Acta Optica Sinica, Volume. 44, Issue 18, 1801005(2024)

Synchronous Measurement Method of Seawater Temperature and Salinity Based on Raman Spectrum

Rui Dong, Wangquan Ye*, Bin Gui, Yu Chen, Yuan Lu, Jinjia Guo, and Ronger Zheng
Author Affiliations
  • Faculty of Information Science and Engineering, Ocean University of China, Qingdao 266100, Shandong , China
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    Figures & Tables(12)
    Decomposition of OH Raman stretching vibration peaks corresponding to different local hydrogen bonds of water molecules
    Optical layout for Raman spectral measurement of water with controllable temperature
    Flow chart of optimization process of spectral peak fitting using L-M algorithm
    Decomposed sub-peaks of 2800-3800 cm-1 and residual between fitted and original spectra
    Comparison of Raman peaks of OH at different temperatures and electrical conductivities after spectral pretreatment.(a) Different temperatures; (b) different electrical conductivities
    Two-dimensional distribution diagram of spectral intensity at characteristic peak position as a function of temperature and electrical conductivity. (a) 3200 cm-1; (b) 3490 cm-1
    Normalized intensity of OH Raman subpeaks varying with temperature and electrical conductivity. (a) Varying with temperature; (b) varying with electrical conductivity
    Temperature and electric conductivity prediction results and related evaluation indicators of different quantitative algorithms on test set. (a) PLSR; (b) LASSO; (c) SVR; (d) LSTM+AM
    Structure diagram of Stacking ensemble learning model
    Prediction results and evaluation indicators of temperature and electric conductivity in test set using Stacking model
    • Table 1. Concentration and electric conductivity (salinity) distributions of sample

      View table

      Table 1. Concentration and electric conductivity (salinity) distributions of sample

      ParameterValue
      Concentration /(mmol/L)0501002004005007001000
      Conductivity /(mS/cm)3.135.8110.9020.9038.6047.2063.6088.30
      Salinity /PSU1.603.106.1012.5024.4030.4042.5062.70
    • Table 2. Temperature measurements of samples with different electric conductivities (salinities) at set temperatures

      View table

      Table 2. Temperature measurements of samples with different electric conductivities (salinities) at set temperatures

      Tset*3.13 mS/cm5.81 mS/cm10.90 mS/cm20.90 mS/cm38.60 mS/cm47.20 mS/cm63.60 mS/cm88.30 mS/cm
      2.002.703.06/3.042.52/2.632.592.80/2.762.71/2.712.712.66/2.67
      4.004.67/4.654.984.494.614.724.524.69
      6.006.506.796.49/6.35/6.276.426.536.406.456.48
      8.008.418.698.30/8.238.358.498.36/8.268.388.37
      10.0010.2910.5710.25/10.1010.3010.4110.3010.3410.13
      12.0012.4312.4512.1512.2412.5412.2812.2412.25
      14.0014.2214.3714.1914.1514.2514.2114.1914.18
      16.0016.1216.2416.0716.1016.1216.2016.1116.12
      18.0018.0518.2218.0018.0318.0418.0918.0318.07
      20.0019.9420.0319.9819.9519.9820.0119.9519.96
      22.0021.8821.9021.8721.8921.9021.9621.8821.91
      24.0023.8223.8023.8123.8223.8223.8723.8123.84
      26.0025.7125.7025.7625.7725.7525.7925.7125.76
      28.0027.6627.6227.7127.6827.7127.6727.6227.67
      30.0029.6429.5229.6229.6429.6229.6129.5829.62
      32.0031.5431.3831.5631.5931.4931.5331.3831.50
      34.0033.3233.2533.3533.3533.3233.48
      36.0035.3135.1735.4135.28/35.4235.2635.1335.2935.37
      38.0037.0437.0237.2937.3537.2537.1637.2236.89/37.01
      40.0039.0638.3039.1238.9538.9438.9138.7538.97
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    Rui Dong, Wangquan Ye, Bin Gui, Yu Chen, Yuan Lu, Jinjia Guo, Ronger Zheng. Synchronous Measurement Method of Seawater Temperature and Salinity Based on Raman Spectrum[J]. Acta Optica Sinica, 2024, 44(18): 1801005

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    Paper Information

    Category: Atmospheric Optics and Oceanic Optics

    Received: Dec. 20, 2023

    Accepted: Feb. 2, 2024

    Published Online: Sep. 11, 2024

    The Author Email: Ye Wangquan (yewangquan@ouc.edu.cn)

    DOI:10.3788/AOS231952

    CSTR:32393.14.AOS231952

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