AEROSPACE SHANGHAI, Volume. 42, Issue 1, 102(2025)

Effects of Composite and Dual-layer Silane Films on the Corrosion Resistance of Mg-Gd-Y Rare Earth Magnesium Alloys

Chenkai XIE*, Jiangang JIN, Lijun ZHANG, and Caiyuan LIN
Author Affiliations
  • Shanghai Spaceflight Precision Machinery Institute,Shanghai201600,China
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    Figures & Tables(11)
    Structural molecular formulae of KH560,BTSE,and OTES
    SEM images of KH560 silane film,BKO composite silane film,and BKO dual-layer silane film
    Contact angles of the KH560 silane film,BKO composite silane film,and BKO dual-layer silane film
    Polarization curves of three silane films in the NaCl solution with a mass fraction of 3.5%
    XPS full spectrum diagram of the BKO dual-layer silane film and high resolution spectra of Mg,O,and Si
    Electrochemical impedance spectra of three membrane layers in a 3.5% mass fraction NaCl solution
    Equivalent circuits of the KH560 silane film,BKO composite silane film,and BKO dual-layer silane film
    • Table 1. Mass fractions of various elements on the surfaces of different silane films

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      Table 1. Mass fractions of various elements on the surfaces of different silane films

      硅烷膜COMgSi
      KH560硅烷膜14.909.5970.115.39
      BKO复合膜硅烷膜22.4522.3538.8216.38
      BKO双层膜硅烷膜24.0323.5130.0722.39
    • Table 2. Fitting parameters corresponding to the polarization curves of three silane films in the NaCl solution with a mass fraction of 3.5%

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      Table 2. Fitting parameters corresponding to the polarization curves of three silane films in the NaCl solution with a mass fraction of 3.5%

      镁合金基体及硅烷膜Icorr/(A·cm-2)Ecorr (V)
      镁合金基体6.91×10-5-1.373
      KH560硅烷膜1.18×10-7-1.346
      BKO复合硅烷膜1.14×10-8-1.227
      BKO双层硅烷膜6.97×10-9-1.184
    • Table 3. Corrosion morphology of different silane films in the NaCl solution with a mass fraction of 3.5% for different time

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      Table 3. Corrosion morphology of different silane films in the NaCl solution with a mass fraction of 3.5% for different time

      材料0 h24 h72 h168 h
      裸镁合金
      KH560硅烷膜
      BKO复合硅烷膜
      BKO双层硅烷膜
    • Table 4. Fitting parameters of the electrochemical impedance spectra of three types of silane films

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      Table 4. Fitting parameters of the electrochemical impedance spectra of three types of silane films

      硅烷膜Rf1/(Ω·cm2)Rf2/(Ω·cm2)Rct/(Ω·cm2)
      KH560硅烷膜1.04×1035.47×105
      BKO复合膜硅烷膜1.28×1041.84×106
      BKO双层膜硅烷膜3.08×1041.84×1031.60×106
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    Chenkai XIE, Jiangang JIN, Lijun ZHANG, Caiyuan LIN. Effects of Composite and Dual-layer Silane Films on the Corrosion Resistance of Mg-Gd-Y Rare Earth Magnesium Alloys[J]. AEROSPACE SHANGHAI, 2025, 42(1): 102

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    Paper Information

    Category: Integration of Material Structure and Function

    Received: Aug. 15, 2024

    Accepted: --

    Published Online: May. 13, 2025

    The Author Email:

    DOI:10.19328/j.cnki.2096-8655.2025.01.010

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