Chinese Journal of Liquid Crystals and Displays, Volume. 40, Issue 1, 111(2025)
Endowing circularly polarized luminescence in liquid crystal composites for desired applications
Fig. 1. Design concept of incorporating aggregation-induced emission (AIE) molecules into chiral photonic cellulose films to develop novel circularly polarized light (CPL) emissive materials. (a) Right-handed CPL emission created by cellulose nanocrystal (CNC)-luminophore composite film; (b) Left-handed CPL emission expectantly created by self-assembly of hydroxypropyl cellulose (HPC)with luminophores; (c) Combined comparison of luminescence properties |glum| and Φ values; (d)Fluorescence photographs and glum values of other chiral luminescent films formed by combining methacrylic anhydride-functionalized HPC (HPC-MA)with other N-(3-(phenylamino)allylidene)aniline hydrochloride derivatives under 365 nm UV irradiation; (e) Comparison of the glum values with other chiral cellulose luminescent materials[21].
Fig. 3. (a) Photomodulation for the left-handed CPL with low and high glum; (b) Total overlap of the reflection bands of the LC system with the fluorescent dye BITM emission peaks; The glum (c) and CPL spectra (d) when the emission and reflection spectra completely overlap without UV irradiation, and the CPL is excited at 580 nm; (e) LC system reflection band partially overlapping with the BITM emission peak; The glum (f) and CPL (g) spectra when the emission spectra partially overlap with the reflection band; (h) Reversible change of glum value when UV and visible light are alternately irradiated. Light intensity of CPL at 715 nm versus polarization angle in the polar coordinate system; (i) Light intensity of CPL at 715 nm after passing through the polarizer; (j) Intensity of CPL at 715 nm after passing through the quarter-wave plate and the polarizer[29].
Fig. 4. Schematic diagram of the fabrication of a multicolour CPL chiral liquid crystal system[31]
Fig. 5. Rational design of a series of dicyanodistyrylbenzene-cholesterol derivatives molecules with CPL optical activity consisting of an AIE active unit, two cholesterol, and eight or five methylene units as linkers[32].
Fig. 6. (a) Schematic diagram of the composition of the CPL system including quantum dots (InP/ZnSeS/ZnS), liquid crystals (5CB) and chiral dopant (S811 or R811); (b, c) High-resolution transmission electron microscopy images and absorption and fluorescence spectra of quantum dots; (d) UV absorption spectra of 5CB (black) and S811 (blue); (e) Schematic representation of the CPL structure formed through the helical co-assembly strategy; (f) Photograph of the multimodal response security material; (g) Schematic representation of the multimodal response of the security material to external stimuli, including light activation, polarization, temperature, voltage, pressure and viewing angle[36].
Fig. 7. (a) Hybrid chiral photonic films displaying dual CPL and CPRTP prepared by evaporation-induced self-assembly strategy; (b) Chemical structures of PVA, CNC and CD; (c) Mechanistic explanation of CPL and CPRTP for hybrid chiral photonic films[39].
Fig. 8. Illustration of CPL production and CPL-induced formation of chiral helices by Azo supramolecular polymers. (a) Unpolarized light passing through a chiral CNC film could be transformed into transmitted CPL; (b) CDs@CNC film shows CPL emission under unpolarized UV irradiation; (c) Supramolecular azo polymers are transformed from a disordered phase to a smetic liquid crystal after thermal annealing, and were induced into chiral helical structures under transmitted CPL or CPL[41].
Fig. 9. UCNPs and CsPbBr3 perovskite nanocrystals introduced in CLC achieve upconversion circularly polarized luminescence (UC-CPL) through a radiative energy transfer process to enhance the emission intensity and obtain a high glumvalue, and UC-CPL switching can also be achieved through electric field and mechanical force tuning[43].
Fig. 10. (a) Manufacturing process of cholesteric stacked superstructure; (b) Working principle of the CPL device[44].
Fig. 11. (a) Cross-sectional polarizing optical microscope images of bilayer devices; (b, c) Top-view polarizing optical microscope images of bilayer devices and MAPbBr3 QD-doped CLC devices under UV light; (d) CPL spectra of the corresponding devices; (e) Variation of glum values relative to wavelength for bilayer devices and chiral LC devices; (f) CPL changes of unencapsulated bilayer devices and MAPbBr3 QD-doped chiral LC devices for 6 months at 25 ℃ ambient atmosphere and 50% relative humidity[45].
Fig. 12. (a) Schematic diagram of synthesized polymerizable perovskite quantum dot nanomonomers; (b) Schematic of the preparation process of Lumin-CLCE films[46].
Fig. 13. Schematic representation of the chemical structure and sequential amplification of CPUVL for R-/S-TP, 4CzIPN, and 5CB[49].
Fig. 14. Design and concept of 4D information encryption and decryption[51]
Fig. 15. (a) Manufacturing strategy for flexible 3D display panels; (b) Schematic of the flexible array panel; (c~h) Photographs of the “USTC 1958” patterns obtained by printing on polyethylene terephthalate (PET) fabric, scale bar: 1 cm; (i) Photograph of the flexible 3D display panel when the pattern is displayed on it, scale bar: 1 cm; (j) Photograph of a wearable watch-like flexible 3D display panel, scale bar: 1 cm; (k) Conceptual drawing of a wearable 3D display device[53].
Fig. 16. Enantioselective photopolymerization initiated by UC-CPUVL[49]
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Mingjiang ZHANG, Ruiqi SU, Taotao ZHUANG. Endowing circularly polarized luminescence in liquid crystal composites for desired applications[J]. Chinese Journal of Liquid Crystals and Displays, 2025, 40(1): 111
Category: Liquid Crystal luminescence Materials
Received: Aug. 12, 2024
Accepted: --
Published Online: Mar. 31, 2025
The Author Email: Taotao ZHUANG (tzhuang@ustc.edu.cn)