Chinese Journal of Lasers, Volume. 45, Issue 8, 811001(2018)

Detection of Heavy Metals in Soil Based on Polarization Resovled LIBS Technique

Yu Yang1, Zhao Nanjing2, Meng Deshuo2, Ma Mingjun2, and Lan Zhigao1
Author Affiliations
  • 1[in Chinese]
  • 2[in Chinese]
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    Figures & Tables(12)
    Schematic of polarization experimental apparatus
    Spectra of sample in the wavelength range of 400-450 nm
    LIBS spectra of characteristic spectral line Pb Ⅰ: 405.780 nm under the conditions of polarization and non-polarization
    Variation of spectral intensity of characteristic spectral line Pb Ⅰ: 405.780 nm with polarization angle
    Variation of spectral intensity of continuous background radiation with polarization angle
    RSD under the conditions of polarization and non-polarization
    Calibration curve of Pb without polarization
    Calibration curve of Pb with polarization
    • Table 1. Soil samples contained different concentrations of Pb

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      Table 1. Soil samples contained different concentrations of Pb

      Serial number of soil sampleMass fraction /10-6
      1100
      2200
      3300
      4400
      5500
      6600
      7700
      8800
      9900
    • Table 2. Polarization degree of four characteristic spectral lines and corresponding continuous background radiation

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      Table 2. Polarization degree of four characteristic spectral lines and corresponding continuous background radiation

      Characteristicspectralline /nmPolarizationdegreeContinuousbackgroundradiation /nmPolarizationdegree
      Fe Ⅰ: 404.5810.27403.5-404.00.70
      Pb Ⅰ: 405.7800.17405.0-405.40.64
      Ca Ⅰ: 422.6700.25421.0-421.40.69
      Mg Ⅰ: 518.3610.23517.7-518.00.67
    • Table 3. SBR of four characteristic spectral lines under the conditions of polarization and non-polarization

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      Table 3. SBR of four characteristic spectral lines under the conditions of polarization and non-polarization

      ConditionSBR
      Fe Ⅰ: 404.581 nmPb Ⅰ: 405.780 nmCa Ⅰ: 422.670 nmMg Ⅰ: 518.361 nm
      Polarization3.283.889.332.62
      Non-polarization18.3321.9949.4319.25
    • Table 4. Limit of detection of Pb under the conditions of polarization and non-polarization

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      Table 4. Limit of detection of Pb under the conditions of polarization and non-polarization

      ConditionkSBcL /10-6
      Polarization1.4318.839.4
      Non-polarization1.9311.217.4
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    Yu Yang, Zhao Nanjing, Meng Deshuo, Ma Mingjun, Lan Zhigao. Detection of Heavy Metals in Soil Based on Polarization Resovled LIBS Technique[J]. Chinese Journal of Lasers, 2018, 45(8): 811001

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    Paper Information

    Category: spectroscopy

    Received: Jan. 31, 2018

    Accepted: --

    Published Online: Aug. 11, 2018

    The Author Email:

    DOI:10.3788/CJL201845.0811001

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