Journal of the Chinese Ceramic Society, Volume. 53, Issue 8, 2088(2025)

Spent LiFePO4 Lithium Leach Solution Low Carbon Deep Decontamination Technology and Mechanism

ZHANG Xiaoming1,2, CHEN Jianan1, DENG Xinyan1, XU Zhenhua1, WANG Xin1,2、*, and HUANG Guoyong1
Author Affiliations
  • 1State Key Laboratory of Heavy Oil, College of New Energy and Materials, China University of Petroleum-Beijing, Beijing 102249, China
  • 2Lithium Group Co., Ltd., Xinyu 338000, Jiangxi, China
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    References(20)

    [1] [1] YU W H, GUO Y, XU S M, et al. Comprehensive recycling of lithium-ion batteries: Fundamentals, pretreatment, and perspectives[J]. Energy Storage Mater, 2023, 54: 172-220.

    [2] [2] FEI Z T, ZHOU S Y, ZHANG Y J, et al. Toward high voltage performance of LiCoO2 cathode materials directly regenerated with a bulk and surface synergistic approach from spent lithium-ion batteries[J]. ACS Sustainable Chem Eng, 2022, 10(20): 6853-6862.

    [3] [3] LI G H, REN Z M, LI A L, et al. Highly stable surface and structural origin for lithium-rich layered oxide cathode materials[J]. Nano Energy, 2022, 98: 107169.

    [4] [4] TAO H B, YANG Y, XU S M, et al. A lattice defect-inspired leaching strategy toward simultaneous recovery and separation of value metals from spent cathode materials[J]. Waste Manag, 2021, 135: 40-46.

    [5] [5] KUMAR J, NEIBER R R, PARK J, et al. Recent progress in sustainable recycling of LiFePO4-type lithium-ion batteries: Strategies for highly selective lithium recovery[J]. Chem Eng J, 2022, 431: 133993.

    [6] [6] REN X G, LI Y J, XI X M, et al. High performance LiFePO4 nanomaterial obtained by a tavorite-to-olivine phase transition at low-temperature[J]. Chem Eng J, 2023, 453: 139611.

    [7] [7] CHEN S P, LV D, CHEN J, et al. Review on defects and modification methods of LiFePO4 cathode material for lithium-ion batteries[J]. Energy Fuels, 2022, 36(3): 1232-1251.

    [8] [8] SIM G S, NANTHAGOPAL M, SANTHOSHKUMAR P, et al. Biomass-derived nitrogen-doped carbon on LiFePO4 material for energy storage applications[J]. J Alloys Compd, 2022, 902: 163720.

    [9] [9] BI H J, ZHU H B, ZU L, et al. Eddy current separation for recovering aluminium and lithium-iron phosphate components of spent lithium-iron phosphate batteries[J]. Waste Manag Res, 2019, 37(12): 1217-1228.

    [10] [10] YI C X, YANG Y, ZHANG T, et al. A green and facile approach for regeneration of graphite from spent lithium ion battery[J]. J Clean Prod, 2020, 277: 123585.

    [11] [11] QIU X J, WANG C Y, XIE L L, et al. Challenges and perspectives towards direct regeneration of spent LiFePO4 cathode[J]. J Power Sources, 2024, 602: 234365.

    [12] [12] YANG Y P, ZHANG J L, ZHANG H, et al. Simultaneous anodic de-lithiation/cathodic lithium-embedded regeneration method for recycling of spent LiFePO4 battery[J]. Energy Storage Mater, 2024, 65: 103081.

    [13] [13] XU Y L, ZHANG B C, GE Z F, et al. Direct recovery of degraded LiFePO4 cathodeviamild chemical relithiation strategy[J]. Chem Eng J, 2023, 477: 147201.

    [14] [14] WANG B, YIN Y W, DENG H Y, et al.In-siturepair of failed LiFePO4 cathode using residual Li- and C-containing impurities from active material separation process[J]. Chem Eng J, 2024, 497: 154922.

    [15] [15] DU J W, QING J L, FANG K Y, et al. The priority leaching of lithium from spent LiFePO4 cathode without the oxidization[J]. Resour Conserv Recycl, 2024, 202: 107374.

    [16] [16] SHAN M H, DANG C Y, MENG K, et al. Recycling of LiFePO4 cathode materials: From laboratory scale to industrial production[J]. Mater Today, 2024, 73: 130-150.

    [23] [23] KUMAR R, LIU C J, HA G S, et al. Downstream recovery of Li and value-added metals (Ni, Co, and Mn) from leach liquor of spent lithium-ion batteries using a membrane-integrated hybrid system[J]. Chem Eng J, 2022, 447: 137507.

    [26] [26] ZHANG X M, XIE W, ZHOU X L, et al. Study on metal recovery process and kinetics of oxidative leaching from spent LiFePO4 Li-batteries[J]. Chin J Chem Eng, 2024, 68: 94-102.

    [27] [27] VELARDE L, NABAVI M S, ESCALERA E, et al. Adsorption of heavy metals on natural zeolites: A review[J]. Chemosphere, 2023, 328: 138508.

    [28] [28] AKHTAR F, ANDERSSON L, OGUNWUMI S, et al. Structuring adsorbents and catalysts by processing of porous powders[J]. J Eur Ceram Soc, 2014, 34(7): 1643-1666.

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    ZHANG Xiaoming, CHEN Jianan, DENG Xinyan, XU Zhenhua, WANG Xin, HUANG Guoyong. Spent LiFePO4 Lithium Leach Solution Low Carbon Deep Decontamination Technology and Mechanism[J]. Journal of the Chinese Ceramic Society, 2025, 53(8): 2088

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    Paper Information

    Special Issue:

    Received: Dec. 31, 2024

    Accepted: Sep. 5, 2025

    Published Online: Sep. 5, 2025

    The Author Email: WANG Xin (WX841780383@163.com)

    DOI:10.14062/j.issn.0454-5648.20240857

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