Journal of Synthetic Crystals, Volume. 54, Issue 6, 1068(2025)

Lithium Storage Properties of Nanosized Hollow Cubic ZnMn2O4/rGO Composite Materials

Lin ZHANG, Qianghao CAI, Hanwen DAI, Yanming WANG, and Fei WANG*

ZnMn2O4 is a potential anode material for lithium-ion batteries with high specific capacity, but its high-rate performance and cycle life need to be improved. In this paper, ZnMn2O4 hollow cubes with an edge length of about 200 nm were prepared by a facile microemulsion method at room temperature followed by an annealing process. The cubes consist of interconnected nanoparticles with sizes of 30~50 nm. In order to improve the conductivity of the material, ZnMn2O4/rGO composite was prepared by mixing ZnMn2O4 with graphene oxide (GO) followed by a heat treatment. The phase composition, microstructure, lithium storage properties and mechanism of the composite were systematically investigated. As an anode material for lithium-ion batteries, ZnMn2O4/rGO delivers discharge capacities of 1 193 and 620 mAh·g-1 at current densities of 0.1 and 4 A·g-1, respectively. A discharge capacity of 806 mAh·g-1 can be achieved after 700 cycles at 1 A·g-1. The outstanding rate performance and cycle stability can be attributed to the synergistic effect of ZnMn2O4 and reduced graphene oxide (rGO). The smaller secondary cube/primary nanoparticle sizes enable the short Li+ diffusion distance. The hollow structure provides space for volume expansion of the material during lithiation, so that the cube can maintain its structural integrity. The rGO not only constructs a 3D electron transport network of the material to accelerate the electron transport speed, but also buffers the volume change during lithium insertion/extraction to maintain the structure stability of the material. This study provides a feasible strategy for the preparation of high-performance metal oxide anode materials.

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Lin ZHANG, Qianghao CAI, Hanwen DAI, Yanming WANG, Fei WANG. Lithium Storage Properties of Nanosized Hollow Cubic ZnMn2O4/rGO Composite Materials[J]. Journal of Synthetic Crystals, 2025, 54(6): 1068

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Paper Information

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Received: Feb. 12, 2025

Accepted: --

Published Online: Jul. 8, 2025

The Author Email: Fei WANG (wangfeichem@126.com)

DOI:10.16553/j.cnki.issn1000-985x.2025.0025

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