Journal of Semiconductors, Volume. 46, Issue 7, 072701(2025)

Facile construction of p-Si/n-SnO2 junction towards high performance self-powered UV photodetector

Xingyu Li, Li Tian, Jinshou Wang, and Hui Liu*
Author Affiliations
  • Hubei Minzu University, School of Chemistry and Environmental Engineering, Enshi 445000, China
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    Figures & Tables(7)
    (Color online) (a) A schematic diagram of the SnO2 microbelt-based UV PD. (b) Optical image of the as prepared SnO2 microbelt and (c) SnO2 microbelt based UV PD.
    (Color online) Morphology and structure of SnO2 microbelts. (a)−(c) SEM images at different magnifications of SnO2 microbelts (Inset in Fig. 1(a) is the optical image of as-prepared SnO2 samples). (d) XRD pattern of a single SnO2 microbelt.
    (Color online) XPS and UV−vis spectra of SnO2 microbelts. (a) The survey spectrum, high-resolution X-ray photoelectron spectra for (b) Sn 3d core level, (c) O 1s core level. (d) The UV−vis absorption spectrum. The inset in (d) is a plot of (αhν)2 versus hν for the SnO2 microbelts, with Eg representing the optical band gap.
    (Color online) Photoelectrical performances of the single SnO2 microbelt based photodetector. (a) The I−V curves under dark, and under illumination with 500 and 300 nm in ambient air, (b) I−t curve under 3 V and 300 nm (0.311 mW∙cm−2), (c) instant photo response and (d) spectral photo response ranging 250 to 500 nm (Inset: a semi-log plot showing the responsivity as a function of wavelength).
    (Color online) Photoelectrical performances of the self-powered p-Si/n-SnO2 UV PD. (a) Illumination area of single SnO2 microbelt and p-Si/n-SnO2 based UV PD. (b) I−V curves under dark conditions and under exposure to 500 and 300 nm UV light in ambient conditions, (c) I−t curve at 300 nm and 3 V, (d) instant photo response and (e) spectral photo response from 250 to 500 nm at a basis of 3 V.
    (Color online) Self-powered performances of the SnO2−p-Si UV PD. (a) I−t curve at 300 nm and 0 V, (b) spectral photo response from 250 to 700 nm at a basis of 0 V (Inset: a plausible response mechanism for the p-Si/n-SnO2 heterojunction device).
    • Table 1. Comparison of the key parameters and fabrication methods of SnO2-based self-powered photodetectors against those of other nanomaterial counterparts.

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      Table 1. Comparison of the key parameters and fabrication methods of SnO2-based self-powered photodetectors against those of other nanomaterial counterparts.

      PhotodetectorsPreparation methods*Wavelength(nm)Dark currentRise timeDecay timeReference
      *CBD, chemical bath deposition; SC, spin coating; TA, thermal annealing; DP, drop pyrolysis; EBE, electron beam evaporation; MS, magnetron sputtering; STO, Sn thermal oxidation; PLD, pulsed laser deposition; ES, electrospinning; HT, hydrothermal; TV, thermal evaporation.
      n-SnO2/p−CuZnSCVD + CBD3000.1 pA at 0 V45 µs at 0 V1.17 ms at 0 V[10]
      SnO2/Cs2AgBiBr6SC + SC3659.5 nA at 0 V2 ms at 0 V2 ms at 0 V[11]
      SnO2/CsPbBr3CVD + DP3002 pA at 0 V[12]
      SnO2/CsBi3I10SC + SC6501.9 pA at 0 V7.8 µs at 0 V8.8 µs at 0 V[13]
      SnO2/NiOEBE + MS3657.3 pA at 5 V89 ms at 0 V89 ms at 0 V[15]
      SnO2/CuICVD + TV3000.1 pA at 0 V0.3 ms at 0 V1.1 ms at 0 V[16]
      β-Bi2O3/SnO2ES + HT3650.6 nA at 0 V~0.92 s at 0 V~0.92 s at 0 V[18]
      SnO2/p-SiCVD3000.04 pA at 0 V150 μs at 1 V3.3 ms at 1 VThis work
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    Xingyu Li, Li Tian, Jinshou Wang, Hui Liu. Facile construction of p-Si/n-SnO2 junction towards high performance self-powered UV photodetector[J]. Journal of Semiconductors, 2025, 46(7): 072701

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    Paper Information

    Category: Research Articles

    Received: Dec. 7, 2024

    Accepted: --

    Published Online: Aug. 27, 2025

    The Author Email: Hui Liu (HLiu)

    DOI:10.1088/1674-4926/24090048

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