Spectroscopy and Spectral Analysis, Volume. 42, Issue 10, 3084(2022)

Phosphorus Species of Biochar Modified by Phosphoric Acid and Pyrophosphoric Acid Based on Spectral Analysis

Xu-yang WANG1、*, Tao SUN1、1;, Xin-ping ZHU1、1;, Guang-mu TANG2、2;, Hong-tao JIA1、1; *;, and Wan-li XU2、2;
Author Affiliations
  • 11. College of Resources and Environment Science, Xinjiang Agricultural University, Urumqi 830052, China
  • 22. Institute of Soil and Fertilizer & Agricultural Sparing Water, Xinjiang Academy of Agricultural Sciences, Urumqi 830091, China
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    Figures & Tables(7)
    Raman spectra of the wheat straw (a) and cotton stalk (b) biochars before and after modificationP- and PA- represent modified by H3PO4 and H4P2O7, respectively, Same below
    SEM image and the corresponding P elemental mapping images of the wheat straw (a) and cotton stalk (b) biochars before and after modification
    FTIR spectra of the wheat straw (a) and cotton stalk (b) biochars before and after modification
    XPS spectra and the relative content of characteristic peaks of wheat straw (a) and cotton stalk (b) biochars before and after modification
    High-resolution P(2p) (a, b) and O(1s) (c, d) spectra of the wheat straw and cotton stalk biochars before and after modification
    Changes of phosphorus relative content of the wheat straw (a) and cotton stalk (b) biochars before and after modification
    • Table 1. Basic properties of biochar

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      Table 1. Basic properties of biochar

      性质处理
      WBCP-WBCPA-WBCCBCP-CBCPA-CBC
      C/%54.13±0.15 aA53.78±0.08 bA45.21±0.12 cA53.62±0.01 aA40.17±0.7 bA33.35±0.17 cA
      N/%0.59±0.03 cA0.90±0.04 aA0.62±0.07 bA1.25±0.06 bA1.87±0.03 aA0.88±0.04 cA
      H/%2.33±0.04 cA2.6±0.04 bA3.04±0.02 aA2.05±0.05 cA3.04±0.04 bA3.14±0.06 aA
      O*/%17.16±0.57 bB29.23±1.03 aA17.86±1.39 bB38.04±1.06 aA20.94±1.47 cB33.39±0.81 bA
      灰分/%24.98±1.25 bA13.48±1.23 cB33.90±1.35 aA18.45±0.99 cB20.54±1.38 bA29.25±2.01 aA
      总P/(g·kg-1)2.91±0.05 cB13.81±0.32 bA20.15±0.62 aB4.62±0.08 cA20.61±0.14 bA37.13±0.48 aA
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    Xu-yang WANG, Tao SUN, Xin-ping ZHU, Guang-mu TANG, Hong-tao JIA, Wan-li XU. Phosphorus Species of Biochar Modified by Phosphoric Acid and Pyrophosphoric Acid Based on Spectral Analysis[J]. Spectroscopy and Spectral Analysis, 2022, 42(10): 3084

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    Paper Information

    Category: Research Articles

    Received: Aug. 4, 2021

    Accepted: Jan. 27, 2022

    Published Online: Nov. 23, 2022

    The Author Email: Xu-yang WANG (1515375795@qq.com)

    DOI:10.3964/j.issn.1000-0593(2022)10-3084-07

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