Researching | Manipulation strategy of cation inhomogeneity in perovskite solar cells

Journal of Semiconductors, Volume. 46, Issue 5, 050202(2025)

Manipulation strategy of cation inhomogeneity in perovskite solar cells

Jiale Sun¹, Xuxia Shai^1、*, Weitao chen¹, Shenchao Li¹, Jinlan He¹, Xinxing Liu², Dongmei He², Yue Yu², and Jiangzhao Chen^2、**

Author Affiliations

¹Institute of Physical and Engineering Science/Faculty of Science, Kunming University of Science and Technology, Kunming 650500, China

²Faculty of Materials Science and Engineering, Kunming University of Science and Technology, Kunming 650093, China

show less

Full Text Get PDF

Figures&Tables (2)

References (20)

Paper Information

References(20)

[1] Z L Zhang, Y S Feng, J K Ding et al. Rationally designed universal passivator for high-performance single-junction and tandem perovskite solar cells. Nat Commun, 16, 753(2025).

[2] Z J Ding, H Yang, S S Li et al. A-site cation segregation in alloyed perovskite solar cells. ACS Photonics, 11, 5061(2024).

[3] L Liu, J Z Lu, H Wang et al. A-site phase segregation in mixed cation perovskite. Mater Rep: Energy, 1, 100064(2021).

[4] K Y Yan, M Z Long, T K Zhang et al. Hybrid halide perovskite solar cell precursors: colloidal chemistry and coordination engineering behind device processing for high efficiency. J Am Chem Soc, 137, 4460(2015).

[5] R Quintero-Bermudez, A Gold-Parker, A H Proppe et al. Compositional and orientational control in metal halide perovskites of reduced dimensionality. Nat Mater, 17, 900(2018).

[6] X Zhang, R Munir, Z Xu et al. Phase transition control for high performance ruddlesden–popper perovskite solar cells. Adv Mater, 30, 1707166(2018).

[7] H X Dang, K Wang, M Ghasemi et al. Multi-cation synergy suppresses phase segregation in mixed-halide perovskites. Joule, 3, 1746(2019).

[8] C Zhu, X Niu, Y Fu et al. Strain engineering in perovskite solar cells and its impacts on carrier dynamics. Nat Commun, 10, 815(2019).

[9] N X Li, Y Q Luo, Z H Chen et al. Microscopic degradation in formamidinium-cesium lead iodide perovskite solar cells under operational stressors. Joule, 4, 1743(2020).

[10] J W Li, Q S Dong, N Li et al. Direct evidence of ion diffusion for the silver-electrode-induced thermal degradation of inverted perovskite solar cells. Adv Energy Mater, 7, 1602922(2017).

[11] K Wang, W S Subhani, Y L Wang et al. Metal cation in efficient perovskite solar cells: progress and perspective. Adv Mater, 31, 1902037(2019).

[12] L E Mundt, F Zhang, A F Palmstrom et al. Mixing matters: nanoscale heterogeneity and stability in metal halide perovskite solar cells. ACS Energy Lett, 7, 471(2022).

[13] Q Zhou, Y Y Yang, D M He et al. Simultaneous suppression of multilayer ion migration via molecular complexation strategy toward high-performance regular perovskite solar cells. Angew Chem Int Ed, 64, e202416605(2025).

[14] B B Liu, X D Ren, R Li et al. Chen. Stabilizing top interface by molecular locking strategy with polydentate chelating biomaterials toward efficient and stable perovskite solar cells in ambient air. Adv Mater, 36, 2312679(2024).

[15] J Cao, S X Tao, P A Bobbert et al. Interstitial occupancy by extrinsic alkali cation in perovskites and its impact on ion migration. Adv Mater, 30, 1707350(2018).

[16] H Z Lu, Y H Liu, P Ahlawat et al. Vapor-assisted deposition of highly efficient, stable black-phase FAPbI3 perovskite solar cells. Science, 370, b8985(2020).

[17] Z J Huang, Y Bai, X D Huang et al. Anion-π interactions suppress phase impurities in FAPbI3 solar cells. Nature, 623, 531(2023).

[18] Y Bai, Z J Huang, X Zhang et al. Initializing film homogeneity to retard phase segregation for stable perovskite solar cells. Science, 378, 747(2022).

[19] S W Liu, X Y Guan, W S Xiao et al. Effective passivation with size-matched Alkyldiammonium iodide for high-performance inverted perovskite solar cells. Adv Funct Mater, 32, 2205009(2022).

[20] Z Liang, Y Zhang, H F Xu et al. Homogenizing out-of-plane cation composition in perovskite solar cells. Nature, 624, 557(2023).

Tools

Get Citation

Copy Citation Text

Jiale Sun, Xuxia Shai, Weitao chen, Shenchao Li, Jinlan He, Xinxing Liu, Dongmei He, Yue Yu, Jiangzhao Chen. Manipulation strategy of cation inhomogeneity in perovskite solar cells[J]. Journal of Semiconductors, 2025, 46(5): 050202

Download Citation

EndNote(RIS)BibTex Plain Text

Set citation alerts for article

Save article for my favorites

Paper Information

Category: Research Articles

Received: Mar. 12, 2025

Accepted: --

Published Online: Jun. 4, 2025

The Author Email: Xuxia Shai (XXShai), Jiangzhao Chen (JZChen)

DOI:10.1088/1674-4926/25030012

Topics

laser devices and laser physics

Lasers and Laser Optics

laser manufacturing

Instrumentation, Measurement and Metrology