Spectroscopy and Spectral Analysis, Volume. 41, Issue 9, 2872(2021)

Hyperspectral Estimation Model of Heavy Metal Arsenic in Soil

Zhi-yuan LI1、*, Fan DENG1、1; *;, Jun-liang HE2、2;, and Wei WEI1、1;
Author Affiliations
  • 11. School of Geosciences, Yangtze University, Wuhan 430100, China
  • 22. College of Resources and Environment Sciences, Shijiazhuang University, Shijiazhuang 050035, China
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    Figures & Tables(12)
    Study area and the distribution of the soil sampling points
    Transformed soil reflectance spectra after
    Smoothed reflectance spectra of soil samples
    Continuum removal correlation coefficient curve
    Scatter plots of fitting and testing sets for MLSR(a): Fitting set; (b): Testing set
    Scatter plots of the two set of samples of fitting and testing for M-PLSR(a):Fitting samples; (b): Testing samples
    • Table 1. Descriptive statistics of the arsenic content (mg·kg-1) in soil

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      Table 1. Descriptive statistics of the arsenic content (mg·kg-1) in soil

      重金属最小值平均值最大值标准差河北省背景值
      As10.84413.23015.1251.00513.6
    • Table 2. Statistical results of single factor pollution index of the soil arsenic

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      Table 2. Statistical results of single factor pollution index of the soil arsenic

      元素最小值平均值最大值样点数
      0.7<Pi≤11<Pi≤2
      As/(mg·kg-1)0.7970.9731.1122919
    • Table 3. Maximum correlation coefficients of heavy metal As content and spectral indexes

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      Table 3. Maximum correlation coefficients of heavy metal As content and spectral indexes

      光谱指标最大相关波段/nm相关系数
      SR2 342-0.289*
      FD1 211-0.527**
      SD2 208-0.470**
      RT1 7400.357*
      RTFD1 359-0.249
      RTSD1 0650.485**
      AT1 7400.353*
      ATFD464-0.370**
      ATSD2 2080.372**
      CR6820.603**
    • Table 4. Results of MLSR model

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      Table 4. Results of MLSR model

      参数建模样本验证样本
      r0.8140.776
      RMSE0.1590.318
      F29.4378.482
    • Table 5. Results of U-PLSR model

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      Table 5. Results of U-PLSR model

      参数建模样本验证样本
      rRMSEFrRMSEF
      FD0.2600.7532.3740.3200.6871.194
      ATFD0.2000.8141.6890.0250.9940.239
      RTSD0.2130.8011.8260.2960.7220.939
      CR0.3650.6473.8720.3810.6492.465
    • Table 6. Results of M-PLSR model

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      Table 6. Results of M-PLSR model

      参数建模样本验证样本
      r0.8520.812
      RMSE0.1470.312
      F32.3848.598
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    Zhi-yuan LI, Fan DENG, Jun-liang HE, Wei WEI. Hyperspectral Estimation Model of Heavy Metal Arsenic in Soil[J]. Spectroscopy and Spectral Analysis, 2021, 41(9): 2872

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    Paper Information

    Category: Research Articles

    Received: Jun. 11, 2020

    Accepted: --

    Published Online: Oct. 29, 2021

    The Author Email: LI Zhi-yuan (oliverblues@outlook.com)

    DOI:10.3964/j.issn.1000-0593(2021)09-2872-07

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