    Effect of potassium borohydride concentration on fluorescence intensity
    Effect of iron matrix on fluorescence intensity
    Effect of coexisting ions on the determination of tellurium(a): Chromium; (b): Nickel; (c): Manganese; (d): Copper; (e): Molybdenum; (f): Tungsten; (g): Titanium; (h): Silicon; (i): Vanadium
    Calibration curve
    • Table 1. Determination results of tellurium in synthetic sample

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      Table 1. Determination results of tellurium in synthetic sample

      试样碲加入
      量/μg
      理论值/
      (μg·g-1)
      测定值/
      (μg·g-1)
      偏倚/
      (μg·g-1)
      GB/T 223.55
      允许差/
      (μg·g-1)
      6#0.101.251.290.040.3
      7#0.202.502.44-0.060.3
      8#0.506.256.19-0.061.0
      9#1.012.512.3-0.21.5
      10#2.025.024.9-0.11.5
      11#4.050.051.01.04.0
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    Pan LIU, Mi-fang DU, Zhi-ya LI, Ling-qing GAO, Hua-yun HAN, Xin-yao ZHANG. Determination of Trace Tellurium Content in Steel by Hydride Generation Atomic Fluorescence Spectrometry[J]. Spectroscopy and Spectral Analysis, 2022, 42(10): 3103

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    Paper Information

    Category: Research Articles

    Received: Aug. 9, 2021

    Accepted: Feb. 15, 2022

    Published Online: Nov. 23, 2022

    The Author Email:

    DOI:10.3964/j.issn.1000-0593(2022)10-3103-06

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