Journal of the Chinese Ceramic Society, Volume. 53, Issue 5, 1225(2025)

Symbiotic Regulation and Carbonization Mechanism of γ-C2S and β-C2S in Low-calcium Clinker System

ZHANG Yunzi1, WANG Yali1, PEI Tianrui1, ZHENG Yongchao2, and ZHAO Sixue2
Author Affiliations
  • 1School of Materials Science and Engineering, Beijing University of Technology, Beijing 100124, China
  • 2State Key Laboratory of Solid Waste Reuse for Building Materials, Beijing Building Materials Academy of Science Research, Beijing 100041, China
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    References(21)

    [2] [2] YOUNG J F, BERGER R L, BREESE J. Accelerated curing of compacted calcium silicate mortars on exposure to CO2[J]. J Am Ceram Soc, 1974, 57(9): 394-397.

    [3] [3] ASHRAF W, OLEK J. Carbonation behavior of hydraulic and non-hydraulic calcium silicates: Potential of utilizing low-lime calcium silicates in cement-based materials[J]. J Mater Sci, 2016, 51(13): 6173-6191.

    [5] [5] SAHU S D, MEININGER R C. Sustainability and durability of solidia cement concrete[J]. Concr Int, 2020, 42(8): 29-34.

    [6] [6] HOU G H, CHEN J N, LU B, et al. Composition design and pilot study of an advanced energy-saving and low-carbon rankinite clinker[J]. Cem Concr Res, 2020, 127: 105926.

    [8] [8] CHANG J, FANG Y F, SHANG X P. The role of -C2S and -C2S in carbon capture and strength development[J]. Mater Struct, 2016, 49(10): 4417-4424.

    [10] [10] JIANG T, CUI K, CHANG J. Development of low-carbon cement: Carbonation of compounded C2S by -C2S and -C2S[J]. Cem Concr Compos, 2023, 139: 105071.

    [11] [11] GUAN X M, LIU S H, FENG C H, et al. The hardening behavior of -C2S binder using accelerated carbonation[J]. Constr Build Mater, 2016, 114: 204-207.

    [12] [12] SAITO T, SAKAI E, MORIOKA M, et al. Carbonation of -Ca2SiO4 and the mechanism of vaterite formation[J]. J Adv Concr Technol, 2010, 8(3): 273-280.

    [13] [13] TAN Y C, LIU Z C, WANG F Z. Effect of temperature on the carbonation behavior of -C2S compacts[J]. Cem Concr Compos, 2022, 133: 104652.

    [14] [14] ZHAO S X, LIU Z C, MU Y D, et al. Effect of chitosan on the carbonation behavior of -C2S[J]. Cem Concr Compos, 2020, 111: 103637.

    [15] [15] FANG Y F, LIU Z C, WANG Q H, et al. Strength development and products evolution of -C2S and -C3S induced by accelerated carbonation curing[J]. J Wuhan Univ Technol Mater Sci Ed, 2020, 35(6): 1053-1060.

    [16] [16] LIU S H, WANG J J, ZHANG H B, et al. Microstructure of -dicalcium silicate after accelerated carbonation[J]. J Wuhan Univ Technol Mater Sci Ed, 2019, 34(1): 122-126.

    [18] [18] WANG X G, LUO H Y, ZOU F B, et al. High-performance CO2 sequestration solid materials consist of -C2S and -C2S binary clinkers synthesized from carbide slag and sandstone: Sintering, carbonation, and microstructure[J]. ACS Sustain Chem Eng, 2024, 12(18): 6840-6855.

    [20] [20] BARBIER J, HYDE B G. The structures of the polymorphs of dicalcium silicate, Ca2SiO4[J]. Acta Crystallogr B Struct Sci, 1985, 41(6): 383-390.

    [21] [21] CHAN C J, KRIVEN W M, YOUNG J F. Physical stabilization of the → transformation in dicalcium silicate[J]. J Am Ceram Soc, 1992, 75(6): 1621-1627.

    [24] [24] LEI M, MU Y D, LIU Z C, et al. Structural evolution and characterization of -C2S (-C2S) compacts during carbonation[J]. ACS Sustainable Chem Eng, 2023, 11(1): 444-457.

    [26] [26] MU Y D, LIU Z C, WANG F Z. Comparative study on the carbonation-activated calcium silicates as sustainable binders: Reactivity, mechanical performance, and microstructure[J]. ACS Sustain Chem Eng, 2019, 7(7): 7058-7070.

    [28] [28] GHOSH S N, HANDOO S K. Infrared and Raman spectral studies in cement and concrete (review)[J]. Cem Concr Res, 1980, 10(6): 771-782.

    [29] [29] YLMN R, JGLID U. Carbonation of Portland cement studied by diffuse reflection Fourier transform infrared spectroscopy[J]. Int J Concr Struct Mater, 2013, 7(2): 119-125.

    [30] [30] ZAJAC M, SKIBSTED J, LOTHENBACH B, et al. Effect of sulfate on CO2 binding efficiency of recycled alkaline materials[J]. Cem Concr Res, 2022, 157: 106804.

    [31] [31] WANG D, FANG Y F, ZHANG Y Y, et al. Changes in mineral composition, growth of calcite crystal, and promotion of physico-chemical properties induced by carbonation of -C2S[J]. J CO2 Util, 2019, 34: 149-162.

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    ZHANG Yunzi, WANG Yali, PEI Tianrui, ZHENG Yongchao, ZHAO Sixue. Symbiotic Regulation and Carbonization Mechanism of γ-C2S and β-C2S in Low-calcium Clinker System[J]. Journal of the Chinese Ceramic Society, 2025, 53(5): 1225

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    Paper Information

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    Received: Oct. 30, 2024

    Accepted: May. 29, 2025

    Published Online: May. 29, 2025

    The Author Email:

    DOI:10.14062/j.issn.0454-5648.20240689

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