Journal of Inorganic Materials, Volume. 38, Issue 9, 1089(2023)

Controlling Vertical Composition Gradients in Sn-Pb Mixed Perovskite Solar Cells via Solvent Engineering

Xiaodong DAI1,2, Luwei ZHANG2, Yicheng QIAN2, Zhixin REN2, Huanqi CAO2、*, and Shougen YIN2
Author Affiliations
  • 11. School of Science, Tianjin University of Technology, Tianjin 300384, China
  • 22. Key Laboratory of Display Materials and Photoelectric Devices (Ministry of Education), Tianjin Key Laboratory for Photoelectric Materials and Devices, National Demonstration Center for Experimental Function Materials Education, School of Materials Science and Engineering, Tianjin University of Technology, Tianjin 300384, China
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    Figures & Tables(10)
    Crystal structures of perovskite films prepared with different amounts of antisolvent
    (a) PL spectra from the front and back sides of PF-DMSO0.25; (b) Cross-sectional SEM images of PSCs of PF-DMSO0.25 and EDS scanning areas; (c) Lead/tin elemental ratios in different depth regions of the cross-sectional SEM images of PF-DMSO0.25 or PF-DMSO0.50; Colorful figures are available on website
    Phase structure and photoelectric properties of perovskites films PF-DMSOx
    Numerical simulation of devices with NG, WO, IG heterojunctions
    XRD pattern of thin films prepared by spin coating SnI2
    (a-d) EDS spectra of regions 1-4 of PF-DMSO0.50 film and (e-h) EDS spectra of regions 1-4 of PF-DMSO0.25 film
    Statistical charts of (a) open-circuit voltage, (b) fill factor and (c) short-circuit current density for devices of PF-DMSOx (x=0.20,0.25,0.33,0.50,1.00)
    UV-Vis absorption spectra of PF-DMSO0.50 and PF-DMSO0.25
    Transmittance spectrum of ITO conductive glass used in the experiments
    • Table 1. Main simulation parameters of perovskite solar cell structures

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      Table 1. Main simulation parameters of perovskite solar cell structures

      IngredientThickness/μmEg/eV χ/eV εrNc/cm-3Nv/cm-3μn/(cm2V-1∙s-1) μp/(cm2V-1∙s-1) Nd/cm-3Na/cm-3Nt/cm-3Ref.
      PEDOT: PSS0.032.2332.2×10151.8×10180.020.0002-3.17×10141×1015[35,39, 40-42]
      Perovskite0.61.25-1.234.15-4.21001.0×10181.0×101822-1.0×10182.5×1016[43-45]
      PCBM0.052.03.93.92.5×10212.5×10200.20.22.93×1017-1×1015[42, 46]
      BCP0.013.53.7101.8×10182.2×10180.020.0021×10211×10101×10[42, 46]
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    Xiaodong DAI, Luwei ZHANG, Yicheng QIAN, Zhixin REN, Huanqi CAO, Shougen YIN. Controlling Vertical Composition Gradients in Sn-Pb Mixed Perovskite Solar Cells via Solvent Engineering [J]. Journal of Inorganic Materials, 2023, 38(9): 1089

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    Paper Information

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    Received: Nov. 28, 2022

    Accepted: --

    Published Online: Mar. 6, 2024

    The Author Email: Huanqi CAO (caoh@tjut.edu.cn)

    DOI:10.15541/jim20220710

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