NUCLEAR TECHNIQUES, Volume. 47, Issue 7, 070502(2024)

Preparation and ultrasonic cutting of 3C-SiC nanowires by chemical vapor deposition method

Shancheng PENG1,2, Yiyan LI1,3, Huilei MA1,2, Mingqi DU4, Chuanxin LIU5, and Zhoutong HE1、*
Author Affiliations
  • 1Shanghai Institute of Applied Physics, Chinese Academy of Sciences, Shanghai 201800, China
  • 2University of Chinese Academy of Sciences, Beijing 100049, China
  • 3School of Nuclear Science and Technology, University of South China, Hengyang 421001, China
  • 4College of Sciences, Shihezi University, Shihezi 832003, China
  • 5Science and Technology on Thermostructural Composite Materials Laboratory, Northwestern Polytechnical University, Xi'an 710072, China
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    Background

    3C-SiC (β-SiC) exhibits outstanding electrochemical properties and radiation resistance, surpassing hexagonal-phase silicon carbide in irradiation resistance. As a promising candidate for the next generation of structural materials in nuclear applications and high-performance precision electronic devices for challenging reactor environments, the material has been garnering significant attention in recent decades. Within this realm, the exploration of one-dimensional silicon carbide nanomaterials has become a focal point in silicon carbide materials research. However, their practical applications have been hindered by challenges such as the absence of effective nanomaterial processing methods and processing complexities. Notably, ultrasonic processing technology has demonstrated effectiveness in addressing these challenges.

    Purpose

    This study aims to synthesize and study 3C-SiC nanowires (NWs), investigating their ultrasonic fracture behavior for comprehensive understanding of the ultrasonic fracture characteristics of 3C-SiC NWs, laying the groundwork for basic research in the processing of one-dimensional SiC nanomaterials.

    Methods

    Firstly, silicon carbide nanowires were prepared by chemical vapor deposition. Then the silicon carbide nanowires were characterized by microstructure observed by scanning electron microscope (SEM), transmission electron microscope (TEM), X-Ray diffraction (XRD) and Raman spectrum. Subsequently, the 3C-SiC nanowires were subjected to ultrasonic treatment, and the average length-to-diameter ratios of the ultrasonically treated nanowires were statistically analyzed to elucidate the effect of ultrasonic treatment on the nanowires. Finally, the strength of the silicon carbide nanowires was estimated by combining the bubble jet model and statistical data.

    Results

    The findings reveal that the synthesized 3C-SiC NWs are predominantly of the 3C-SiC phase, exhibiting a notable presence of stacking faults. Ultrasonic treatment significantly influences the SiC NWs, leading to a noticeable reduction in the average Length-Diameter ratio, stabilizing at 18 post-treatment.

    Conclusions

    The observed results align with the effects of bubble jetting and are corroborated by the ultrasonic fragmentation behavior of 3C-SiC NWs. These findings offer valuable insights for the manipulation of nanomaterial size and morphology. This study provides a new perspective for the ultrasonic cutting of silicon carbide nanowires and the strength research of nanowires, and is of great significance for the future application of silicon carbide nanowires in the field of nuclear energy.

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    Shancheng PENG, Yiyan LI, Huilei MA, Mingqi DU, Chuanxin LIU, Zhoutong HE. Preparation and ultrasonic cutting of 3C-SiC nanowires by chemical vapor deposition method[J]. NUCLEAR TECHNIQUES, 2024, 47(7): 070502

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    Paper Information

    Category: Research Articles

    Received: Mar. 7, 2024

    Accepted: --

    Published Online: Aug. 27, 2024

    The Author Email: HE Zhoutong (贺周同)

    DOI:10.11889/j.0253-3219.2024.hjs.47.070502

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