Chinese Journal of Lasers, Volume. 52, Issue 12, 1202205(2025)

In‑Situ Phase Formation and MechanicalProperty Enhancement Mechanism of Laser Cladding FeCoNiCrMo Coating Doped with LaB6

Jitai Han1, Chen Cui1,2、*, Kui Zhu1,3, Yin Li1,3, Yanan Ge4, Sida Tang5, Weimin Ma1, and Peng Li1,3
Author Affiliations
  • 1School of Automation, Wuxi University, Wuxi 214105, Jiangsu , China
  • 2School of Mechanical and Aerospace Engineering, Nanyang Technological University, Singapore 639798
  • 3School of Automation, Nanjing University of Information Science and Technology, Nanjing 210044, Jiangsu , China
  • 4Department of Basic Experimental Teaching, Nanjing University of Aeronautics and Astronautics, Nanjing 211106, Jiangsu , China
  • 5School of Electrical and Information Engineering, Wuxi University, Wuxi 214105, Jiangsu , China
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    Figures & Tables(19)
    Laser cladding powders. (a) FeCoNiCrMo powder; (b) LaB6 powder
    Macroscopic morphology of LaB6/FeCoNiCrMo cladding coatings
    XRD patterns of each cladding layer
    Morphology (left) and elements distribution (right) at the interface between C2 cladding layer and the substrate
    Microstructures of cladding layers. (a) C0 cladding layer; (b) C1 cladding layer; (c) C2 cladding layer; (d) C3 cladding layer; (e) C4 cladding layer; (f) microstructure of agglomeration area
    Typical phases in the cladding layers: σ-CrMo, La2O3, and TiB phases
    HRTEM images of TiB/La2O3 interface and the corresponding FFT (fast Fourier transform) patterns
    Mapping of LaB6/FeCoNiCrMo high entropy alloy cladding layer
    Microhardness of each cladding layer and Ti6Al4V substrate
    Strengthening improvement value of LaB6/FeCoNiCrMo cladding layers
    Friction coefficient of Ti6Al4V substrate and each cladding layer. (a) Real-time friction coefficient; (b) average friction coefficient
    Wear scar morphology of the substrate and each cladding layer. (a)(b) Ti6Al4V; (c)(d) C0 cladding layer; (e)(f) C1 cladding layer; (g)(h) C2 cladding layer; (i)(j) C3 cladding layer; (k)(l) C4 cladding layer
    Wear morphology of Ti6Al4V substrate. (a) Macroscopic wear profile; (b)(c) microscopic wear morphology and enlarged view of the marked area; (d) EDS analysis at the marked points A and B
    Wear morphology of cladding layers. (a) Wear morphology of C0 cladding layer; (b) wear morphology of C1 cladding layer; (c)(d) wear morphology of C2 cladding layer; (e)‒(g) wear morphology of C3 cladding layer; (h)(i) wear morphology of C4 cladding layer
    EDS map scanning analysis of C2 cladding layer wear surface
    Friction and wear mechanism of LaB6/FeCoNiCrMo
    Corrosion resistance of Ti6Al4V substrate and each cladding layer. (a) Potentiodynamic polarization curve; (b) self-corrosion current density
    • Table 1. Chemical composition of Ti6Al4V substrate and FeCoNiCrMo powder

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      Table 1. Chemical composition of Ti6Al4V substrate and FeCoNiCrMo powder

      MaterialMass fraction of each element /%
      FeCoNiCrMoTiAlV
      Ti6Al4VBal.6.044.02
      FeCoNiCrMo17.6718.7518.7016.4028.48
    • Table 2. EDS analysis of positions 1, 2, and 3 in Fig.6

      View table

      Table 2. EDS analysis of positions 1, 2, and 3 in Fig.6

      PositionAtomic fraction /%
      TiAlVFeCoNiCrMoLaO
      116.041.633.332.786.644.7533.6131.22
      222.354.512.034.251.281.454.342.8123.5133.47
      362.342.351.086.547.5811.254.254.61
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    Jitai Han, Chen Cui, Kui Zhu, Yin Li, Yanan Ge, Sida Tang, Weimin Ma, Peng Li. In‑Situ Phase Formation and MechanicalProperty Enhancement Mechanism of Laser Cladding FeCoNiCrMo Coating Doped with LaB6[J]. Chinese Journal of Lasers, 2025, 52(12): 1202205

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    Paper Information

    Category: Laser Surface Machining

    Received: Jan. 13, 2025

    Accepted: Mar. 3, 2025

    Published Online: Jun. 3, 2025

    The Author Email: Chen Cui (cc1040514416@163.com)

    DOI:10.3788/CJL250463

    CSTR:32183.14.CJL250463

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