Acta Optica Sinica, Volume. 45, Issue 4, 0416001(2025)
Few-Layer 2H-MoS2 Packaged La2Ti2O7 Nanostep Heterostructure Design and Its Efficient Photocatalytic Hydrogen Production
Fig. 1. Preparation process and morphology test results of MoS2/LTO composite. (a) Preparation process of MoS2/LTO composite; (b) SEM and (c) TEM images of LTO; (d) TEM image of MoS2; (e) SEM, (f) TEM, (g) HRTEM, and (h) EDS element distribution images of MoS2/LTO
Fig. 2. Chemical and phase composition test results of LTO, MoS2, and MoS2/LTO. (a) XRD patterns; (b)(c) XRD patterns of MoS2/LTO with different MoS2 mass fractions; (d) XPS survey spectra of MoS2/LTO; high-resolution XPS spectra of (e) Mo 3d, (f) S 2p, (g) La 3d, (h) Ti 2p, and (i) O 1s
Fig. 3. Band structure test and theoretical calculation results of LTO, MoS2, and MoS2/LTO. (a) UV-vis DRS; (b) Tauc plots and (c) Mott‒Schottky plots of LTO and MoS2; band structures and density of states of (d)(e) LTO and (f)(g) MoS2; average electrostatic potential of (h) LTO (010), (i) LTO (012), and (j) MoS2 (001)
Fig. 4. Photocatalytic performance test results. (a) Photocatalytic H2 production performance of different samples; (b) comparison of H2 production rates of MoS2/LTO with different MoS2 mass fractions; (c) AQE and UV-vis DRS of MoS2/LTO; (d) cycling H2 production performance of recycled MoS2/LTO
Fig. 5. Electrochemical test and theoretical calculation results. (a) EIS Nernst curves and (b) I-t plots of LTO and MoS2/LTO; differential charge density and plane-averaged differential charge density along the Δρ(Z) direction of (c)(e) MoS2(001)/LTO(010) and (d)(f) MoS2(001)/LTO(012) heterojunctions
Fig. 6. Separation and transfer processes of photo-generated electrons (e-) and holes (h+) in the MoS2/LTO heterostructure
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Liang Mao, Haifeng Weng, Xiaoyan Cai. Few-Layer 2H-MoS2 Packaged La2Ti2O7 Nanostep Heterostructure Design and Its Efficient Photocatalytic Hydrogen Production[J]. Acta Optica Sinica, 2025, 45(4): 0416001
Category: Materials
Received: Oct. 21, 2024
Accepted: Dec. 10, 2024
Published Online: Feb. 21, 2025
The Author Email: Cai Xiaoyan (xycai@cumt.edu.cn)
CSTR:32393.14.AOS241669