Acta Optica Sinica, Volume. 44, Issue 22, 2230002(2024)

Qualitative and Quantitative Comparative Investigation of Gas for Different Focusing Arrangements by Laser-Induced Breakdown Spectroscopy

Jiaxu Zhang1,2, Chen Chen3,4, Nan Li1,2、*, Yifan Luo1,2, Yangyang Zhao1,2, Jinge Guan1,2, Yongqiu Zheng1,2, and Chenyang Xue1,2
Author Affiliations
  • 1School of Instrument and Electronics, North University of China, Taiyuan 030051, Shanxi , China
  • 2State Key Laboratory of Dynamic Measurement Technology, North University of China, Taiyuan 030051, Shanxi , China
  • 3Xi’an Aerospace Propulsion Institute, Xi’an 710025, Shaanxi , China
  • 4National Key Laboratory of Solid Rocket Propulsion, Xi’an 710025, Shaanxi , China
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    Figures & Tables(12)
    Schematic diagram of LIBS experimental setup for gas measurements
    Typical time-resolved spectra of atomic lines of O and N. (a) Typical time-resolved spectra; (b) delay dependences of intensity
    Typical LIBS spectra of atomic line of O Ⅰ 777.4 nm for five focusing arrangements. (a) Typical LIBS spectra of atomic line of O Ⅰ 777.4 nm; (b) variation of peak areas
    Signal stability of LIBS for five focusing arrangements. (a) CDC1; (b) CDC2; (c) CDC3; (d) CDC4; (e) SL1
    Breakdown probability curves for two typical focusing arrangements. (a) CDC3; (b) SL1
    RMS radius of focused spots for two focusing arrangements. (a) CDC3; (b) SL1
    Typical LIBS spectra and the calibration curves of the atomic line of O Ⅰ 777.4 nm obtained for two focusing arrangements of nitrogen-oxygen gas mixtures. (a) Typical spectra of varied concentrations of O obtained for SL1; (b) LIBS calibration curve and predicted data obtained for SL1; (c) typical spectra of varied concentrations of O obtained for CDC3; (d) LIBS calibration curve and predicted data obtained for CDC3
    Typical LIBS spectra and calibration curves of atomic line of N Ⅰ 862.9 nm obtained for two focusing arrangements of oxygen-nitrogen gas mixtures. (a) Typical spectra of varied concentrations of N obtained for SL1; (b) LIBS calibration curve and predicted data obtained for SL1; (c) typical spectra of varied concentrations of N obtained for CDC3; (d) LIBS calibration curve and predicted data obtained for CDC3
    • Table 1. Focusing parameters of optical simulation for five focusing arrangements

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      Table 1. Focusing parameters of optical simulation for five focusing arrangements

      Focusing

      arrangement

      Root-mean-square radius /μmFocusing lens spot radius /mm
      SL1212.6683.000
      CDC112.6175.147
      CDC219.1107.006
      CDC325.1128.941
      CDC431.92810.947
    • Table 2. Calculated depth of focus and stability of line intensity for five typical focusing arrangements

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      Table 2. Calculated depth of focus and stability of line intensity for five typical focusing arrangements

      Focusing arrangementDepth of focus /mmRSD /%
      SL123.78713.87
      CDC113.8654.98
      CDC210.1863.67
      CDC37.9811.97
      CDC46.5192.47
    • Table 3. Comparison of prediction parameters of nitrogen-oxygen gas mixtures

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      Table 3. Comparison of prediction parameters of nitrogen-oxygen gas mixtures

      Focusing arrangementPredicted concentration /%RSD /%RMSELOD /%
      SL1128.931.4050.243
      187.10
      CDC3122.280.4820.009
      181.58
    • Table 4. Comparison of prediction parameters of oxygen-nitrogen gas mixtures

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      Table 4. Comparison of prediction parameters of oxygen-nitrogen gas mixtures

      Focusing

      arrangement

      Predicted

      concentration/%

      RSD/%RMSELOD/%
      SL1129.341.3810.665
      188.03
      CDC3122.440.6780.061
      183.14
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    Jiaxu Zhang, Chen Chen, Nan Li, Yifan Luo, Yangyang Zhao, Jinge Guan, Yongqiu Zheng, Chenyang Xue. Qualitative and Quantitative Comparative Investigation of Gas for Different Focusing Arrangements by Laser-Induced Breakdown Spectroscopy[J]. Acta Optica Sinica, 2024, 44(22): 2230002

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    Paper Information

    Category: Spectroscopy

    Received: Jun. 27, 2024

    Accepted: Aug. 6, 2024

    Published Online: Nov. 19, 2024

    The Author Email: Nan Li (linan@nuc.edu.cn)

    DOI:10.3788/AOS241216

    CSTR:32393.14.AOS241216

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