Spectroscopy and Spectral Analysis, Volume. 42, Issue 11, 3345(2022)

Research Progress and Trend of Gas Raman Sensing Enhancement Technology

Fu WAN1; 2;, Hu GE1; 2;, Qiang LIU1; 2;, Wei-ping KONG1; 2;, Jian-xin WANG1; 2;, and Wei-gen CHEN1; 2;
Author Affiliations
  • 1. College of Electrical Engineering, Chongqing University, Chongqing 400044, China
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    Figures & Tables(14)
    Schematic diagram of the multi-pass cavity
    Multi-pass cavity Raman detection system[26]
    The basic setup of a PDH system
    PDH error signal
    Raman spectrum showing H2 Q(1) branch[35]
    Schematic diagram of optical feedback frequency locking process based on external resonant cavity
    The relationship between the laser coupled frequency and the free-running frequency, where ω0 is the center frequency of the cavity mode
    F-P cavity enhanced Raman detection system based on optical feedback[40]
    Schematic diagram of Raman laser cavity for gas Raman enhancement
    Basic principle of fiber-enhanced gas Raman spectroscopy
    Silver-plated capillary Raman detection system[46]
    Hollow fiber Raman detection system[53]
    Schematic diagram of the combination of optical fiber and F-P cavity for gas Raman signal enhancement
    • Table 1. Summary of limit of detection

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      Table 1. Summary of limit of detection

      增强类型文献来源拉曼增益倍数
      (激光功率增益倍数)
      最小检测下限/(μL·L-1)
      多次反射腔
      增强
      2298未给出
      24(45)H2(96.6), CO2(126), CH4(21), C2H4(63), C2H2(42)
      2083未给出
      521CO2(51.97), CH4(9.9), C2H6(14.1), C3H8(15.9)
      26(16)H2(0.1)
      F-P型腔
      增强
      3550H2(10)
      36(5 900)未给出
      6(850)O2(1 412), CO2(317), C2H4(261), N2(3 540)
      4(833)CH4(50), H2S(100), H2(140), N2(1 000)
      41(2 200)CO2(17.4), O2(50.7), N2(53.5), C2H2(5.8)
      激光腔增强43未给出H2(100), N2(50), O2(10), H20(10), CO(50), CO2(25), CxHy(10), NH3(10)
      镀银毛细管
      增强
      44未给出N2(300)
      4560CO2(143), H2O(400)
      46未给出CO2(430), H20(400)
      空芯光纤
      增强
      48未给出CH4(20), C3H8(20)
      49700C7H8(400), C3H6O(100), C2H3Cl3(1200)
      51未给出CO2(15)
      55未给出N2(9), O2(8), CO2(4), N2O(19), CH4(0.2), H2(4.7)
      58未给出C3H8(20), C4H10(20), C2H6(30), H2S(33)
      59未给出O2(125), CO2(25)
      61未给出CxHy(90~180)
      62未给出H2(5.4), SO2(7)
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    Fu WAN, Hu GE, Qiang LIU, Wei-ping KONG, Jian-xin WANG, Wei-gen CHEN. Research Progress and Trend of Gas Raman Sensing Enhancement Technology[J]. Spectroscopy and Spectral Analysis, 2022, 42(11): 3345

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    Paper Information

    Category: Research Articles

    Received: Oct. 21, 2021

    Accepted: --

    Published Online: Nov. 23, 2022

    The Author Email:

    DOI:10.3964/j.issn.1000-0593(2022)11-3345-10

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