[1] [1] Liu D, Li X, Chen S, et al. Atomically dispersed platinum supported on curved carbon supports for efficient electrocatalytic hydrogen evolution ［J］. Nature Energy, 2019, 4(6): 512-518.

[2] [2] Rao C N R, Chhetri M. Borocarbonitrides as Metal-Free Catalysts for the Hydrogen Evolution Reaction ［J］. Advanced Materials, 2019, 31(13): 1803668.1-13.

[3] [3] Lee S W, Chen S, Sheng W, et al. Roles of Surface Steps on Pt Nanoparticles in Electro-oxidation of Carbon Monoxide and Methanol ［J］. Journal of the American Chemical Society, 2009, 131(43): 15669-15677.

[4] [4] Tian N, Zhou Z Y, Sun S G. Platinum Metal Catalysts of High-Index Surfaces: From Single-Crystal Planes to Electrochemically Shape-Controlled Nanoparticles ［J］. The Journal of Physical Chemistry C, 2008, 112(50): 19801-19817.

[5] [5] Feng L L, Yu G, Wu Y, et al. High-Index Faceted Ni3S2 Nanosheet Arrays as Highly Active and Ultrastable Electrocatalysts for Water Splitting ［J］. Journal of the American Chemical Society, 2015, 137(44): 14023-14026.

[6] [6] Narayanan R, El-sayed M A. Shape-Dependent Catalytic Activity of Platinum Nanoparticles in Colloidal Solution ［J］. Nano Letters, 2004, 4(7): 1343-1348.

[7] [7] Wang D Y, Chou H L, Cheng C C, et al. FePt nanodendrites with high-index facets as active electrocatalysts for oxygen reduction reaction ［J］. Nano Energy, 2015, 11(0): 631-639.

[8] [8] Zong C, Chen C J, Zhang M, et al. Transient Electrochemical Surface-Enhanced Raman Spectroscopy: A Millisecond Time-Resolved Study of an Electrochemical Redox Process ［J］. Journal of the American Chemical Society, 2015, 137(36): 11768-11774.

[9] [9] Dong J C, Zhang X G, Briega-martos V, et al. In situ Raman spectroscopic evidence for oxygen reduction reaction intermediates at platinum single-crystal surfaces ［J］. Nature Energy, 2018, 4(1): 60-67.

[10] [10] Li C Y, Le J B, Wang Y H, et al. In situ probing electrified interfacial water structures at atomically flat surfaces ［J］. Nature Materials, 2019, 18(7): 697-701.

[11] [11] Yao Y, Zhu S, Wang H, et al. A Spectroscopic Study on the Nitrogen Electrochemical Reduction Reaction on Gold and Platinum Surfaces ［J］. Journal of the American Chemical Society, 2018, 140(4): 1496-1501.

[12] [12] Bohra D, Ledezma-yanez I, Li G, et al. Lateral Adsorbate Interactions Inhibit HCOO? while Promoting CO Selectivity for CO2 Electrocatalysis on Silver ［J］. Angewandte Chemie, 2019, 131(5): 1359-163.

[13] [13] Dou S, Wang X, Wang S. Rational Design of Transition Metal-Based Materials for Highly Efficient Electrocatalysis ［J］. Small Methods, 2019, 3(1): 18002-18011.

[14] [14] Jin H, Liu X, Chen S, et al. Heteroatom-Doped Transition Metal Electrocatalysts for Hydrogen Evolution Reaction ［J］. ACS Energy Letters, 2019, 4(4): 805-810.

[15] [15] Balogun M S, Zhu Y, Qiu W, et al. Chemically Lithiated TiO2 Heterostructured Nanosheet Anode with Excellent Rate Capability and Long Cycle Life for High-Performance Lithium-Ion Batteries ［J］. ACS Applied Materials & Interfaces, 2015, 7(46): 25991-26003.

[16] [16] Carey D M, Korenowski G M. Measurement of the Raman spectrum of liquid water ［J］. The Journal of Chemical Physics, 1998, 108(7): 2669-2675.

[17] [17] Walrafen G E. Raman Spectral Studies of Water Structure ［J］. The Journal of Chemical Physics, 1964, 40(11): 3249-3256.

[18] [18] Zou S Z, Chen Y X, Mao B W, et al. SERS studies on electrode/electrolyte interfacial water I. Ion effects in the negative potential region ［J］. Journal of Electroanalytical Chemistry, 1997, 424(1): 19-24.

[19] [19] Du Q, Freysz E, Shen Y R. Vibrational spectra of water molecules at quartz/water interfaces ［J］. Physical Review Letters, 1994, 72(2): 238-241.

[20] [20] Nihonyanagi S, Ye S, Uosaki K, et al. Potential-dependent structure of the interfacial water on the gold electrode ［J］. Surface Science, 2004, 573(1): 11-16.

[21] [21] Noguchi H, Okada T, Uosaki K. Molecular structure at electrode/electrolyte solution interfaces related to electrocatalysis ［J］. Faraday Discussions, 2009, 140(0): 125-137.

[22] [22] Schultz Z D, Shaw S K, Gewirth A A. Potential Dependent Organization of Water at the Electrified Metal?Liquid Interface ［J］. Journal of the American Chemical Society, 2005, 127(45): 15916-15922.